我国首次发现的碳氢钠石

碳氢钠石是一种无水碱金属碳酸盐矿物,最初发现于美国的绿河盆地。一九八二年,在我国河南省泌阳凹陷首次发现。该矿物的化学成分是Na_2CO_3和NaHCO_3,分子式是:Na_2CO_3·3NaHCO_3。该矿物晶体呈板状,无色透明,主要产在重碳钠盐组成的碱矿层中。经测试确定,该矿物属二轴晶负光性,主折射率:Ng=1.531,Nm=1.524,Np=1.435,2V=31.45°;晶胞参数:a=10.046,b=15.633,c=3.492,a=92°8′,β=95。42′,γ=108°34′;最强的粉晶衍射线有:3.70(35),2.97(100),2.67(41),2.213(60);主要的红外光谱吸收带是:2616,1692,1662,1359,1048,1018,839,677cm_(-1)。据碳氢钠石的产状和共生组合特征,该矿物产于富钠,高P_(CO_2)的碳酸盐型内陆盐湖,是较高温度条件下快速蒸发的产物。     

岱海14 C测年的现代碳库效应研究*

碳库效应的复杂性是影响建立湖泊沉积物高精度年代序列的一大障碍。本项研究通过我国内蒙古半干旱区封闭湖泊表层沉积物、湖水、现生沉水植物狐尾藻、现生鲤鱼鱼骨和湖岸表层土壤等一系列样品的¹⁴ C年代测定,表明现代岱海确实存在碳库效应。碳库效应年龄因湖水盐度在湖区的不均而有所变化,岱海西部湖区弓坝河径流补给量大,湖水盐度较东部稍低,碳库效应年龄也略小于东部湖区。表层沉积物中有机质包含浮游生物和沉水植物的混合信息,因而其碳库效应年龄较沉水植物年龄轻,岱海湖心表层沉积物碳库效应年龄在2000a左右。这一碳库效应年龄较通过沉积钻孔¹⁴ C年龄线性回归获得的年龄偏大,可能的原因是在时间序列上碳库效应并非恒定。     

Efficiency of heavy liquid separation to concentrate magnetic particles

Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na₆[H₂W₁₂O₄₀], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage.     

Mass movements in cave sediments: investigation of a ∼40,000-year-old guano mudflow inside the entrance of the Great Cave of Niah, Sarawak, Borneo

The West Mouth of the Great Cave at Niah in Sarawak, northwest Borneo and the North Passage that leads to the West Mouth contain large deposits of guano. The main deposit, several metres thick in places, forms the sloping floor of the entire North Passage. A mass movement deposit identified in the West Mouth, having a volume of 600 m³, originated as a guano mudflow up the North Passage in the order of 40,000 years ago. This failure of the guano slope was investigated to determine whether particular conditions or events could be identified as the most likely causes. The physical, hydrological and geotechnical properties of samples of the material were determined so that the stability of the slope could be assessed. Stability analyses showed that shearing failure of the slope would require inputs of water to the slope in quantities for which no feasible explanation can be suggested. However, the properties of the guano are similar to those of loess, indicating a high susceptibility to ‘hydrocollapse’. Very shallow failure of the slope, possibly as several smaller mudflows, could therefore have occurred due to additional water in quantities that could realistically be supplied as rainwater spray, possibly with a seismic trigger. The climate must therefore have been wetter than it is at present. These findings have implications for the interpretation of sediment deposits in other relict caves.     

Progress in isotope paleohydrology using lake sediment cellulose

Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced by studies conducted over the past 15 years that span Holocene and pre-historical timescales.     

Paleolimnological reconstructions of Rouyn-Noranda lakes within the zone of influence of the Horne Smelter,Québec,Canada

Diatoms were identified and enumerated from a surface sediment calibration set of 50 lakes in northwestern Québec. The relationship between species composition and environmental variables was examined using canonical correspondence analysis (CCA). Forward selection and Monte Carlo permutation tests in CCA indicated that diatom species distributions in the data set are most strongly correlated to lakewater pH. A strong (r ² _boot = 0.83) weighted averaging calibration model, that includes bootstrapped error estimates, was developed for inferring past lakewater pH. Using this model, temporal changes in pH were reconstructed for two kettle lakes, Lac de la Pépinière and Lac Perron. Based on limnological data, both the study lakes were expected to have recently acidified due to increased acidic precipitation and increases in anthropogenic metal loading. However, our long-term pH inference data indicate that these lakes were naturally acidic during pre-industrial times. Nonetheless, the rate of acidification, particularly in Lac de la Pépinière, has accelerated in the last ∼75 years. These long-term pH records developed for the dilute lakes in northwestern Québec suggest that the region has received increased atmospheric pollutants from the nearby Horne smelter in Rouyn-Noranda. The pH inference profiles are markedly different from many other paleolimnological studies in acid-sensitive regions of Canada that have become acidic primarily as a result of industrial activities. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users.     

