贵州都匀大亮锌矿床闪锌矿稀土元素地球化学特征及其指示意义北大核心CSCD

贵州都匀大亮锌矿床是牛角塘铅锌矿田的重要组成部分,目前所开采的对象为近年来在“陡倾斜带”中新发现的矿体,其研究还十分薄弱。本研究采用ICP-MS测试技术,对大亮锌矿闪锌矿进行了稀土元素测试,以揭示该矿床成矿作用。结果表明,10件闪锌矿样品的ΣREE值低,质量分数为(0.15~0.40)×10^(-6)(平均0.24×10^(-6))。样品的LREE/HREE值变化范围为7.07~15.76(平均10.95),(La/Yb)_(N)值范围为4.75~28.57(平均11.54),(La/Sm)_(N)值为2.16~6.01(平均3.49),(Gd/Yb)^(N)值为0.34~3.68(平均1.67)。闪锌矿样品稀土元素呈现轻稀土富集的右倾模式,且轻稀土元素的分异程度远远高于重稀土元素。样品具有显著Eu正异常(δEu为6.60~54.29,平均18.10),无明显的Ce异常(δCe主要为0.93~1.09,平均1.01)。闪锌矿轻稀土富集及显著Eu正异常的特点表明,其稀土元素为矿石初始沉淀时从成矿热液中继承而来,未明显受到后期地质作用的影响。稀土元素特征表明该闪锌矿形成于较低温度和极强还原条件。大亮锌矿闪锌矿Y/Ho比值为11.33~32.17(平均22.71),与区域矿床及地层的对比表明成矿物质主要来自下伏地层,可能有少量来自赋矿围岩。     

广西三江县土壤硒含量分布特征及其影响因素研究

以广西三江县土壤为研究对象,采集了表层土壤样2 751件和土壤垂向剖面样180件,测定了土壤中硒的含量。利用多元统计分析、地统计学法、GIS空间分析技术和Pearson相关性分析法研究了土壤硒的含量特征和影响因素。结果表明:研究区表层土壤硒平均含量为0.63 mg/kg,变化范围为0.10~14.41 mg/kg。研究区土壤硒资源丰富,足硒和富硒土壤面积为95.87%。土壤硒含量的分布主要受到地质背景的控制,不同成土母岩形成的表层土壤硒含量存在较大差异,寒武系以黑色岩系为母质的土壤硒含量最高,平均含量达2.58 mg/kg,变化范围为0.31~14.41 mg/kg。不同土壤类型中,黄壤硒含量最高,平均含量达0.75 mg/kg,变化范围为0.24~2.07 mg/kg,水稻土硒含量最低,平均含量为0.51 mg/kg;不同土地利用类型土壤硒含量差异较大,除水田为基本自然状态以外,其余地类均呈现富集。研究区表层土壤硒含量总体上受控于深层土壤硒含量,成土过程中表层土壤硒含量发生了次生富集。同时土壤pH、Corg、P、S、Al₂O₃、TFe₂O₃含量和CIA等对土壤硒含量的分布也有一定的影响。     

Thermal analysis of energy piles in sand

The present work investigates the behaviour of geothermal energy piles in sand subjected to thermal loading and the resulting soil-structure interaction, numerically using the finite element software Abaqus and user-defined material subroutines for soil. The stress-strain response of sand has been simulated using CASM constitutive model based on critical-state soil mechanics. Detailed parametric sensitivity studies have been carried out to understand the effects of different end conditions of the pile, relative densities of the soil, coefficients of lateral earth pressure of the ground, lengths and diameters of the pile, thermal loads, coefficients of friction at the pile-soil interface, critical-state friction angles of soil, thermal conductivity of soil, specific heat of soil and thermal conductivity of the pile on the stress response of soil, deformation of the pile and soil, and strains in the pile. The results show that negative shear stress is generated in the soil at the pile-soil interface. In the pile with both ends restrained the lateral earth pressure coefficient in soil increases due to high radial strain generation. Moreover, the lateral earth pressure coefficient in soil increases with the increase in the thermal load, the coefficient of friction at the pile-soil interface and the critical-state friction angle of the soil.     

