6710铀矿区火成岩的地球化学特征及其构造和成矿意义

火山岩型铀矿床通常与酸性至中性的火山岩类有关 ,而 6 710铀矿区的铀矿化与双峰式火山岩和基底花岗岩有紧密的空间关系。研究表明该套双峰式火山岩中玄武岩的Rb Sr等时线年龄为173± 9 7Ma ,流纹岩为 16 4 8± 0 57Ma。前者的不相容元素地球化学特征与板内拉斑玄武岩相一致 ;后者为准铝质 (ACNK =0 88- 0 96 ) ,稀土元素 (ΣREE :(2 50 33- 2 95 99)× 10 - 6 )和高场强元素 (Y ,Zr,Nb等 )的含量较高 ,与A型花岗岩的地球化学特征相似。基底花岗岩的Rb Sr等时线年龄为 2 4 9 9± 5 5Ma ,岩石为过铝质 (ANKC =1 18- 1 2 6 ) ,富集LREE((La/Lu) N=2 8 51-55 0 9)和大离子亲石元素 (Rb ,Th ,U等 ) ,与同造山S型花岗岩的地球化学特征一致。双峰式火山岩表明该区在燕山早期具有拉张裂解的地球动力学背景 ,基底花岗岩代表了海西晚期的挤压造山环境。它们分别为本区铀成矿提供了矿化剂 (CO2 - 3)和铀源。     

大陆下地壳层流作用及其大陆动力学意义

大量的地质和地球物理资料表明 ,年轻的大陆构造活动区的下地壳可能因热软化而出现透入性非地震式顺层韧性流动 ,这种下地壳层流作用驱动大陆上地壳发生地震式脆性断块运动 ,形成盆山格局 ,发生圈层耦合。大陆下地壳低粘度物质顺层流动可能是在地幔岩浆底侵作用为下地壳提供热能和添加幔源物质的基础上 ,并在地幔上升派生的重力和剪切力作用下 ,造成大陆下地壳热软化物质从盆地下部的幔隆区顺层流向相邻造山带之下的幔拗区。在下地壳层流过程中 ,地温场和速度场发生变     

由包体推导的河北汉诺坝下地壳-上地幔地温线及其地质意义

通过对采自河北汉诺坝玄武岩中的下地壳和上地幔包体的详细研究 ,建立了本区下地壳—上地幔地温线。该地温线高于大洋地温线和古老地盾地温线 ,接近克拉通边缘的地温线 ,符合该区的大地构造环境。由该地温线建立的下地壳—上地幔地质结构剖面表明 ,该区下地壳主要由不同类型的麻粒岩相岩石组成 ,其化学成分以镁铁质为主 ,深度范围为 2 5～ 4 2km。上地幔由超镁铁质的二辉橄榄岩组成 ,在尖晶石二辉橄榄岩和石榴石二辉橄榄岩之间有一过渡层。由地温线确定的壳幔边界位于 4 2km附近 ,与地震资料确定的莫霍面一致 ,但在壳幔边界之上的下地壳底部有下地壳麻粒岩和超镁铁质岩的互层。这一现象可以解释在下地壳底部常见的层状反射层。该区岩石圈底界大约在 95km ,其下的软流层仍由石榴石二辉橄榄岩组成     

Element geochemistry of weathering profile of dolomitite and its implications for the average chemical composition of the upper-continental crust--Case studies from the Xinpu profile,northern Guizhou Province,China

Geochemical behavior of chemical elements is studied in a dolomitite weathering profile in upland of karst terrain in northern Guizhou.Two stages can be recognized during the process of in situ weathering of dolomitite:the stage of sedentary accumulation of leaching residue of dolomitite and the stage of chemical weathering evolution of sedentary soil.Ni,Cr,Mo,W and Ti are the least mobile elements with reference to Al.The geochemical behavior of REE is similar to that observed in weathering of other types of rocks.Fractionation of REE is noticed during weathering,and the two layers of REE enrichments are thought to result from downward movement of the weathering front in response to changes in the environment.It is considered that the chemistry of the upper part of the profile,which was more intensively weathered,is representative of the mobile components of the upper curst at the time the dolomitite was formed,while the less weathered lower profile is chemically representative of the immobile constitution.Like glacial till and loess,the "insoluble" materials in carbonate rocks originating from chemical sedimentation may also provide valuable information about the average chemical composition of the upper continental crust.     

