New data on Sr-and C-isotopic chemostratigraphy of the Upper Riphean type section (Southern Urals)

New data on Sr-and C-isotopic systematics of carbonate rocks from the Upper Riphean stratotype (Karatau Group of the southern Urals) are obtained for several southwestern sections of the Bashkirian meganticlinorium, which have not been studied before. The results obtained supplement the Sr-and C-isotopic information for the group upper horizons thus detailing chemostratigraphic characterization of the entire succession. Limestone and dolostone samples used to analyze the Sr isotope composition satisfy strict geochemical criteria of the isotopic system retentivity and have been subjected to preliminary treatment in ammonium acetate to remove secondary carbonate phases. Data on 255 samples of carbonate rocks (171 studied for the first time) show that δ¹³C value varies in the Karatau Group succession from ?2.8 to +5.9 ‰ V-PDB with several in-phase excursions from the general trend in all the sections studied in the area 90 × 130 km. The δ¹³C variation trend demarcates several levels in the carbonate succession of the Karatau Group suitable for objectives of regional stratigraphy and for C-isotope chemostratigraphic subdivision of the Upper Riphean. The results of Sr isotopic analysis of 121 samples (51 unstudied before) from the Karatau Group imply that rocks in its lower part (the Katav Formation and basal horizon of the Inzer Formation) experienced considerable secondary alterations, while limestones and dolostones of the overlying interval of the group are frequently unaltered. In the “best” samples satisfying geochemical criteria of the isotopic system retentivity, the ⁸⁷Sr/⁸⁶Sr initial ratio increases from 0.70521–0.70532 in the lower Inzer deposits to 0.70611 in the upper Min’yar carbonates, decreasing to <0.70600 near the top of the latter. Above the regional hiatus separating the Min’yar and Uk formation, this ratio grows from 0.70533 to 0.70605–0.70609 in the limestone succession of the last formation.     

New Generation of Probabilistic Seismic Hazard Assessment for the Area Cologne/Aachen Considering the Uncertainties of the Input Data

A new earthquake catalogue for central, northern and northwestern Europe with unified M_w magnitudes, in part derived from chi-square maximum likelihood regressions, forms the basis for seismic hazard calculations for the Lower Rhine Embayment. Uncertainties in the various input parameters are introduced, a detailed seismic zonation is performed and a recently developed technique for maximum expected magnitude estimation is adopted and quantified. Applying the logic tree algorithm, resulting hazard values with error estimates are obtained as fractile curves (median, 16% and 84% fractiles and mean) plotted for pga (peak ground acceleration; median values for Cologne 0.7 and 1.2 m/s² for probabilities of exceedence of 10% and 2%, respectively, in 50 years), 0.4 s (0.8 and 1.5 m/s²) and 1.0 s (0.3 and 0.5 m/s²) pseudoacclerations, and intensity (I₀ = 6.5 and 7.2). For the ground motion parameters, rock foundation is assumed. For the area near Cologne and Aachen, maps show the median and 84% fractile hazard for 2% probability of exceedence in 50 years based on pga (maximum median value about 1.5 m/s²), and 0.4 s (>2 m/s²) and 1.0 s (about 0.8 m/s²) pseudoaccelerations, all for rock. The pga 84% fractile map also has a maximum value above 2 m/s² and shows similarities with the median map for 0.4 s. In all maps, the maximum values fall within the area 6.2–6.3° E and 50.8–50.9° N, i.e., east of Aachen.     

Relations between climatic variability and hydrologic time series from four alluvial basins across the southwestern United States

Hydrologic time series of groundwater levels, streamflow, precipitation, and tree-ring indices from four alluvial basins in the southwestern United States were spectrally analyzed, and then frequency components were reconstructed to isolate variability due to climatic variations on four time scales. Reconstructed components (RCs), from each time series, were compared to climatic indices like the Pacific Decadal Oscillation (PDO), North American Monsoon (NAM), and El Niño-Southern Oscillation (ENSO), to reveal that as much as 80% of RC variation can be correlated with climate variations on corresponding time scales. In most cases, the hydrologic RCs lag behind the climate indices by 1–36 months. In all four basins, PDO-like components were the largest contributors to cyclic hydrologic variability. Generally, California time series have more variation associated with PDO and ENSO than the Arizona series, and Arizona basins have more variation associated with NAM. ENSO cycles were present in all four basins but were the largest relative contributors in southeastern Arizona. Groundwater levels show a wide range of climate responses that can be correlated from well to well in the various basins, with climate responses found in unconfined and confined aquifers from pumping centers to mountain fronts.     