基于DEA和Malmquist的中国城市代谢效率研究

运用物质流、数据包络分析(DEA)及Malmquist指数对中国31个案例城市进行了城市代谢效率的研究。通过将城市代谢系统社会经济产出、环境非期望产出及水、电、化石能源、金属矿物、建筑材料、食物等投入部分纳入进DEA和Malmquist指数中,测得了案例城市的2000年、2010年代谢效率及变化趋势。研究结果发现,中国城市代谢系统效率总体相对较高,尤其是东中部地区城市的综合效率、纯技术效率和规模效率要高于西部地区城市,大城市的代谢综合效率高于巨型、超大和特大城市。2000~2010年,城市代谢综合效率、纯技术效率等所有效率指标的均值均呈现出下降趋势,但是中、西部地区城市的综合效率和纯技术效率却呈改善趋势,并且特大和超大城市的综合效率高于巨型城市。     

A visco‐plastic constitutive model for granular soils modified according to non‐local and gradient approaches

An already available non‐associated elastic–viscoplastic constitutive model with anisotropic strain hardening is modified in order to describe both the constitutive parameter dependency on relative density and the spatio‐temporal evolution of strain localization. To achieve this latter goal, two distinct but similar approaches are introduced: one inspired by the gradient theory and one by the non‐local theory. A one‐dimensional case concerning a simple shear test for a non‐homogeneous infinitely long dense sand specimen is numerically discussed and a finite difference scheme is employed for this purpose. The results obtained by following the two different approaches are critically analysed and compared. Copyright © 2001 John Wiley & Sons, Ltd.     

On flow of a heat conducting fluid through a porous medium

Summary . A two-space singular perturbation technique is employed to derive approximate governing equations for flow of a viscous heat-conducting fluid through a rigid porous solid. It is assumed that buoyancy forces are significant, and it is shown that standard approximations used in the study of flow through a porous medium are valid provided that Gr ≫ 1, where Gr is a Grashof number calculated using a typical pore radius as the length scale. Results previously derived in the literature for flow through an isotropic random array of spherical particles are used to show how the permeability and conductivity tensors can be calculated for a problem of interest in planetary science.     

气象服务产业化、商品化趋势及其对策

20世纪50年代以来,大气科学的发展和新科技在气象实践中的运用,不同程度地提高着气象成果的多样性、专业性、应用性和有效性,从而创造了气象成果产业化、商品化的物质技术条件;社会生产和居民生活对气象成果更为多样的、专一的需要,形成了气象成果产业化、商品化的市场条件。我国气象服务有偿化的发展已成为趋势;但从社会需求与气象服务自身现状考察,认真转变观念、积极调整结构、大力拓展市场、深化基础研究乃是加速气象成果产业化、商品化趋势的基本对策。     

Microplane constitutive model for porous isotropic rocks

The paper deals with constitutive modelling of contiguous rock located between rock joints. A fully explicit kinematically constrained microplane‐type constitutive model for hardening and softening non‐linear triaxial behaviour of isotropic porous rock is developed. The microplane framework, in which the constitutive relation is expressed in terms of stress and strain vectors rather than tensors, makes it possible to model various microstructural physical mechanisms associated with oriented internal surfaces, such as cracking, slip, friction and splitting of a particular orientation. Formulation of the constitutive relation is facilitated by the fact that it is decoupled from the tensorial invariance restrictions, which are satisfied automatically. In its basic features, the present model is similar to the recently developed microplane model M4 for concrete, but there are significant improvements and modifications. They include a realistic simulation of (1) the effects of pore collapse on the volume changes during triaxial loading and on the reduction of frictional strength, (2) recovery of frictional strength during shearing, and (3) the shear‐enhanced compaction in triaxial tests, manifested by a deviation from the hydrostatic stress–strain curve. The model is calibrated by optimal fitting of extensive triaxial test data for Salem limestone, and good fits are demonstrated. Although these data do not cover the entire range of behaviour, credence in broad capabilities of the model is lend by its similarity to model M4 for concrete—an artificial rock. The model is intended for large explicit finite‐element programs. Copyright © 2002 John Wiley & Sons, Ltd.     

Macro- and meiofaunal recolonisation of dredged material used for habitat enhancement: temporal patterns in community development

In recent years, dredged material has become regarded as a potential resource and used to create and/or improve intertidal habitats (i.e., beneficial use). This paper presents the results of a sampling programme to investigate the long-term (42 months post-recharge) macro- and meiofaunal recolonisation processes of a beneficial use scheme in south-east England. While univariate indices of community structure indicated that the scheme’s meiofaunal community was never significantly different from that of a nearby reference area, such attributes for macrofauna were continually significantly below those of the reference area, although this was not the case for all reference stations. Multivariate analyses revealed that macro- and meiofaunal community structures were always significantly different from those of the reference communities. We discuss the factors responsible for these observations and propose that assessing recovery of a beneficial use scheme should be undertaken using pre-defined criteria in addition to comparisons with a reference site.     

锂离子电池硅基负极材料研究进展

硅是青海省储量丰富的资源之一,因其储锂容量高、安全性能优越,而成为锂离子电池理想的负极材料,但由于硅在深度嵌脱锂时体积效应大,易与导电介质、集流体失去电接触,造成电极循环性能迅速下降。对抑制其体积效应、增加其电导率的"低维化"和"复合化"两种技术进行了介绍。