四种前处理方法对电感耦合等离子体质谱测定植物样品中27种微量元素的影响

采用HNO₃-HClO₄-HF常压消解、HNO₃-H₂O₂-HF高压密闭消解、HNO₃-H₂O₂微波消解,干法灰化后残渣用HNO₃-HF-HClO₄溶解等四种方法对植物样品进行前处理,使用电感耦合等离子体质谱(ICP-MS)对植物样品中的27种元素进行定量分析,探讨了不同前处理方法对ICP-MS测定植物样品中微量元素的影响。分析结果表明: HNO₃-HClO₄-HF常压消解使用大量试剂,污染环境,造成空白值高;在常压体系中HClO₄的加入能提高样品的消解效率,但赶酸不完全,会造成复合离子对钒和砷的干扰;干法灰化过程中某些元素(硼、汞等)会损失;常压消解和高压密闭消解中加入HF能有效地提高铍、稀土、钇、钛、锑、铀等元素的回收率,但在蒸干赶HF的过程中,会造成硼和汞的损失,并且钢套的生锈会造成铬、镍空白值高。尽管没有一种方法能适用于所有元素的分析,但相比较而言,HNO₃-H₂O₂微波消解体系操作简单,大部分元素(除铍、钛、锑、铋、稀土)能得到满意的结果,精密度(RSD)均小于10%(n=10),相对误差(RE)为-4.6%~13.6%。     

中国东北、韩国东南和日本西南部早白垩世非海相与海相地层对比,非海相软体动物的生物年代学和古地理意义

根据非海相与海相,特别是共同的海相和非海相软体动物化石的对比,并结合放射性同位素测年,中国东北黑龙江东部和辽宁西部,韩国东南部庆尚盆地,日本西南部内带岐阜县北部牧户/庄川地区和外带四国德岛和物部地区早白垩世地层得到了对比,产自这些地层的非海相软体动物的时代也因此受到了约束。著名的中国东北含煤地层龙爪沟和鸡西群,盛产热河生物群/动物群的热河群的时代均为欧特里沃期/巴列姆期阿普特期,它们的上覆地层桦山群和孙家湾组为阿尔必期。韩国西南部新洞群和除金洞组以外的河阳群为阿普特期阿尔必期,不整合于新洞群之下的卯谷组主要为欧特里沃期。日本西南部内带的牧户/庄川地区的手取群和外带德岛和物部地区的物部川群均为欧特里沃期阿尔必期。Cuniopsis kihongi,Nakamuranaia leei,Koreanaia cheongi和Trigonioides(Wakinoa)tetoriensis的时代为欧特里沃期早巴列姆期。Viviparus onogoensis,Unio ogamigoensis,Myrene(Mesocorbicular)tetoriensis及Tetoria(Tetoria)yokoyami为欧特里沃期阿普特期。Arguniella cf.quadrata,A.cf.ventricosa,Sphaerium(Sphaerium)anderssoni,Probaicalia vitimensis和Pr.gerassimovi为欧特里沃期/巴列姆期阿普特期。Nakamuranaia chingshanensis,Plicatounio(Plicatounio)multiplicatus,Sphaerium(Sphaerium)coreanicum和Micromelania?katoensis为阿普特期阿尔必期。Nippononaia sinensis,Nip.tetoriensis,Nip.ryosekiana和Trigo-nioides(Wakinoa)wakinoensis是阿普特期的标志。Trigonioides(Trigonioides)quadratus,T.(T.)heilongjiangensis,Plicatounio(Plicatounio)naktongensis,Unio longus与Sphaerium(Sphaerium)chintaoense为晚阿普特期阿尔必期或阿尔必期的标志化石。我国东北、韩国东南和日本西南部非海相,特别是淡水软体动物接近的相似性表明这三地区在早白垩世时相连,并处于同一水系。但是,在欧特里沃期阿尔必期期间,这一陆块的东部,即频临古太平洋的日本西南部的外带因地势低而多被海水覆盖,在牧户/庄川和黑龙江东部存有遭受海侵的浅而窄的海湾,凡兰吟期,特别是欧特里沃期/巴列姆期之前,中国东北韩国东南部日本西南部陆块为受造山运动引起的隆起和沉降活动影响的高低不平的高原,经受了广泛而长期的剥蚀。多数含有包括熔岩和凝灰岩在内的火山岩,并与北东北北东方向的断裂带近于平行分布的非海相白垩纪盆地直至欧特里沃期/早巴列期(有些地区可能稍早(凡兰吟期))(134～126Ma),即华北克拉通破坏的高峰期(130～120Ma)才形成。这一现象表明,这些盆地受断裂,特别是伴随有强烈火山喷发和时而局部海侵的沿着古太平洋西北缘和郯庐断裂带的构造运动的控制。     

