环境水土对重要建筑材料的腐蚀作用

从建筑材料和水土中活跃成分的化学性质出发,讨论环境水土成分对重要建筑材料的腐蚀的机理及其评价的有关问题。     

Prediction of uniaxial compression PFC3D model micro‐properties using artificial neural networks

Artificial neural networks are used to predict the micro‐properties of particle flow code in three dimensions (PFC3D) models needed to reproduce macro‐properties of cylindrical rock samples in uniaxial compression tests. Data for the training and verification of the networks were obtained by running a large number of PFC3D models and observing the resulting macro‐properties. Four artificial networks based on two different architectures were used. The networks used different numbers of input parameters to predict the micro‐properties. Multi‐layer perceptron networks using Young's modulus, Poisson's ratio, uniaxial compressive strength, model particle resolution and the maximum‐to‐minimum particle ratio showed excellent performance in both training and verification. Adding one more variable—namely, minimum particle radius—showed degrading performance. Copyright © 2009 John Wiley & Sons, Ltd.     

Grain size composition and transport of sedimentary organic carbon in the Changjiang River (Yangtze River) Estuary and Hangzhou Bay and their adjacent waters

Surface sediments from the Changjiang River(Yangtze River) Estuary,Hangzhou Bay,and their adjacent waters were analyzed for their grain size distribution,organic carbon(OC) concentration,and stable carbon isotope composition(δ13C).Based on this analysis,about 36 surface sediment samples were selected from various environments and separated into sand(0.250 mm,0.125–0.250 mm,0.063–0.125 mm) and silt(0.025–0.063 mm)fractions by wet-sieving fractionation methods,and further into silt-(0.004–0.025 mm) and clay-sized(0.004mm) fractions by centrifugal fractionation.Sediments of six grain size categories were analyzed for their OC andδ13C contents to explore the grain size composition and transport paths of sedimentary OC in the study area.From fine to coarse fractions,the OC content was 1.18%,0.51%,0.46%,0.42%,0.99%,and 0.48%,respectively,while theδ13C was –21.64‰,–22.03‰,–22.52‰,–22.46‰,–22.36‰,and –22.28‰,respectively.In each size category,the OC contribution was 42.96%,26.06%,9.82%,5.75%,7.09%,and 8.33%,respectively.The OC content in clay and fine silt fractions(0.025 mm) was about 69.02%.High OC concentrations were mainly found in offshore modern sediments in the northeast of the Changjiang River Estuary,in modern sediments in the lower estuary of the Changjiang River and Hangzhou Bay,and in Cyclonic Eddy modern sediments to the southwest of the Cheju Island.Integrating the distribution of terrestrial OC content of each grain size category with the δ13C of the bulk sediment indicated that the terrestrial organic material in the Changjiang River Estuary was transported seaward and dispersed to the Cyclonic Eddy modern sediments to the southwest of the Cheju Island via two pathways:one was a result of the Changjiang River Diluted Water(CDW) northeastward extending branch driven by the North Jiangsu Coastal Current and the Yellow Sea Coastal Current,while the other one was the result of the CDW southward extending branch driven by the Taiwan Warm Current.     

Plastic debris as nesting material in a Kittiwake-(Rissa tridactyla)-colony at the Jammerbugt, Northwest Denmark

This paper continues the investigations of Clemens and Hartwig from 1992 on the proportion of garbage used as nesting material in the Kittiwake colony at Bulbjerg in the Jammerbugt in Northwest Denmark. Whereas in the year 1992 plastic garbage items were included in 39.3% of 466 Kittiwake nests in the Bulbjerg colony, in 2005 57.2% of 311 nests contained plastic debris. Although it has been forbidden to dispose of plastic garbage into the marine environment since the implementation of the MARPOL 73/78-Agreement/Annex V (Regulation for the Prevention of Pollution by Ship Waste) of 1989 and especially since the declaration of the North Sea as a MARPOL-Special Area for garbage in 1991, the pollution of the oceans and the North Sea is still an ubiquitous problem, particularly with regard to plastic waste. Plastic waste is presumably not used preferentially for nest-building, but in the context of available nesting material in the waters surrounding the breeding colony. Therefore the share of garbage parts in nests of certain species of birds is an indicator of the amount of waste in the natural environment in the vicinity of their breeding site.     