Geology and hazard implications of the Maraunot notch in the Pinatubo Caldera,Philippines

The 1991 Pinatubo eruption left 5–6 km³ of debris on the volcano slopes, much of which has been mobilized into large lahars in the following rainy seasons. Also during the eruption, collapse, localized in part along preexisting faults, left a caldera 2.5 km in diameter that almost immediately began to accumulate a 1.6 × 10⁸ m³ lake. By 2001, the water had risen to the fault-controlled Maraunot Notch, the lowest, northwestern portion of the caldera rim comprising the physiographic sill of the Caldera Lake. That year, a narrow artificial canal dug into an old volcanic breccia underlying the outlet channel failed to induce a deliberate lake breakout, but discharge from heavy rains in July 2002 rapidly deepened the notch by 23 m, releasing an estimated 6.5 × 10⁷ m³ of lake water that bulked up into lahars with a volume well in excess of 1.6 × 10⁸ m³. Lakes in other volcanoes have experienced multiple breakouts, providing practical motivation for this study. Fieldwork and high-resolution digital elevation models reveal andesites and ancient lacustrine deposits, strongly fractured and deformed along a segment of the Maraunot Fault, a prominent, steeply dipping, left-lateral fault zone that trends N35°–40°W within and parallel to the notch. Seismicity in 1991 demonstrated that the Maraunot Fault is still active. The fault zone appears to have previously been the erosional locus for a large channel, filled with avalanche or landslide deposits of an earlier eruption that were exhumed by the 2002 breakout floods. The deformed lacustrine sediments, with an uncalibrated ¹⁴C age of 14,760 ± 40 year BP from a single charcoal sample, attest to the existence of an earlier lake, possibly within the Tayawan Caldera, rim remnants of which survive as arcuate escarpments. That lake may well have experienced one or more ancient breakouts as well. The 2002 event greatly reduced the possibility of another such event by scouring away the erodible breccia, leaving less erodible fractured andesites and lacustrine rocks, and by enlarging the outlet channel and its discharge capacity. Several lines of evidence indicate, however, that future lahar-generating lake breakouts at the notch may keep populations of Botolan municipality downstream at risk: (1) a volume of 9.5 × 10⁷ m³ of lake water remains perched 0.8 km above sea level; (2) seismicity in 1991 demonstrated that the Maraunot Fault is still active and movements of sufficient magnitude could enlarge the outlet and the discharge through it; (3) more likely, however, with or without earthquake activity, landslides from the steep to overhanging channel walls could block the channel again, and a major rainstorm could then cause a rise in lake level and sudden breakouts; (4) intrusion of a new dome into the bottom of the lake, possibly accompanied by phreatic explosions, could expel large volumes of lahar-generating water.     

The deep-lake deposit in the Upper Triassic Yanchang Formation in Ordos Basin, China and its significance for oil-gas accumulation

The deep-lake facies of the Yanchang Formation represents a large outflowing lake basin in the Ordos area. Its deposition can be divided into four stages lake genetic and expanding stage, peak stage, inversion stage and dying stage. All the stages are obviously consistent with the evolution of depositional environment and the paleoclimate in the region. The study indicates that the lake basin has evolution fluctuations from highstand to lowstand for four times in its evolution history, and the deposition center of the lake has not obviously moved, staying along the Huachi-Yijun belt. The deep lake sedimentary system mainly consists of deep water deltas and turbidite fans during the entire evolution course of the lake basin in the Late Triassic. The former mainly developed on the slope of steep shore of the delta in the early period of the deep-water expansion and gradually experienced a big shift from deep-water deltas to shallow-water platform delta. And the latter appeared almost in all the above stages and had two types of turbidite fans, slope-moving turbidite fans and slump turbidite fans. The slope-moving turbidite fans have relatively complete facies belts overlapping one another vertically and consist of the slope channel of inter fans, the turbidite channel, inter turbidite channel and turbidite channel front of middle fans and outer fans (or lakebottom plain). However, the slide-moving turbidity fans are formed in the deep lake with their microfacies difficult to be distinguished, and only the center microfacies and edge microfacies can be determined. The two types of the turbidity fans are similarly distributing in the near-root-slope and far-root-slope regions. The deep-lake deposition governs the distribution of the hydrocarbon and reservoir, while the slope-moving turbidite fans are excellent reservoirs for oil-gas exploration due to their great thickness, widespread distribution and accumulation properties.     

洞庭湖吞吐调蓄数学模型及调洪功能评估

洞庭湖是一个吞吐调节型湖泊,是我国第二大淡水湖。近年来,洪涝灾害十分频繁,人们的生命财产安全受到严重威胁。为满足洞庭湖减灾防灾综合治理的需要,本文通过对8个不同时相的TM图像计算机解译和面积计算,查明了洞庭湖的面积和容积,建立了湖水面积与水位及湖水体积与水位的相关数学模型,并对其蓄洪调节能力进行评价,获得了满意的效果。该成果对洞庭湖区防洪减灾及综合治理具有十分重要的意义。