高压密闭消解-电感耦合等离子体质谱法测定海洋沉积物中稀土元素

样品用HNO3-HF高压密闭消解,电感耦合等离子体质谱测定海洋沉积物中15种稀土元素。研究了消解方法、酸体系和质谱干扰对稀土元素测定的影响。结果表明,相比于电热板消解和微波消解,高压密闭消解具有酸用量少、消解完全、消解过程损失少等优点;HNO3-HF体系能有效地分解海洋沉积物样品;利用干扰离子校正方程,能有效地校正Ba和轻稀土元素所形成的多原子离子干扰。15种稀土元素的方法检出限为3～15 ng/g。使用水系沉积物标准物质GBW 07309和GBW 07311、海底沉积物标准物质GBW 07313进行验证,测定值与标准值基本吻合,相对标准偏差和相对误差均低于5%。方法用于长江口沉积物样品的测定,精密度(RSD,n=6)小于5%,加标回收率为95.8%～104%。该方法检出限低,精密度和准确度高,适用于大批海洋沉积物样品的分析。     

海底可控源电磁采集站的低时漂技术研究

海洋可控源电磁方法要求位于海底的多台可控源电磁采集站对微弱的电磁信号进行长期同步连续观测,对各台采集站的时间一致性严格要求。为解决海底无法进行GPS授时这一技术难题,提出了以高稳OCXO(恒温晶体振荡器)与精确授时GPS结合为硬件基础,形成通过下水前对钟、出水后对钟以及时漂补偿等组成的低时漂技术。通过室内及海洋试验,实现了多台海底可控源电磁采集站同步观测,显著降低数据同步误差。     

Role of Storm in Ramgarh and West Bokaro Coalfields and Its Implication in Adjacent Peninsular Gondwana Coalfields, India

The Permian Gondwana sediments in the Damodar-Koel Valley, Rajmahal and Deoghar basins were deposited on a northwest palaeoslope in broad valleys within uplands (e.g. Aravalli-Vindhyan, Chattisgarh, Chotanagpur and Santhal Parganas upland). The main winds during Permian Period were mostly the westerly winds coming from the northwest low pressure belt in the Tethys, which found no barrier between the Vindhyan and Santhal Parganas uplands and then changing its direction, moving towards east. Frequent storm activity also took place from the northwest Tethyan low pressure belt and followed the same path of wind. Possibly there was a barrier in the form of a dense rain forest or elevated land at the place of East Bokaro coalfield and its adjoining southern part, which acted as a deterrent and minimized the effect of storm towards further east of the Damodar Valley. Intense tropical hurricanes for the generation of storm generated bedforms, cannot be ruled out, which probably, in some cases, causes marine inundation/flooding deep into the landmass and also mass (?) uprooting of trees.     

祁连山南麓退耕地主要植物群落植冠层的截留性能

退耕地人工群落植冠层的截留能力,是群落生态效益的重要组成部分,这一研究不仅可以掌握退耕还林还草工程作用的机理,还可以更好地指导工程实践,促进工程建设步伐。通过“简易吸水法”,可以快速掌握退耕地植冠层的最大截留潜力。青海省大通县退耕较早、平均年龄约10a以上的青海云杉、华北落叶松等几种人工群落,它们的林冠截留量较高,平均达1．93mm,为当地3种截留量最高、林龄50a之上天然群落的61％。青海云杉、华北落叶松、白桦、青杨、中国沙棘等退耕地人工群落的截留量,基本上显示出与林龄之间呈线性或Cubic、Quadratic正相关关系。在植物群落分层截留、消化吸收降雨的这一空间垂直序列中,植冠层截留量虽然较低,平均仅1．29mm(0．25～2．38mm),但植冠层的主要作用还在于减轻、缓冲雨水直接打击地面,改变降水的侵蚀性危害,而这些作用要远远高于截留量自身的区区数量。     

