含芘氨基酸衍生物对水中Cd2+、Pb2+的高选择性识别研究

本文报道了一种新型含芘氨基酸衍生物-L-[4-（1-芘基）]丁酰基苯丙氨酸（缩写为PLT）,通过对PLT与离子结合前后其二聚体/单体荧光发射峰强度比的检测表明该衍生物对水中的重金属离子Cd^2＋和Pb^2＋表现出了极强的识别性能,而对水中所存在的其它离子则具有完全不同的响应特性.     

江阴互通桥梁的施工控制测量

结合无锡江阴互通桥梁施工实例,着重介绍了互通桥梁施工控制测量的测点布置和具体作业方法及拱度控制、标高控制和预压的方法;同时,文章还总结了控制测量过程中用到的一些新测量思路及方法。     

立交桥曲线箱梁动力分析模型

提出了1种双脊骨空间有限元模型,用来模拟和分析立交桥曲线箱梁的固有振动特性和动力反应。将曲线箱梁分别看作是由空间梁或壳组成的空间结构,并分别采用分段空间直梁模型、壳元模型和实体元模型进行模拟,分析相同曲线箱梁的振动特性和地震时程反应,通过与双脊骨模型的计算结果的比较验证双脊骨模型的可靠性。初步研究了在相同曲率半径下不同跨度的曲线箱梁的固有振动特性,分析了双脊骨模型的脊骨间距、横向连接间距等参数对模型计算结果的影响。研究结果可为曲线梁桥抗震性能和地震反应分析提供参考。     

Residence, Resorption and Recycling of Zircons in Devils Kitchen Rhyolite, Coso Volcanic Field, California

Zircons from the Devils Kitchen rhyolite in the PleistoceneCoso Volcanic field, California have been analyzed by in situPb/U ion microprobe (SHRIMP-RG) and by detailed cathodoluminescenceimaging. The zircons yield common-Pb-corrected and disequilibrium-corrected²⁰⁶Pb/²³⁸U ages that predate a previously reported K–Arsanidine age by up to 200 kyr, and the range of ages exhibitedby the zircons is also approximately 200 kyr. Cathodoluminescenceimaging indicates that zircons formed in contrasting environments.Most zircons are euhedral, and a majority of the zircons areweakly zoned, but many also have anhedral, embayed cores, witheuhedral overgrowths and multiple internal surfaces that aretruncated by later crystal zones. Concentrations of U and Thvary by two orders of magnitude within the zircon population,and by 10–20 times between zones within some zircon crystals,indicating that zircons were transferred between contrastingchemical environments. A zircon saturation temperature of 750°Coverlaps within error a previously reported phenocryst equilibrationtemperature of 740 ± 25°C. Textures in zircons indicativeof repeated dissolution and subsequent regrowth are probablycaused by punctuated heating by mafic magma input into rhyolite.The overall span of ages and large variation in U and Th concentrations,combined with calculated zircon saturation temperatures andresorption times, are most compatible with crystallization inmagma bodies that were emplaced piecemeal in the crust at Cosoover 200 kyr prior to eruption, and that were periodically rejuvenatedor melted by subsequent basaltic injections. KEY WORDS: zircon geochronology; residence time; rhyolite; ion microprobe; California     

塔里木河中游输水堤防的修建对地下水化学特征的影响

通过对塔里木河中游输水堤防修建后,沙子河口、乌斯满和阿其河口三个断面地下水化学特征自2001—2003年的时空变化的监测与分析,初步揭示了在输水堤防影响下地下水化学特征变化的初步规律,结果表明：在空间上,沙子河口断面地下水化学变化规律完全被颠倒过来,乌斯满断面,地下水化学变化规律受输水堤防的影响不十分明显,但地表积盐严重,阿其河口断面,则呈现复杂的变化;在时间上,丰枯期地下水化学特征的正常变化规律在沙子河口被彻底改变,在乌斯满和阿其河口呈现出复杂变化。由于地下水循环具有潜在性和迟滞性,要彻底揭示在输水堤防影响下地下水化学特征时空变化的规律,需要进一步跟踪监测研究。     

离子色谱法测定夏县温泉水中阴离子含量

利用离子色谱法对水中常见的7种阴离子进行定性和定量的分析,在既定的条件下,分别建立校正曲线法(外标法)及单点校正法模板,并对温泉水样校正分析。结果显示,外标法测得离子数据较为平稳,相对偏差均小于5%,适用于观测温泉水中其含量的变化。     

塑膜温室油桃休眠期的温度变化

本文详尽分析了冰岛低压和大西洋高压的长期变化规律，发现两者均具有明显的阶段性变化，而且冰岛低压和大西洋高压的强度具有明显的反相关。同时，还分析了大西洋高压和冰岛低压与我国气候的关系，发现大西洋高压与我国冬季气温基本呈正相关，而冰岛低压与我国气温大致呈反相关，但均没有显著影响，所以两者都不是影响我国气候变化的重要天气系统。     

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.     

三峡水利枢纽主体工程施工控制测量

介绍了采用测边三角网和GPS静态测量实施三峡工程加密控制网的应用情况,阐述了随着光电测距精度的不断提高及水电施工环境的影响,采用测边网加测距三角高程网实施控制网加密是当前行之有效的一种好方法;此外,GPS测量以其限定条件少、操作简单、高自动化的内业处理等优点为施工控制测量开辟了一条新途径。     

红树植物白骨壤叶片衰老过程中叶肉细胞Ca2+水平的变化

用焦锑酸钙沉淀的电镜细胞化学方法，研究了白骨壤叶片衰老过程中叶肉细胞Ca^2 水平的变化．结果表明，在白骨壤幼叶和成熟叶叶肉细胞中，焦锑酸钙沉淀颗粒大量出现在液池和细胞间隙中，细胞壁中也可见少量沉淀，而细胞基质中则看不到焦锑酸钙沉淀．在衰老叶中，细胞基质和细胞膜上焦锑酸钙沉淀增加，而液泡和细胞间隙中的锑酸钙沉淀则显著减少，并且叶绿体外膜部分破损，结构破坏，核膜与液泡膜内部结构模糊，叶绿素含量、净光合速率、气扎手率和蒸腾速率显著下降．Ca^2 的区域性分布的变化与植物叶片衰老密切相关。