不同卸荷速率下岩石强度特性研究

卸荷条件下的岩石强度特性研究对于分析开挖作用下岩石工程的安全性具有极为重要的意义。卸荷试验中影响岩石强度的因素很多,包括岩性、卸荷点的位置、卸荷应力路径和卸荷速率等,以锦屏大理岩为对象,重点研究卸荷速率对强度的影响。提出用屈服接近速率来统一表征加荷和卸荷下的应力增加或减小的速率,通过比较加荷和卸荷条件下的屈服接近速率表明,当围压卸荷速率为常规试验轴向应力加荷速率的0.2～0.3倍时,两种应力路径下接近破坏时的屈服接近速率相当。通过2D弹塑性细胞自动机的数值试验和大理岩的室内卸围压试验来验证理论分析的结果,表明:围压卸荷速率越大,岩样的强度就越高;当卸荷速率为常规轴向加荷速率的0.2～0.3倍时,卸荷和加荷路径下的强度相当。从而得出结论:对于各种卸荷应力路径,如果卸荷点处于弹性范围内,当接近破坏时的屈服接近速率一定时,应力路径对强度的影响不明显。     

地球动力系统、地球物质系统与滑坡生成机理研究

我国是地质灾害非常严重的国家之一,长期以来,地质灾害影响了社会的经济建设和发展。由于它具有渐变性、突发性等特点,给国家和人民的生命财产带来了巨大的损失。本文从地球动力系统、地球物质系统的角度对滑坡生成机理进行了研究,并以绵阳市北川县为例,对滑坡形成的主要影响因素进行了探讨。     

山西平顺地区矽卡岩型铁矿床地质特征及成矿物质来源探讨

山西平顺地区矽卡岩型铁矿主要产于燕山期中性侵入岩与中奥陶统碳酸岩地层接触带及其附近。矿化蚀变带明显,钠长石化是重要的找矿标志。北落峡ZK28-7钻孔岩芯样地球化学特征、黄铁矿(206Pb/204Pb=17.741～18.301,平均值17.993;207Pb/204Pb=15.433～15.551,平均值15.495)以及早期(206Pb/204Pb=17.859～18.474;207Pb/204Pb=15.429～15.431)和晚期侵入岩(206Pb/204Pb=17.959～18.223,平均值18.088;207Pb/204Pb=15.434～15.566,平均值15.536)的Pb同位素组成共同表明,除晚期中性侵入岩是磁铁矿的成矿母岩之外,还包括早期超基性-基性侵入岩,它也是磁铁矿形成的重要成矿母岩之一,其很可能是通过被晚期闪长岩同化交代,大量铁矿质进入了晚期闪长岩,经后期钠化蚀变,铁质析出,形成磁铁矿,间接的提供物质来源。     

东昆仑得尔龙地区华力西期花岗岩地质地球化学特征及构造环境分析

东昆仑得尔龙地区花岗岩体侵位于二叠纪—三叠纪早期,岩石类型为黑云母花岗闪长岩、黑云母二长花岗岩、二云母二长花岗岩。早期次的黑云母花岗闪长岩中含有暗色的镁铁质矿物包体。SiO2含量为65.04%~73.47%,全碱含量为5.29%~8.52%,K2O/Na2O平均值为0.70,Al2O3平均为14.79%;亏损高场强元素Ta,Nb;∑REE平均为142.9×10-6,轻稀土元素相对富集,(La/Yb)N平均为17.15,δEu平均为0.71,表现为弱亏损。研究表明得尔龙地区花岗岩属次铝-过铝(高钾)钙碱性S型花岗岩,形成于后造山环境;岩浆源区的物质是多源的,主要为地壳物质的重熔,其次为幔源岩浆的底侵。     

福建平潭青峰老红砂物源示踪分析

本研究分别在平潭青峰、坛南湾和闽江口琅岐岛采集18个老红砂样品、19个海滩砂样品以及40个河滩砂样品,并对这些样品进行粒度和稀土元素(REE)测量。结果发现老红砂与闽江口琅岐岛河口砂的稀土元素含量特征十分接近;分别对老红砂与闽江河口砂REE数据以及坛南湾海滩砂与闽江口砂(REE)进行了判别函数分析,老红砂的∑REE平均值为84.25μg/g,琅岐岛河口砂的∑REE平均值为89.81μg/g,相似性明显;坛南湾海滩砂的∑REE平均值为16.41μg/g,与闽江河口砂含量差别较大。研究表明:青峰老红砂沉积物主要来源于闽江口河口砂,末次间冰期暖湿气候下闽江输砂量增大,河口外沿岸流增强,大量河砂进入海坛海峡,在强劲的季风搬运下,沉积于平潭岛北部,形成以青峰为代表的平潭岛北部老红砂;而坛南湾海滩砂代表海洋波浪搬运的泥沙,不是老红砂的物源。