海洋浮游藻色素分析和化学分类研究进展

综述了海洋浮游藻色素分析和化学分类研究的最新进展。指出目前以色谱柱串联技术为基础的高分辨高效液相色谱质谱联用已经成为色素分析方法的主要发展趋势。利用此方法对藻类特征色素进行再分析有助于获得对藻类色素分布的新认识。CHEMTAX是在宏观上对浮游藻进行化学分类的良好工具,采用多次运算的方式可以减少其对初始色素比值的依赖,使结果向"真实值"收敛,提高结果的准确性。指出研究以特征色素比值组合为基础的浮游藻精细化学分类方法,以及将以色素分析为基础的浮游藻化学分类应用于了解浮游藻功能类群在生源要素和生物矿物质等的生物地球化学循环过程中的作用是未来的发展趋势。     

柱撑蛭石吸附去除废水中重金属离子的实验研究

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。     

高速铁路和城市蔓延对雾霾污染的异质性影响

为了探寻高铁开通能否抑制雾霾污染以及这种抑制作用在不同城市空间形态下是否存在异质性,本文首先分析了高铁和城市蔓延对雾霾污染的作用机制,在利用LandScan数据测算2003-2016年中国281个地级市城市蔓延指标的基础上,采用动态空间面板模型检验了城市蔓延与雾霾污染的空间动态关系.借助双重差分(DID)模型验证了高铁...     

岩溶地下水集中开采区水质系统预测研究

在岩溶地区，地下水的超强度开采与工业“三废”及生活废弃物不合理的排放，造成了地下水较严重的污染。用动态系统方法建立的地下水污染时间序列递推预测模型，在岩溶地下水环境质量预测与管理方面都具有指导意义。     

Rio Tinto estuary (Spain): 5000 years of pollution

 Mining of massive sulfide deposits in southwestern Spain extending back to the Copper and Bronze Ages has resulted in the pollution of the Rio Tinto fluvial-estuarine complex, the site of Columbus' departure for the New World in 1492. Additional sources of potential pollution include the large industrial complex at Huelva near the lower portion of the estuary. Extensive analysis of surface sediment samples and cores has established that there are no geographic trends in the distribution of the pollutants, which include Cu, Fe, Pb, Zn, Ti, Ba, Cr, V and Co. These data have, however, demonstrated that tidal flux within the estuary carries phosphorus and perhaps other elements from the industrial complex at Huelva to the tidal limit of the system, several kilometers upstream from the discharge site. Radiometric analysis of short cores shows that sedimentation rates over at least the past couple of centuries have been about 0.3 cm/year. These data and that from a single deep core demonstrate that the estuary was polluted from mining activity long before the large-scale operations began in the late nineteenth century. Received: 3 May 1999 · Accepted: 18 October 1999     

MARINE SOURCE ROCKS AND THEIR DEPOSITIONAL CONDITIONS OF MESOZOIC—CENOZOIC IN THE GAMBA—TINGRE BASIN,SOUTH TIBET:ORGANIC GEOCHEMICAL STUDY

MARINE SOURCE ROCKS AND THEIR DEPOSITIONAL CONDITIONS OF MESOZOIC—CENOZOIC IN THE GAMBA—TINGRE BASIN,SOUTH TIBET:ORGANIC GEOCHEMICAL STUDY1　FuJiamo ,ShengGuoying ,XuJiayou,et.al.ApplicationofbiologicalmarkersintheassessmentofpaleoenvironmentsofChinesenon marinesediments[J] .OrganicGeochemistry ,1990 ,16 :76 9～ 779. 2　JenkynsHC .Cretaceousanoxicevents:fromcontinentstooceans[J] .JournaloftheGeologicalSociety ,1980 ,137:171～188. …     

石油污染多孔介质湿润性变异特征

一定程度的石油污染可使多孔介质的湿润性发生变异,导致介质持水能力降低、地下水石油污染、粮食产量品质下降等.采用滴水穿透时间法与酒精溶液入渗法,测定了亚粘土和粗砂在不同柴油、机油含量下的斥水水平,确定了亚粘土、粗砂由亲水表面变为疏水表面的临界含油量.结果表明,亚粘土、粗砂湿润性变异的临界机油含量分别约为7%、0.5%,粗砂湿润性变异的临界柴油含量约为14%,而柴油污染对亚粘土湿润性的影响不显著.另外,当石油污染多孔介质的含水量达到某一临界值时,湿润性将再次发生反转,由疏水表面变回亲水表面.测得机油、柴油污染粗砂的临界含水量约在0.2%~1%之间,机油污染亚粘土的临界含水量在数值上与其含油量近似相等.      

Salinisation des nappes côtières : cas de la nappe nord du Sahel de Sfax,Tunisie

The intensive agricultural and economic activities induce the increase of the risk of groundwater quality degradation through high groundwater pumping rates. The salinization and contamination are the main sources of this pollution, especially in coastal aquifers. The explanation of the origin of salinity for the shallow aquifer of Northern Sahel of Sfax was analysed by a chemical study of the groundwater main compounds. The partitioning of groundwaters into homogenous groups is undertaken by graphical techniques, including a Stiff pattern diagram, an expanded Durov diagram and several binary diagrams. The study indicates the presence of various salinization processes. In the recharge area, salinization is the result of dissolution/precipitation of the aquifer formation material (group I). The irrigation water return and the intensive pumping have been identified as major sources of salinization in the south by direct cation exchange and mixing reactions (groups II and III). The anomaly of high groundwater salinity observed near the Hazeg zone was explained by the presence of a seawater intrusion in this area. This hypothesis is related to the high chloride concentration, to the presence of inverse cation exchange reactions (group IV), and to the piezometric level inferior to sea level. To cite this article: R. Trabelsi et al., C. R. Geoscience 337 (2005).     

三姑泉域水环境质量评价及水污染控制对策

为确保三姑泉域水资源的可持续开发利用,采用常规方法对泉域水环境质量进行了评价。结果表明:三姑泉域的地表水和地下水已不同程度遭受污染,水环境的污染与煤矿开采以及工业废水和生活污水的不合理排放有关。结合当地实际提出水污染控制对策。研究成果为三姑泉域水资源管理和保护提供科学依据。     

能源基地地下水污染及防治措施

能源基地地下水已受到不同程度的污染,随着基地大规模开发建设,地下水污染将更加严重。对基地一些地区地下水的污染特征、污染途径和污染源进行了分析研究,并在此基础上提出了相应的防治措施和建议。