Rb–Sr and Sm–Nd isotopic studies of mafic igneous rocks from the Ryoke plutono-metamorphic belt in the Setouchi area, Southwest Japan: implications for the genesis and thermal history

Abstract Rb–Sr and Sm–Nd isochron ages were determined for whole rocks and mineral separates of hornblende‐gabbros and related metadiabases and quartz‐diorite from Shodoshima, Awashima and Kajishima islands in the Ryoke plutono‐metamorphic belt of the Setouchi area, Southwest Japan. The Rb–Sr and Sm–Nd whole‐rock‐mineral isochron ages for six samples range from 75 to 110 Ma and 200–220 Ma, respectively. The former ages are comparable with the Rb–Sr whole‐rock isochron ages reported from neighboring Ryoke granitic rocks and are thus due to thermal metamorphism caused by the granitic intrusions. On the contrary, the older ages suggest the time of formation of the gabbroic and related rocks. The initial ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios of the gabbroic rocks (0.7070–0.7078 and 0.51217–0.51231 at 210 Ma, respectively) are comparable with those of neighboring late Cretaceous granites and lower crustal granulite xenoliths from Cenozoic andesites in this region. Because the gabbroic rocks are considered to be fragments of the lower crustal materials interlayered in the granulitic lower crust, their isotopic signature has been inherited from an enriched mantle source or, less likely, acquired through interaction with the lower crustal materials. The Sr and Nd isotopic and petrologic evidence leads to a plausible conclusion that the gabbroic rocks have formed as cumulates from hydrous mafic magmas of light rare earth element‐rich (Sm/Nd < 0.233) and enriched isotopic (?_Sr > 0 and ?_Nd < 0) signature, which possibly generated around 220–200 Ma by partial melting of an upper mantle. We further conclude that they are fragments of refractory material from the lower crust caught up as xenoblocks by granitic magmas, the latter having been generated by partial melting of granulitic lower crustal material around 100 Ma.     

土壤铁锰结核中锰矿物类型鉴定的探讨

用化学选择溶提、X射线衍射 (XRD)等技术 ,对土壤铁锰结核中锰矿物类型的鉴定进行了探讨。结果表明 :根据 0 .1mol·L-1盐酸羟胺 (HAHC)处理前后土壤铁锰结核的XRD峰的变化 ,可鉴定出其所含的锂硬锰矿和钙锰矿 ;分析HAHC处理前后同一XRD谱线上不受锰矿物干扰的相邻层状硅酸盐矿物衍射峰与所含锰矿物衍射峰强度的比值变化 ,确定了水钠锰矿的存在 ;结合铁锰结核中与锰矿物类型相关的元素含量 ,可鉴定出其所含的钡硬锰矿和铅锰矿。     

Geochemical Characteristics of Sinian Manganese Deposits in China

Sinian is one of the main periods of the formation of manganese deposits in China. Sinian manganesedeposits are mainly hosted in carbon-rich black shale and siliceous shale formed during the Sinian interglacial period. The composition of manganese ore is simple. The main ore mineral is manganiferous carbonates. The grade of manganese ore is about 16-25%, with Mn/Fe>5 and P/Mn=0.006-0.14. Based on the tectonic setting and geological and geochemical characteristics of manganese deposits, this paper discusses the process of migration and concentration of manganese and ore-forming conditions of Sinian manganese deposits in China.     

上部地壳岩石变形与方解石质岩石的低温流动

系统总结了上部地壳环境中方解石质岩石的浅成流动机制与低温糜棱岩成因研究的几个重要方面：（１）地壳岩石脆－韧性转变域与岩石变形机制;（２）变形作用过程中流体相的物理与化学意义;（３）方解石质岩石的流动机制、变形特点与蠕变规律。同时讨论了对于地壳浅部层次方解石质石流主变学研究中存在的主要问题以及解决这些问题的基本思路与科学意义。     

铅同位素动力学模型及其在示踪花岗岩成因中的应用

介绍了壳幔铅混合模式和铅连续生长模式 ,并首次将这两个模式推广到花岗岩成因研究中。通过对世界上一些花岗岩体中长石铅同位素数据的壳幔混合模式计算 ,发现在约 3 1Ga时曾发生过一次全球性的大规模U ,Pb分异事件。将铅连续生长模式计算结果与其它一些一致性信息对比发现 ,该模式对示踪花岗岩的源区时代非常敏感。对以地壳铅为主的花岗岩 ,其铅连续生长模式年龄与其成岩年龄相当 ;而对造山带花岗岩 ,两者之间的关系具有不确定性。对中国南、北秦岭和大别—苏鲁造山带花岗岩中长石铅同位素数据的计算结果对比表明 ,即使属于同一个造山带的岩体 ,其铅的来源和演化历史也存在较大的差别。此外 ,青岛崂山碱性花岗岩的各种铅同位素性质与中国东部其它碱性花岗岩体存在差别 ,但与苏鲁地体花岗岩表现的铅同位素行为一致 ,表明崂山碱性花岗岩的成因与苏鲁花岗岩体的成因具有更强的相关性。