A Laboratory and Theoretical Study on the Uptake of SO2 Gas by Large and Small Water Drops Containing Heavy Metal Ions

Laboratory experiments have been carried out to investigate the uptake of sulfur dioxide by water drops containing heavy metal ions where the metal ions serve as catalysts to oxidise the taken up S(IV) into S(VI). During the gas uptake the drops were freely suspended at their terminal velocity in the airstream of the Mainz vertical wind tunnel. Two series of experiments were carried out, one with large millimeter size water drops containing manganese or iron ions, and the other with small water drops containing manganese ions and having radii in hundreds of micron size range. The experimental results were compared against model computations using the Kronig–Brink model and the fully mixed model, modified for the case that heavy metal ions present in the liquid phase act as catalysts for the oxidising process. The results of the model calculations show that there are only small differences between the predicted gas uptake according to the two models. In addition it was found that the experimental obtained results from the uptake of SO₂ by water drops containing heavy metal ions for both, large and small water drops did agree with the model results.     

闪电首次回击过程的光谱特性

用无狭缝摄谱仪，拍摄了4次云对地闪电首次回击过程390一660nm波长范围的光谱，并将原子结构的理论应用于闪电光谱的研究，用多组态Dirac—Fock方法，系统考虑相对论效应、电子关联、弛豫效应等重要贡献，对光谱的精细结构进行了计算，给出了谱线的波长、振子强度以及相应的上能级激发能量。通过与试验观测谱线的比较分析发现，大多数谱线对应的上激发能在23ev左右。首次回击过程中，闪电通道内NII离子的密度最大，并且大多数处于n＝3的激发态。     

湘南稀土矿床的放射性特征及其对开采的影响

湘南主要稀土矿区的岩、矿石和稀土矿物的放射性特征表明，矿区放射性强度的高低与稀土总量无关，而与矿石的铀、钍含量密切相关；主要矿区的放射性对其开发与产品都没有影响，但长期接触对人体有一定危害。因此，开采时必须加强防护，防止放射性的长期照射，并选用无放射性的清洁饮用水，以保护人体健康。     

气相色谱和薄层色谱法在形态分析中的应用

评述了气相色谱和薄层色谱法用于氯、溴、碘、硫、硒、碲、铬、氮、磷、砷、钒、碳、锡、铅、铁和汞１６种元素的不同形态分析的进展。这些形态包括不同价态、有机态、无机态、阳离子和阴离子态等。由于气相色谱和薄层色谱法都具有分离和检测两种功能结合的特点，因此它们是用于元素形态分析的有效和方便的方法。引用１９８０～１９９４年文献９２篇     

Comparison of Cu and Zn cycling in eutrophic lakes with oxic and anoxic hypolimnion

Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation 1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by freshly formed Mn- and Fe-oxides.     

Impact of UV-B, Heat and Chemicals on Ethylene-Production of Lichens

To assess the impact of UV-B radiation combined with NaHSO₃ in solution under laboratory conditions, we compared the amounts of stress-ethylene produced by two lichen species of the same genus. Ramalina lacera, an epiphytic Mediterranean lichen, was found to be rather sensitive to UV-B combined with NaHSO₃, relative to the epilithic desert lichen R. maciformis. The impact of high temperatures with FeCl₂ in solution, measured by amounts of stress ethylene accentuated the adaptability of R. maciformis to desert conditions, whereas R. lacera appeared to be rather sensitive to extreme temperatures especially in the case of chemical contamination. The adaptability of R. maciformis to UV-B appears to be related to the photoprotective capabilities of lichen substances.     

重金属迁移转化模型研究

大量重金属污染物迁移转化的现象和研究成果都表明重金属以泥沙颗粒为载体迁移转化,描述重金属在天然水体中的迁移转化必须紧紧抓住泥沙颗粒运动及重金属与泥沙之间的转化关系进行.为此在对现有的重金属迁移转化数学模型进行概括分类的基础上,根据水沙运动与污染物相互作用关系,分析了泥沙颗粒运动及重金属吸附解吸不平衡过程,并结合水沙数学模型,建立了重金属迁移转化的耦合模型.同时在模型合理性分析的基础上,对模型进行了计算分析,分析表明模型能够合理地反映重金属污染物在水体中的迁移转化过程.     

地热井常见主要问题分析与研究

针对目前地热井施工技术现状及地热井使用中常见的问题，进行了较为详细的分析和研究，并就今后发展方向和建议进行了初步探讨。     

视电阻率观察中一种抗介质干扰的尝试

埋地金属管线对视电阻率的观测危害甚大。造成观测值大幅改变，跳动，无规律可循。严重时，甚至台站报废，被迫搬迁。通过一些突发事件的启发，结合现场实验，并引证了一些理论计算，笔者摸索出了只须对金属管道作局部微小的改造，就能基本克服其对观测的干扰的方法。该方法在红格台试验半年多来，取得了明显的效果。观测值恢复到安装的水管以前的水平，再无大幅度的跳动。该方法节约经费，简单易行，大大提高了台站在复杂环境中的生存能力。     

Spatial and Temporal Cusp Structures Observed by Multiple Spacecraft and Ground Based Observations

Downward precipitating ions in the cusp regularly exhibit sudden changes in ion energy distributions, forming distinctive structures that can be used to study the temporal/spatial nature of reconnection at the magnetopause. When observed simultaneously with the Polar, FAST, and Interball satellites, such cusp structures revealed remarkably similar features. These similar features could be observed for up to several hours during stable solar wind conditions. Their similarities led to the conclusion that large-scale cusp structures are spatial structures related to global ionospheric convection patterns created by magnetic merging and not the result of temporal variations in reconnection parameters. The launch of the Cluster fleet allows cusp structures to be studied in great detail and during changing solar wind conditions using three spacecraft with identical plasma and field instrumentation. In addition, Cluster cusp measurements are linked with ionospheric convection cells by combining the satellite observations with SuperDARN radar observations that are used to derive the convection patterns in the ionosphere. The combination of satellite observations with ground-based observations during variable solar wind conditions shows that large-scale cusp structures can be either spatial or temporal. Cusp structures can be described as spatial features observed by satellites crossing into spatially separated flux tubes. Cusp structures can also be observed as poleward-traveling (temporal) features within the same convection cell, most probably caused by variations in the reconnection rate at the magnetopause.