河北东坪金矿地质地球化学特征

东坪金矿位于河北省崇礼区,大地构造处于华北地台北缘,燕辽沉降带与内蒙地轴结合处南侧,距尚义-崇礼-赤城深大断裂10km。区内出露地层主要为太古界桑干群变质岩系,岩性以片麻岩为主。区内断裂构造较发育,主要有EW向,NW向和NE向,其中以EW向的最为发育。 区内岩浆岩也比较发育,沿尚义-崇礼-赤城深大断裂分布,主要有小张家口超基性岩、水泉沟碱性杂岩和上水泉花岗岩。水泉沟碱性杂岩体呈EW向展布,向南北两侧倾斜,主要岩性为碱性长石正长岩、辉石角闪碱性长石正长岩、辉石角闪正长岩和角闪碱性长石正长岩等。     

广西官村岩溶溪流中生物地球化学控制的DIC和NO3-昼夜变化研究

为了解岩溶区控制溪流中溶解无机碳(DIC)和NO_3~-昼夜变化的生物地球化学过程以及DIC和NO_3~-日变化量,于2014-07-22~2014-07-24期间,在广西壮族自治区融安县官村溪流中包括地下河出口(CK)和下游雷崖村(LY)设置两个监测点同时对水体物理化学参数以及C、N同位素(δ~(13) CDIC、δ~(15) N-NO_3~-和δ~(18) O-NO_3~-)展开了为期2d的高分辨率昼夜监测采样工作。结果发现CK点各物理化学参数没有表现出昼夜变化,但是LY点Ca2+、DIC以及PCO2表现出明显的昼夜变化规律,即白天下降夜间上升且与DO和pH表现出明显的负相关关系。相对于CK点,在白天水生光合生物光合作用导致LY点DIC下降的同时δ~(13) CDIC上升,而在夜间呼吸作用导致LY点DIC上升的同时δ~(13) CDIC下降且部分时间段要低于CK点δ~(13) CDIC值。溪流中的NH4+在监测期间基本上都在下降而NO_3~-离子在夜间和上午时间段都在上升,δ~(15) N-NO_3~-却表现出下降的趋势,且比较接近δ~(15) N-NO_3~-初始值,而NO_3~-离子在下午时间段出现下降的趋势。结果表明溪流中DIC昼夜变化主要受到水生植物的光合作用和呼吸作用控制,且通过质量平衡方程计算得知溪流中由于光合作用吸收无机碳而转为有机碳的量为0.94kgC/d,这部分有机碳可以形成相对长期稳定的自然C汇。溪流在夜间和上午时间段发生了N的硝化作用,增长量为2.08kgN/d,但在下午时间段(12:00~18:00)发生了N的同化作用,损失量为0.42kgN/d。溪流输出的NO_3~--N的量为1.66kgN/d,表明在富碳、富钙的岩溶溪流中,有利于水生光合生物的生长,促进N的同化作用的发生,从而减少溪流输出NO_3~--N的量,说明岩溶区溪流N的生物地球化学过程可能在昼夜尺度上改变水质。     

Re-parameterization of a quasi-analytical algorithm for colored dissolved organic matter dominant inland waters

Quasi-Analytical Algorithms (QAAs) are based on radiative transfer equations and have been used to derive inherent optical properties (IOPs) from the above surface remote sensing reflectance (R_rs) in aquatic systems in which phytoplankton is the dominant optically active constituents (OACs). However, Colored Dissolved Organic Matter (CDOM) and Non Algal Particles (NAP) can also be dominant OACs in water bodies and till now a QAA has not been parametrized for these aquatic systems. In this study, we compared the performance of three widely used QAAs in two CDOM dominated aquatic systems which were unsuccessful in retrieving the spectral shape of IOPS and produced minimum errors of 350% for the total absorption coefficient (a), 39% for colored dissolved matter absorption coefficient (a_CDM) and 7566.33% for phytoplankton absorption coefficient (a_phy). We re-parameterized a QAA for CDOM dominated (hereafter QAA_CDOM) waters which was able to not only achieve the spectral shape of the OACs absorption coefficients but also brought the error magnitude to a reasonable level. The average errors found for the 400–750 nm range were 30.71 and 14.51 for a, 14.89 and 8.95 for a_CDM and 25.90 and 29.76 for a_phy in Funil and Itumbiara Reservoirs, Brazil respectively. Although QAA_CDOM showed significant promise for retrieving IOPs in CDOM dominated waters, results indicated further tuning is needed in the estimation of a(λ) and a_phy(λ). Successful retrieval of the absorption coefficients by QAA_CDOM would be very useful in monitoring the spatio-temporal variability of IOPS in CDOM dominated waters.     

