4A沸石吸附模拟核素Sr,Cs后的组分变化和结构表征

通过4A沸石吸附模拟核素Sr,Cs前后的化学成分分析、X衍射分析和红外光谱分析等手段方法,分析探讨了模拟核紊Sr,Cs在4A沸石的赋存状态,结果表明：4A沸石与模拟核素Sr,Cs之间主要以离子交换的方式发生作用,Sr^2 ,Cs^ 取代4A沸石中的可交换离子Na^ ,占据4A沸石a笼中的6元环和8元环。导致4A沸石的晶胞参数增大,晶格发生畸变。     

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.     

离子色谱法测定夏县温泉水中阴离子含量

利用离子色谱法对水中常见的7种阴离子进行定性和定量的分析,在既定的条件下,分别建立校正曲线法(外标法)及单点校正法模板,并对温泉水样校正分析。结果显示,外标法测得离子数据较为平稳,相对偏差均小于5%,适用于观测温泉水中其含量的变化。     

台湾地震观测系统的发展与现状

台湾地处环太平洋地震带,在欧亚板块与菲律宾海板块相互碰撞作用下,地震活动强烈。为加强对台湾地区地震活动的监测工作,深入了解台湾地区的地震活动特性,减轻地震灾害,经过十几年的不断整合与建设,台湾地区已拥有“实时地震观测网”、“实时强地动观测网”、“自由场强震观测网”、“全球卫星定位系统GPS观测网”和“宽频地震网”,以及“强震预警系统”和“强震速报系统”等多套地震观测处理系统。为促进海峡两岸地震学界的深入认识和了解,增进两岸交流与合作,本文对台湾地区地震观测系统发展和现状做了较为详细的介绍。     

A laboratory study on groundwater quality and mass movement occurrence

In this study, soil samples collected from the sides of two streams with high debris flow potential at Shenmu and Fengchiou village in Nantou County, Taiwan, were used for seepage tank tests in the laboratory. While the tests were being conducted, observations were made to investigate the relationships among displacement of the slope, quality of the seepage water and occurrence of mass movement. The results showed that according to the change rate, displacement could be divided into two stages, namely, the initial failure displacement stage and primary failure displacement stage. While the displacement of the slope was in primary failure displacement stages, the probability of slope failure became much higher. Before general slope failure, electrical conductivity (EC) and sulfate ion (SO₄ ²⁻) concentration of the seepage water increased significantly. The time when EC of the seepage water started to increase rapidly was much earlier than that when displacement of the slope started to increase significantly. Therefore, from the hazard mitigation view, there will be a longer time for response if EC of the seepage water was monitored.     

塔里木河中游输水堤防的修建对地下水化学特征的影响

通过对塔里木河中游输水堤防修建后,沙子河口、乌斯满和阿其河口三个断面地下水化学特征自2001—2003年的时空变化的监测与分析,初步揭示了在输水堤防影响下地下水化学特征变化的初步规律,结果表明：在空间上,沙子河口断面地下水化学变化规律完全被颠倒过来,乌斯满断面,地下水化学变化规律受输水堤防的影响不十分明显,但地表积盐严重,阿其河口断面,则呈现复杂的变化;在时间上,丰枯期地下水化学特征的正常变化规律在沙子河口被彻底改变,在乌斯满和阿其河口呈现出复杂变化。由于地下水循环具有潜在性和迟滞性,要彻底揭示在输水堤防影响下地下水化学特征时空变化的规律,需要进一步跟踪监测研究。     