A new approach for the development and management of brackish karst springs

A new approach to the method of artificial upraising of the water outlet point, for management and development of brackish karst springs, uses the MODKARST model. Brackish karst springs simulation can be used to estimate the necessary upraising of the spring elevation, so that sea-water intrusion is blocked. The consequent freshwater loss to the sea, due to this upraising, can also be estimated. The method has been applied to the periodically brackish karst Almiros spring at Heraklion of Crete, Greece. The spring simulation showed that the sea-water intrusion could be prevented through an artificial upraising of the water-outlet point, realized by the construction of a dam. The exact upraising has been estimated. Freshwater loss to the sea because of this upraising has also been estimated. The model could also be used as a tool for the management of the spring. For example, it was used to assess management options for the spring during the depletion period of the year 1994. The best scenario for the development of the spring during this period has been estimated.     

Modelling net erosion responses to enviroclimatic changes recorded upon multisecular timescales

Land use change has been recognized throughout the Earth as one of the most important factors influencing the occurrence of rainfall-driven geomorphological processes. However, relating the occurrence of historical soil erosion rates is difficult because of the lack of long-term research projects in river basins. Also, complex models are not adequate to reconstruct erosion rate changes because they require significant input data not always available on long timescales. Given the problems with assessing sediment yield using complex erosion models, the objective of this study is to explore a parsimonious scale-adapted erosion model (ADT) from the original Thornes and Douglas algorithms, which aims at reconstruction of annual net erosion (ANE) upon multisecular timescales. As a test site, the Calore River basin (3015 km² in southern Italy) provides a peculiar and unique opportunity for modelling erosion responses to climate and land cover changes, where input-data generation and interpretation results were also supported by documented hydrogeomorphological events that occurred before and after land deforestation. In this way, ANE_ADT-values were reconstructed for the period 1675–2004 by using precipitation indexes, complemented by recent instrumental records, and by using land cover statistics from documented agrarian sources. Pulses of natural sedimentation in the predeforestation period have been related to Vesuvius volcanic activity and changes in rainstorm frequency. After deforestation, the basin system became unstable with sudden fluctuations in the hydrogeomorphological regime contributing significantly to increased erosion and, in turn, sediment transport sequences via river drainage towards the Tyrrhenian coast.     

Occurrence of salt water above fresh water in dynamic equilibrium in a coastal groundwater flow system near De Panne, Belgium

A salt water lens is found above fresh water under the shore between Dunkerque (France) and Nieuwpoort (Belgium). This inverse density distribution is in a dynamic equilibrium. It develops due to the infiltration of salt water on the back shore during high tide. Under this salt water lens, water infiltrated in the adjacent dune area flows towards the sea and discharges at the seabed. This water quality distribution differs from the classic salt water wedge under fresh water described in the literature. Here, the evolution to this water quality distribution is simulated with a density dependent numerical model. A large tidal range, shore morphology and a permeable groundwater reservoir are the main conditions for the observed water quality distribution. By altering these conditions, intermediate water quality distributions between the classic salt water wedge and the one discussed here develop. Based on these simulations, it is expected that similar kinds of inverse density distribution could be present in a number of coastal areas, which have tides, a gently sloping shore and a permeable substratum.     

Petrogenesis and tectonic setting of Cadomian felsic igneous rocks, Sandıklı area of the western Taurides, Turkey

In the Sandıklı (Afyon) region, western Taurides, the Late Proterozoic rocks of the Sandıklı basement complex are composed of low-grade meta-sedimentary rocks (Güvercinoluk Formation) intruded by felsic rocks (Kestel Cayı Porphyroid Suite, KCPS). The KCPS is a deformed and highly sheared, dome-shaped rhyolitic body with a granitic core. Quartz porphyry dikes intrude both the slightly metamorphic igneous and the sedimentary rocks of the basement complex. Both the quartz porphyries and rhyolites were converted into mylonites with relict igneous textures. Geochemical data show that these felsic igneous rocks are subalkaline and mainly granitic in composition with SiO₂ >72 wt% and Al₂O₃ >11.5 wt%. The chondrite-normalized incompatible trace element patterns are characterized by distinct negative Rb, Nb, Sr, P, Ti, and Eu with enrichment in Th, U, La, Ce, Nd, Sm, and Zr. The REE patterns of the felsic rocks indicate a strong enrichment in LREE but display slightly flat HREE patterns. According to geochemical characteristics and petrogenetic modeling, extrusive and intrusive rocks of the KCPS were probably derived from an upper continental crustal source (partial melting of granites/felsic rocks) by 18–20% fractional melting plus 18–20% Rayleigh fractional crystallization, which seems to be the most effective igneous process during the crystallization of the KCPS. Single zircon age data from the granitoids and fossils from the disconformably overlying sedimentary successions indicate that the metamorphism and the igneous event in the Taurides are related to the Cadomian orogeny. Based on the geological, geochemical and petrogenetic correlation of the post-collisional granitoids it is further suggested that the Tauride belt in western central Turkey was in a similar tectonic setting to the Gondwanan terranes in North Africa (Younger Granitoids) and southern Europe (Spain, France, Bohemia, Brno Massifs) during the Late Cadomian period.     

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.