新疆彩霞山铅锌矿床硫、碳、氢、氧同位素地球化学

文章通过对彩霞山铅锌矿床硫、碳、氢、氧同位素的研究,探讨了矿床成矿流体来源及演化,揭示了成矿作用过程中的某些重要信息.初步认为矿石中的硫主要来自同化了海水硫酸盐的岩浆硫,同时有少量生物还原硫参与;碳、氧同位素组成指示碳来源于壳幔混合.成矿流体以建造水为主,早期有岩浆水参与.     

铵(氮)在岩石和矿物中地球化学行为研究进展

地壳中的氮大都以NH4 储存在矿物中.由于成岩时含氮有机物质的分解作用,氮广泛分布在沉积岩和低级变质岩中;在岩浆岩和变质岩中,氮主要以NH4 存在于含钾硅酸盐(长石和云母类)中;岩浆岩的δ(15N)值和氮浓度明显地不同于沉积物和变沉积岩,主要是由于有机物的缺乏.具有明显铵含量的火成岩主要是含钾矿物的深成岩.因而NH4 可以作为一个"示踪元素"而用于成矿作用等方面的研究.文章还提出了未来的研究方向.     

Organic Carbon Isotopic Evolution during the Ediacaran-Cambrian Transition Interval in Eastern Guizhou, South China： Paleoenvironmental and Stratigraphic Implications

Secular variations of carbon isotopic composition of organic carbon can be used in the study of global environmental variation, the carbon cycle, stratigraphic delimitation, and biological evolution, etc. Organic carbon isotopic analysis of the Nangao and Zhalagou sections in eastern Guizhou reveals a negative excursion near the Precambrian-Cambrian boundary that correlates with a distinct carbonate carbon isotopic negative excursion at this boundary globally. Our results also demonstrate that several alternating positive and negative shifts occur in the Meishucunian, and an obvious negative anomaly appears at the boundary between the Meishucunian and Qiongzhusian. The isotope values are stable in the middle and lower parts but became more positive in the upper part of the Qiongzhusian. Evolution of organic carbon isotopes from the two sections in the deepwater facies can be well correlated with that of the carbonate carbon isotopes from the section in the shallow water facies. Integrated with other stratigraphic tools, we can precisely establish a lower Cambrian stratigraphic framework from shallow shelf to deep basin of the Yangtze Platform.     

Provenance of Precambrian Fe- and Al-rich Metapelites in the Yenisey Ridge and Kuznetsk Alatau, Siberia： Geochemical Signatures

Major, trace and rare earth element contents of Fe- and Al-rich metapelites from the Korda （Yenisey Ridge） and Amar （Kuznetsk Alatau） formations were determined to examine the nature, origin and evolution of their protoliths. Results indicate that these rocks are the redeposited and metamorphosed products of Precambrian kaolinitic weathering crusts, while the geochemical distinctions between the studied metapelites are determined by different weathering conditions in the source area and tectonic settings. The protolith of the Korda Formation metapelites was produced by erosion products of the post-Archean granitoid rocks, which accumulated under humid climate conditions in shallow-water basins along the continental margin. The geochemical characteristics of the deeper primary deposits of the Amar Formation suggest that volcanogenic material of mafic composition derived from an island-arc environment had a major role in supplying the erosion zone. These results agree with lithofacies data and with the geodynamic reconstruction of the evolution of the Yenisey Ridge and Kuznetsk Alatau during the Mesoproterozoic and Neoproterozoic, respectively. It was shown that REEs had limited mobility during contact metamorphism. The coherent mobility of REEs during collisional metamorphism may be attributed both to mineral reactions responsible for modal changes and to local chemical heterogeneity inherited from the initial protolith.     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

中国海洋生态效率时空格局演变及影响要素分析

随着海洋环境问题的日益凸显,海洋经济与海洋生态保护如何协调发展已成为学术界的研究热点。本文使用C2NLS方法对2003-2016年中国沿海11个省区市海洋生态效率进行测度,使用SDE方法对海洋生态效率的时空演进特征进行分析,最后对影响海洋生态效率的因素进行实证探索。结果表明：(1)海洋生态效率整体呈上升趋势,但地区差距并未显著缩小,海洋生态效率的地区分布出现极化趋势。(2)海洋生态效率重心表现出西南向移动特征,东北-西南向的空间格局更加明显。(3)环境规制、海洋科技和对外开放可以有效提高海洋生态效率水平;产业结构效应不显著,可能是由于高污染行业同时具有高产出与高排放的特征导致;区位因素效应不显著,海洋生态效率与地区发展水平之间没有明显的二次型关系,与中国海洋经济整体发展仍处于“倒U”型曲线的上升通道情况相符,部分印证了“环境的库兹涅茨”曲线理论。     