船舶柴油机余热利用系统性能优化

【目的】研究提高船舶主机燃料的综合利用率。【方法】结合MAN 6S50ME型船舶柴油机的余热能量特性和循环热力过程特点,分别建立基本循环、缸套水预热循环和回热循环等三种船舶余热利用有机朗肯循环系统模型,对三种余热利用系统的热力性能与经济性能进行计算和分析。【结果与结论】在三种循环系统中,缸套水预热循环的综合性能更具优势,在循环压力为2000 kPa时,系统的综合性能达到最优,循环净功为555.35 kW,热效率可达18.27%,循环发电净收益提高39.64%。研究结果可为船舶柴油机余热利用系统的设计和优化提供一定的理论指导。     

Imaging spectroscopy in soil-water based site suitability assessment for artificial regeneration to Scots pine

In a humid northern boreal climate, the success rate of artificial regeneration to Scots pine (Pinus sylvestris L.) can be improved by including a soil water content (SWC) based assessment of site suitability in the reforestation planning process. This paper introduces an application of airborne visible-near-infrared imaging spectroscopic data to identify suitable subregions of forest compartments for the low SWC-tolerant Scots pine. The spatial patterns of understorey plant species communities, recorded by the AISA (Airborne Imaging Spectrometer for Applications) sensor, were demonstrated to be dependant on the underlying SWC. According to the nonmetric multidimensional scaling and correlation results twelve understorey species were found to be most abundant on sites with high soil SWCs. The abundance of bare soil, rocks and abundance of more than ten species indicated low soil SWCs. The spatial patterns of understorey are attributed to time-stability of the underlying SWC patterns. A supervised artificial neural network (radial basis functional link network, probabilistic neural network) approach was taken to classify AISA imaging spectrometer data with dielectric (as a measure volumetric SWC) ground referencing into regimes suitable and unsuitable for Scots pine. The accuracy assessment with receiver operating characteristics curves demonstrated a maximum of 74.1% area under the curve values which indicated moderate success of the NN modelling. The results signified the importance of the training set’s quality, adequate quantity (>2.43 points/ha) and NN algorithm selection over the NN algorithm training parameter optimization to perfection. This methodology for the analysis of site suitability of Scots pine can be recommended, especially when artificial regeneration of former mixed wood Norway spruce (Picea abies L. Karst) - downy birch (Betula pubenscens Ehrh.) stands is being considered, so that artificially regenerated areas to Scots pine can be optimized for forestry purposes.     

基于GIS的海洋风浪信息服务系统的设计与实现

风浪要素是海洋环境信息中影响舰船航行安全与人员作业的首要因素.基于GIS技术对海洋风浪信息服务系统进行了设计,实现了台风信息与海浪信息的可视化表达.该系统可为舰船航行中的海洋水文气象保障提供必要的辅助决策,也可为同类GIS系统的设计与开发提供一些参考.     

Major human Hepatitis A virus genotype in Hong Kong marine waters and detection by real-time PCR

Marine waters from seven sites around Hong Kong with varying levels of sewage pollution were analyzed for Hepatitis A virus (HAV) by PCR cloning and DNA sequencing of the highly variable VP1/2A junction of the HAV genome. Phylogenetic analysis of 10 PCR clones from each of the HAV-positive marine sites indicated that human HAV genotype IB is the most widely distributed type in Hong Kong waters. A sensitive and quantitative TaqMan-based PCR method targeting the 5′-noncoding region (5′-NCR) of HAV was used to quantify HAV particles in marine water samples along with the total Escherichiacoli counts being enumerated on TBX medium for comparison. Our results showed that no correlation of any significance between HAV and E. coli counts was observed which underscores the inadequacy in using E. coli as a sanitary standard to predict the levels of HAV in marine waters.