Transformation Process and Mechanism of Lithium Borates

正Amounts of lithium-containing salt lake brine resources are widely distributed in the four provinces named Qinghai,Tibet,Inner Mongolia and Xinjiang province,especially the salt lakes in Qinghai-Tibet Plateau are abundant of     

The Metastable Phase Equilibria of the MeX-MgCl_2-H_2O Systems

正1 Introduction The Pingluoba brine,which characterized as high concentration with sodium,potassium,boron,lithium,and rubidium,possess great development value.The main composition of the brine can be summarized to the     

Study on the Isothermal Evaporation Process at 5℃ with the Brine of Laguocuo Salt Lake

正1 Introduction Tibet has nurmerous salt lakes.Laguocuo is one of the salt lakes,which is located to the sorthern of Ali Plateau,31°59′02″N-32°04′08″N,84°02′03″E-84°12′03″E.Its lake water is rich in potassium,magnesium,lithium,boron,rubidium,cesium and other resources.The study of     

Geochemical and isotopic evidence of a groundwater source in the Corral Canyon meadow complex,central Nevada,USA

Major inorganic ions and stable carbon and oxygen isotopes in stream water, groundwater, groundwater seeps and springs were measured in the Corral Canyon meadow complex and watershed in the Toquima Mountains of central Nevada, USA. The purpose of the study was to determine whether stream water or groundwater was the source of water that supports vegetation in the meadow complex. Water samples from the watershed and meadow complex were mixed cation–HCO₃ type. Stream water sampled at different locations in the meadow complex showed variations in temperature, pH and specific conductance. The cation–anion proportions for stream water were similar to groundwater, groundwater seeps and runoff from the meadow complex. Stable oxygen isotope ratios for stream water (?17·1 to ?17·6‰ versus VSMOW) and groundwater and groundwater seeps in the meadow site (?17·0 to ?17·7‰ versus VSMOW) were similar, and consistent with a local meteoric origin. Dissolved inorganic carbon (DIC) and the δ ¹³C_DIC for stream water (?12·1 to ?15·0‰ versus VPDB) were different from that of groundwater from the meadow complex (?15·3 to ?19·9‰ versus VPDB), suggesting different carbon evolution pathways. However, a simple model based on cation–δ ¹³C_DIC suggests that stream water was being recharged by shallow groundwater, groundwater seeps and runoff from the meadow complex. This leads to the conclusion that the source of water that supports vegetation in the meadow complex was primarily groundwater. The results of this study suggest that multiple chemical and stable carbon isotope tracers are useful in determining the source of water that supports vegetation in meadow complexes in small alpine watersheds. Copyright © 2004 John Wiley & Sons, Ltd.     

全球碳酸锂贸易格局与供应危机传播研究

随着新能源产业的快速发展, 全球碳酸锂贸易量逐渐增长, 但其出口集中于少数国家, 这意味着全球碳酸锂供应存在一定的风险。为了深入了解全球碳酸锂贸易格局演变、供应危机传播路径及影响, 本文构建了2000—2021年全球碳酸锂贸易网络和级联失效模型, 概述了主要出口国贸易流向和贸易格局演变过程, 并模拟了不同供应危机来源的雪崩规模、传播路径及其影响。我们得到: (1)20多年来全球碳酸锂贸易集中度逐渐增加, 出口前三位国家保持稳定, 而主要进口大国变化明显, 贸易格局已由南美供应全球转变为南美供应东亚; (2)碳酸锂贸易供应危机的影响范围逐渐扩大, 间接传播逐渐占据主导地位; (3)智利供应危机对中日韩的影响程度逐渐扩大, 但对欧洲的影响时间最长; 阿根廷和中国的雪崩规模在上升、传播次数增加, 而美国则相反。本文将贸易格局演变与危机传播结合, 明确了全球碳酸锂主要贸易国智利、阿根廷、中国、德国等作为供应危机来源的影响程度及其传播路径。以上分析结果将有利于维护全球碳酸锂贸易稳定和主要贸易国采取应对策略缓解供应危机。     

常州市地下水化学特征与成因分析

常州市是长江三角洲地区典型的工业化城市,多年来的快速发展对地下水环境产生了系列影响,地下水化学组分受到天然条件和人为活动的双重因素控制,现状地下水化学成因和影响因素亟需深入研究。本文在地下水赋存条件分析的基础上,综合采用统计分析、离子比值、主成分分析法对常州各层地下水化学特征和成因开展分析。结果表明,区域潜水水化学类型以HCO₃^-—Ca²⁺·Mg²⁺、HCO₃^-—Ca²⁺和HCO₃^-·Cl^-—Na⁺·Ca²⁺型为主,第Ⅰ承压水以HCO₃^-—Na⁺·Ca²⁺和HCO₃^-—Ca²⁺型为主、第Ⅱ承压水以HCO₃^-—Na⁺     