重力场对飞行器制导的影响及海洋重力测线布设

重点围绕远程飞行器飞行轨道控制保障需求,开展了空中扰动引力计算和地面重力异常测量精度指标及海洋重力测量测线布设方案的分析与论证。首先通过解析和简化飞行器导航误差解表达式,定量估计了地球重力场对远程飞行器飞行轨迹的影响,并以一定量值的落点偏差为限定指标,研究论证了空中扰动引力的计算精度要求。在此基础上,通过对地面重力异常截断误差及数据传播误差的估计和分析,研究确定了地面/海面网格平均重力异常的观测分辨率和计算精度指标。以此为依据,提出了相对应的海洋重力测量测线布设方案,并通过数值计算验证了所提方案的合理性和有效性。     

Geochemistry of Paraná-Etendeka basalts from Misiones,Argentina: Some new insights into the petrogenesis of high-Ti continental flood basalts

The Early Cretaceous (∼135–131 Ma) Paraná-Etendeka continental flood basalts, preserved in bulk in the Paraná basin of southern Brazil and vicinity, have been divided into low-Ti and high-Ti types that govern the southern and northern halves of the basin, respectively. We have examined a new sample set from the southern margin of the northern high-Ti segment of Paraná basalts in Misiones, northeastern Argentina. These basalts are strongly to moderately enriched in TiO₂ (2–4 wt.%), have relatively high Ti/Y (300–500), low MgO (3.5–6.5 wt.%), and high Fe (FeO(tot) 12–14 wt.%) and belong to the Pitanga and Paranapanema magma types of Peate et al. (1992). Nd and Sr isotope compositions are quite unvarying with ε_Nd (at 133 Ma) values of −4.6 to −3.6 and initial ⁸⁷Sr/⁸⁶Sr of 0.7054–0.7059 and show no variation with fractionation. Compared to high-Ti lavas in the central and northern parts of the Paraná high-Ti basalt segment, the lavas from Misiones are similar to those in the northeastern magin of the basin but less radiogenic in initial Nd isotope composition than those in the central part. This variation probably reflects mixed EM1-EM2 source components in the sublithospheric mantle. A polybaric melt model of a sublithospheric mantle source at the garnet lherzolite-spinel lherzolite transition is compatible with the observed Ti budget of the Pitanga and Paranapanema lavas, regardless of the Nd isotope composition of their purported source.     

甘肃北山造山带南缘白石坝一带南岭型花岗岩地球化学特征与锡成矿作用浅析

白石坝一带花岗岩具高硅低铝、富钾贫钠、非常低Sr(24.9×10~(-6)~82.9×10~(-6))高Yb(2.61×10~(-6)~5.74×10~(-6))的南岭型花岗岩特征,A/CNK介于0.91~0.98之间,σ在1.92~2.22之间。明显富集Rb、Th、K等大离子不相容元素,亏损Ba、Sr、P、Ti等元素,并具有弱Nb亏损,稀土元素分布曲线呈明显的"燕式"型,其形成可能来源于下地壳底部部分熔融与地壳物质发生混合形成的产物,源区深度较浅、水含量低和氧逸度低,处于还原状态下的伸展构造背景,有利于锡矿的萃取和富集,研究其区域构造-岩浆演化,对指导区域矿产预测和评价均具有重要的理论和实际意义。     

直线型海洋重力仪负漂移原因分析及处理

分析了直线型KSS31M(SN035)海洋重力仪短期负漂移现象的原因、采取的处理措施和经验总结,认为在减震措施不足的情况下,重力仪长期经受震动,而频繁的搬动会使重力仪弹性系统中的金属弹簧产生较大的弹性疲劳,这种影响在短时间内无法完全消除,由此可能导致月漂移超标;陀螺稳定平台轴因承受震动磨损较严重,轴承间隙变大,导致安装在平台之上的重力传感器经过抛物线测试之后不能完全垂直指向地心,重力在水平方向存在一个微小的分量,最终导致重力读数偏小,即短期负漂移;重力基点环境的变化等对漂移也有一定的影响。建议在搬动重力仪后将仪器保持足够长时间的恒温后再开机,密切监测一段时间,以确保仪器处于良好的工作状态。     

黑河新生地区中侏罗世花岗质岩石锆石U-Pb年龄、地球化学特征及岩石成因

黑河新生地区西古兰河以北二长花岗岩的LA-ICP-MS锆石U-Pb同位素测试结果表明,其形成时代为中侏罗世((163.8±1)Ma)。这些中侏罗世二长花岗岩属于弱过铝质高钾钙碱性系列的Ⅰ型花岗岩,明显富集大离子亲石元素(Rb、Ba、Th)和亏损高场强元素(Zr、Hf、Nb、Ta),元素Sr具有明显的负异常,表明其原始岩浆起源于地壳火成岩的部分熔融。结合区域资料同时代火成岩的组合特征和古太平洋板块的构造演化,认为该二长花岗岩形成于活动大陆边缘,而其形成的地球动力学背景可能为古太平洋板块向欧亚板块俯冲造山后的伸展环境。     

大兴安岭北部新林石英二长岩-花岗岩的地球化学特征及其成因

对额尔古纳地块东南部新林镇附近的侵入岩进行了锆石U-Pb年龄测定、Lu-Hf同位素和岩石地球化学研究。结果表明,岩体形成于141.1~123.8 Ma,是早白垩世岩浆活动的产物。新林石英二长岩-花岗岩高硅较富铝贫镁,属于准铝质、高钾钙碱性系列;具有中等-弱负Eu异常(δEu=0.53~0.72),轻重稀土分异比较明显[(La/Yb)_N=12.42~25.38];相对富集大离子亲石元素Rb、Th、U和LREE,高场强元素Ti、Nb、Ta、P和HREE表现出亏损。新林石英二长岩-花岗岩具有高Sr、低Yb及低Y的特征,且相对富K,属于C型埃达克岩,形成于加厚下地壳的部分熔融。Lu-Hf同位素研究显示其ε_(Hf)(t)为2.1~6.2,二阶段模式年龄(T_(DM2))为1025~786 Ma,认为其岩浆源区为新元古代增生的地壳物质。