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111.
岩土介质中锰的吸附、解吸行为研究 总被引:1,自引:0,他引:1
通过吸附、物理解吸及化学解吸试验,模拟地下水污染特征,进而研究地下水重金属污染作用机理.结果表明,供试土壤对锰具有较强吸附能力,其吸附以化学吸附为主,占总吸附量的 90.94%.供试土壤对其吸持能力较强,不易于其迁移,但很容易造成土壤富集,通过植被进入生态系统,危害人体健康. 相似文献
112.
滇东南中三叠统法郎组是重要的含锰地层,前人对其沉积环境的认识却存在着深水浊流沉积和浅水潮坪沉积的争议。本文通过对建水-开远地区典型剖面的研究,认为法郎组为浊积扇沉积。法郎组底部为碳酸盐滑塌沉积、碎眉流沉积与泥岩粉砂岩互层,中上部逐渐由外扇渐变为中扇辫状水道和辫状水道间沉积,顶部为内扇补给水道和溢岸沉积。相对海水深度总体表现为在拉丁早期逐渐加深,到拉丁中晚期有逐渐变浅。锰矿层主要发育在底部的碎屑流沉积中,其彤成可能与拉丁早期相对水深的增高有关。 相似文献
113.
印尼千岛锰矿贮存于白垩系上统砂岩、泥岩中,呈层状、似层状产出,具有层控特征,局部遭受断裂构造破坏。通过对矿区成矿地质条件分析,初步认为矿床属于海相碎屑沉积类型锰矿床,具有较好的找矿远景。 相似文献
114.
115.
铁锰氧化物对苯酚氧化降解的实验研究 总被引:1,自引:0,他引:1
为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究.土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿.结果表明:苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的... 相似文献
116.
D. Hill 《Australian Journal of Earth Sciences》2013,60(2):203-204
Geological sections are still best drawn at natural scale. Sections with vertical exaggerations are rarely drawn correctly, and even when computed carefully give a false notion of the structural features. Many schematic sections which are not drawn to scale and are supposed to explain a proposed new tectonic interpretation give such a distorted and frequently absurd picture of the structural features that they cannot be regarded as valid. 相似文献
117.
118.
在对滇东南区域地质及锰矿研究成果综合分析的基础上, 以中三叠世拉丁期含锰建造的沉积相研究为基础, 把滇东南的法郎组中的锰矿总结为碎屑岩建造中的斗南式锰矿和碳酸盐岩建造中的白显式锰矿两类, 从解析典型锰矿床的沉积格局入手, 研究了中三叠世拉丁期典型矿床的岩相古地理特征。斗南锰矿形成于礁(滩)后泻湖的滨浅海碎屑岩建造相区、台地碳酸盐建造相区和斜坡碎屑岩建造相区中, 在斜坡碎屑岩建造相内多具有异地堆积的重力流沉积。白显锰矿形成于局限台地水体较为滞流的泻湖相-潮坪相中。在不同沉积格架下, 海水物理化学条件、水动力环境、生物作用和同生断裂活动是影响聚锰作用的重要因素。 相似文献
119.
O. Klemm W. R. Stockwell H. Schlager M. Krautstrunk 《Journal of Atmospheric Chemistry》2000,35(1):1-18
The ozone forming potential of VOCs and NOx for plumes observed from several cities and a power plant in eastern Germany was investigated. A closed box model with a gas phase photochemical reaction mechanism was employed to simulate several scenarios based upon aircraft observations. In several of the scenarios, the initial concentrations of NOx, VOCs, and SO2, were reduced to study the factors limiting the O3 production. Ozone production was limited by the initial VOC concentrations for all of the simulated plumes. Higher O3 concentrations were produced with reduced initial NOx. In one sample with high SO2 mixing ratios (>100 ppb), SO2 was also identified as a significant contributor to the production of O3. 相似文献
120.
Experimental Study of Gold and Platinum Solubility in a Complex Fluid under Hydrothermal Conditions 总被引:2,自引:0,他引:2
Abstract: The solubility of gold was studied in water and aqueous NaCl (1– 5 m) solutions under oxygen and sulfur buffered conditions between 300–500C at a constant pressure 1 kb. Two buffer assemblages HMP and PPM were used. Analysis of the scatter in measured values in log mAu–mNaCl–T frame fixed linear dependence between log mAu and T at any studied iso‐pleth (mNaCl) in the form of log mAu = a. T(C) + b. Coefficients of the equation were calculated for water and NaCl (1, 3, 5 m) solutions. The maximum solubility characterizes the NaCl‐free system in the presence of HMP. In the case, Au solubility increases from (log mAu) –6. 72 to –5. 04 at 300 and 500C, respectively. In the presence of PPM, maximum of Au solubility was obtained for the 5 mNaCl solution. In a similar manner solubility rises from –6. 54 to –5. 77 at 300 and 500C, accordingly. In studied fO2/fS2 area the behavior of Au solubility testified that: (i) – a composite interaction between chloride and hydrosulfide speciation of gold affects its total solubility; (ii) – in addition of NaCl up to about 1. 5 m the solubility decreases, more pronounced in the presence of HMP; (iii) – the contribution of chloride in total Au solubility is more for PPM despite of lower fO2value, than for HMP. The solubility of platinum was studied in the Pt–Cl–S–H2O system between 300 and 500C, 1 kb. PPM solid buffer controlled oxidation state, pH and sulfur activity of solutions (H2O, 1 mNaCl and 0. 1 mHCl). Under the conditions, PtS precipitated from the solutions with increasing temperature and acidity. The PtS solubility in the 0. 1 mHCl solutions lowers slightly in the range of 300–500C from –5. 30 to –5. 60 (in log mPt) that is typical to the hydrosulfide species. It was deduced that reducing media, regulated by the PPM assemblage, suppress activity of chloride species of Pt. More oxidizing conditions were modeled in runs using mixtures of Mn(II), Mn(III) and Mn(IV) oxides to buffer the aqueous‐chloride solutions between 300 and 500C, 1 kb. It was found that MnO tends to oxidize at T below 400C forming intermediate Mn‐hydroxides (β–MnOOH, Mn (OH)2 and Mn2(OH)3Cl). These phases are metastable and transfer to Mn3O4 with increasing duration. Generation of the Mn‐hydroxides leads to a change of physical‐chemical parameters of the solutions, such as water activity, pH and Eh. The last results in abrupt increase in the noble metals dissolution. At stable existence of only Mn3O4, the solubility of both Pt and Au lowers to equilibrium values. Essential catalysis effect of Pt on intensity and rate of Mn(II) oxidation was found. The dominant role of chloride of Pt and Au was defined under most oxidized conditions, specified by Mn2O3–MnO2 buffer. So at 400C, dissolved Au (log mAu) increases from –4. 40 in water to –1. 00 in 0. 1 mHCl, and ones of Pt (log mPt) from –4. 80 to –2. 90 accordingly. Thus, mixing of hydrosulfide and chloride solutions, as well as transformation of the systems to the stable state act upon total solubility of the noble metals. 相似文献