内蒙古迪彦钦阿木斑岩钼矿床绿泥石和绿帘石矿物化学特征及其成矿指示意义

迪彦钦阿木矿床位于大兴安岭中段二连浩特-东乌旗多金属成矿带,是区内新近发现的一个超大型斑岩钼矿床.为了厘清蚀变矿物的成分对找矿的指示意义,文章运用电子探针和LA-ICP-MS对迪彦钦阿木矿床青磐岩化带绿帘石亚带的绿泥石和绿帘石的主微量元素成分进行了分析.电子探针数据表明,这些绿泥石属于铁斜绿泥石(辉绿泥石).绿泥石四面...     

Spatial variation and driving mechanism of soil organic carbon components in the alluvial/sedimentary zone of the Yellow River

Alluviation and sedimentation of the Yellow River are important factors influencing the surface soil structure and organic carbon content in its lower reaches. Selecting Kaifeng and Zhoukou as typical cases of the Yellow River flooding area, the field survey, soil sample collection, laboratory experiment and Geographic Information System(GIS) spatial analysis methods were applied to study the spatial distribution characteristics and change mechanism of organic carbon components at different soil depths. The results revealed that the soil total organic carbon(TOC), active organic carbon(AOC) and nonactive organic carbon(NOC) contents ranged from 0.05–30.03 g/kg, 0.01–8.86 g/kg and 0.02–23.36 g/kg, respectively. The TOC, AOC and NOC contents in the surface soil layer were obviously higher than those in the lower soil layer, and the sequence of the content and change range within a single layer was TOCNOCAOC. Geostatistical analysis indicated that the TOC, AOC and NOC contents were commonly influenced by structural and random factors, and the influence magnitudes of these two factors were similar. The overall spatial trends of TOC, AOC and NOC remained relatively consistent from the 0–20 cm layer to the 20–100 cm layer, and the transition between high-and low-value areas was obvious, while the spatial variance was high. The AOC and NOC contents and spatial distribution better reflected TOC spatial variation and carbon accumulation areas. The distribution and depth of the sediment, agricultural land-use type, cropping system, fertilization method, tillage process and cultivation history were the main factors impacting the spatial variation in the soil organic carbon(SOC) components. Therefore, increasing the organic matter content, straw return, applying organic manure, adding exogenous particulate matter and conservation tillage are effective measures to improve the soil quality and attain sustainable agricultural development in the alluvial/sedimentary zone of the Yellow River.     

扬子板块西缘攀西地区白草矿区黄铁矿标型元素特征及其指示意义

黄铁矿是重要的金属硫化物矿物,在多种矿床中均有产出,其标型特征对矿床成因、矿体空间分布等具有重要的指示意义.以扬子板块西缘攀西地区白草矿区黄铁矿为研究对象,利用矿相学、电子探针等分析方法来对比研究浸染状、致密块状、斑杂状、网脉状矿石中黄铁矿的标型元素特征.结果表明:白草矿区黄铁矿Fe、S平均含量(质量分数,下同)分别为...     

The Weixi High-silica Granitoids in the Central Sanjiang Orogenic Belt, Southwest China: Implications for Growth of the Continental Crust

High-silica granitoids record the formation and evolution of the continental crust. A new intrusive complex has been recognized among silicic volcanic rocks of the Weixi arc, Southwest China. The intrusions consist of granites, granitic porphyries, and granodiorites. Zircon U-Pb age data indicate that the Weixi granitoids formed at 248–240 Ma and were coeval with silicic volcanic rocks of the Weixi arc. The Weixi granitoids are enriched in Rb, Th, and U, depleted in Ba, Sr, Nb, Ta, and Ti, and have high light/heavy rare earth element ratios and slightly negative Eu anomalies. The Weixi granitoids have negative εNd(t) values (?9.8 to ?7.8) and negative zircon εHf(t) values (?12.02 to ?5.11). The geochemical and isotopic features suggest the Weixi granitoids were derived by partial melting of ancient crustal material. The Weixi granitoids and silicic volcanic rocks were derived from the same magma by crystal accumulation and melt extraction, respectively, and they record the formation of a continental arc in the central Sanjiang orogenic belt.