济南四大泉群水化学特征及其成因分析

为明晰济南四大泉群水化学动态变化特征及成因,利用离子比例系数、PHREEQC模拟以及氢氧同位素反演等方法分析各泉群水化学成分特征及其形成过程。研究表明：（1）四大泉群阳离子Ca2+为优势离子,阴离子HCO3-为优势离子;（2）潭西泉和珍珠泉水化学类型稳定,而趵突泉和黑虎泉由HCO3—Ca型变为HCO3·SO4—Ca型;（3）四大泉群受地表水、寒武系凤山组-奥陶系岩溶水以及寒武系张夏组岩溶水混合补给,其中趵突泉、黑虎泉接受寒武系凤山组-奥陶系岩溶水补给占比略大,而潭西泉、珍珠泉接受寒武系张夏组岩溶水补给占比略大;黑虎泉滞留时间最短,循环交替强烈;（4）水岩相互作用强弱程度导致泉群水化学成分差异,溶解沉淀作用强度整体大于阳离子交换作用。趵突泉阳离子交换作用强度最弱,黑虎泉伴随有去白云化作用,潭西泉和珍珠泉水化学作用及强度类似,进一步印证潭西泉和珍珠泉有相同的补给来源及运移机制。该研究成果对水资源合理利用和岩溶大泉的保护具有重要意义。     

WATER RESOURCES TRANSFORMATION AND WATER QUALITY VARIATION IN THE URUMQI RIVER BASIN

ＷＡＴＥＲＲＥＳＯＵＲＣＥＳＴＲＡＮＳＦＯＲＭＡＴＩＯＮＡＮＤＷＡＴＥＲＱＵＡＬＩＴＹＶＡＲＩＡＴＩＯＮＩＮＴＨＥＵＲＵＭＱＩＲＩＶＥＲＢＡＳＩＮＱｕＹａｏｇｕａｎｇ（曲耀光）；ＬｕｏＨｏｎｇｚｈｅｎ（骆鸿珍）（ＬａｎｚｈｏｕＩｎｓｔｉｔｕｔｅｏｆＧ...     

Propagation of Extremely Low Frequency Waves Through the Ionosphere

The propagation features of extremely low frequency electromagnetic waves through the multicomponent ionospheric plasma are studied. It is shown that at relatively lower frequencies refractive index for right hand mode is higher than the left-hand mode, which is reversed at higher frequencies. The thermal temperature of plasma particle causes decrease in phase and group velocities of both right and left-hand modes. The crossover frequencies for different plasma models are computed and variation with ion concentration and thermal velocity is studied. Explicit expression for group velocity and travel time has been derived and studied numerically. Finally, we have presented simulation of the ion whistler spectrograms for Hydrogen, Helium and Oxygen ions present in the ionospheric plasma. The results are compared with the experimentally detected hydrogen and helium ion whistlers. The importance of the present study in the exploration of ionospheric plasma is illustrated.     

Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basins,Southern India

The Palar and Cheyyar River Basins in Tamil Nadu state of Southern India are characterised by different geological formations, and groundwater is the major source for domestic, agricultural and other water-related activities. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes and their relation to groundwater quality. Groundwater samples were collected once a month from 43 groundwater wells in this area from January 1998 to July 1999. Sampling procedures and chemical analysis were carried out as per the standard methods. Chemical data are used for mathematical calculations and graphical plots to understand the chemical process and its relation to the groundwater quality. The chemical composition of groundwater in the central part of the study area mainly depends on the recharge from lakes and the river, which is explained by a mixing mechanism. In addition, weathering of silicate minerals controls the concentration of major ions such as sodium, calcium, magnesium and potassium in the groundwater of this area. Further, the activity ratios indicate that the groundwater is in equilibrium with kaolinite, smectite and montmorrillonite. The reverse ion exchange process controls the concentration of calcium, magnesium and sodium in hard rock formations, and dissolution of carbonate minerals and accessory minerals is the source of Ca and Mg, in addition to cation exchange in the sedimentary formations. In general, the chemical composition of the groundwater in this area is influenced by rock–water interaction, dissolution and deposition of carbonate and silicate minerals, ion exchange, and surface water interactions.