柴达木盆地西部地下卤水水化学特征及其起源演化

柴达木盆地西北角分布有基岩,盆地西部分布山麓堆积及河、湖相沉积地层,新生界发育有多个北西—南东走向的规模不一的背斜,新近系分布有富钾地下卤水。利用统计方法分析卤水中TDS、K+和B2O3的富集情况。结果显示：TDS值出现双峰,卤水样品富K+和B3+的概率分别为628%和6129%。使用Piper图研究地下卤水时,经常出现样品点过于集中而不易反映主要离子含量的变化。本次研究改进了前人的图示方法,绘制适合于表示地下卤水的水化学图。利用钠氯系数、氯溴系数、氯碘系数、钾氯系数、脱硫系数、钙镁系数对研究区卤水水样进行分析,结果显示卤水样品多数未达到石盐沉积,少数达到石盐沉积。研究区水样氢、氧稳定同位素数据显示新近系地下卤水δ18O值和δD值均发生漂移,表明卤水经历长时间的蒸发浓缩。研究区地下卤水起源于早上新世的古大气降水,上新世以后由于青藏高原快速隆升,柴达木盆地抬升和沉降中心东移,接受沉积形成良好的盖层,同时大气环流的改变致使气候变得干燥,地下卤水经历蒸发浓缩封存,形成现今的卤水。     

利用GPS和DEMETER数据分析汶川地震前电离层变化

利用GPS TEC和法国DEMETER卫星ISL探测器的观测数据,分析了汶川地震前电离层变化.结果表明,电离层TEC在5月6-10日地方时下午有连续的负异常现象,5月9日地方时下午有明显的正异常现象.电离层TEC异常的范围主要位于震中南部区域,EW方向上1 100 ～1 670km,SN方向上1 600 ～3 700km.5月6日的负异常偏震中东南,5月7日的负异常偏震中西南,5月9日的正异常偏震中东南.震中西南和南部地区负异常较东南地区明显,震中南部和东南地区正异常程度较西南地区偏高,震中位置所对应南半球磁力线共轭区都出现了一定程度的正或负扰动.DEMETER卫星观测的电子密度Ne和离子密度N.在5月6-10日也出现了明显的负异常,异常分布与电离层TEC异常分布较为一致,主要集中在震中南部.震中所在的经度带上存在2个负异常峰值,且在纬度上关于地磁赤道对称.最后在上述异常的基础上,对基于岩石圈-大气层-电离层耦合的地震电离层异常机理开展了初步讨论.     

等离子体片离子分界线的模拟研究

等离子体片离子向内磁层的渗透在亚暴和磁暴过程中都起到了重要作用.以往对于等离子体片离子向内磁层的渗透都是通过固定磁矩的磁层离子漂移轨道理论来进行的.本文将过去的(U,B)空间中固定磁矩的磁层离子漂移轨道理论扩展为固定能量的磁层离子漂移轨道理论,讨论了等离子体片质子在向地球输运过程中,不同能量的质子开放轨道和封闭轨道的分界线的特性,及其随Kp指数的变化.在高能端,随着能量的升高,等离子体片质子分界线地心距离逐渐增大,且分界线的晨侧地心距离远远大于昏侧的地心距离.在低能端,随着质子能量的降低,质子分界线地心距离逐渐增大,且其分界线的昏侧地心距离要大于晨侧的地心距离.模拟结果还显示随着Kp指数的增强,等离子体片中不同能量的质子分界线都向地球移动.但在低能端和高能端,质子分界线的行为是不一样的.在低能端,随着Kp指数的增大,质子内边界形状基本保持不变.但在高能端,随着Kp指数的增大,质子内边界形状也将发生变化.在E=20 keV,Kp=6和E=10 keV,Kp=3两种情况,质子分界线甚至出现了两个分离的区域,一个是环绕地球的封闭轨道区域,一个是晨侧孤立的锥型区域.等离子体片能量为E的质子的内边界就是具有不同磁矩的Alfven层上能量为E的点的连线.TC-1热离子谱仪对等离子体片离子内边界的观测显示模拟结果与观测结果符合得很好.     

Simultaneous Determination of Fluorine,Chlorine, Bromine and Iodine in Six Geochemical Reference Materials Using Pyrohydrolysis,Ion Chromatography and Inductively Coupled Plasma‐Mass Spectrometry

Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l^?1 for both F and Cl and 10 ng l^?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg^?1 for F and Cl and 2 μg kg^?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg^?1 for F and Cl, 100 μg kg^?1 for Br and 25 μg kg^?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level.