Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.     

Tectonic relation between northeastern China and the Korean peninsula revealed by interpretation of GRACE satellite gravity data

The major continental blocks in northeastern Asia are the North China block and the South China block, which have collided starting from the Korean peninsula. Geologic and geophysical interpretations reveal a well defined suture zone in northeastern China from Qinling through Dabie to Jiaodong. The discovery of high-pressure metamorphic rocks in the Hongseong area of the Korean peninsula, prominent evidence for the collision zone, indicates extension of the collision zone in northeastern China into the Korean peninsula. Interpretation of the GRACE satellite gravity dataset shows two prominent structural boundaries in the Yellow Sea. One extends from the Jiaodong Belt in eastern China to the Imjingang Belt in the Korean peninsula. The other extends from near Nanjing, eastern China, to Hongseong. Tectonic movement in or near the suture zone may be responsible for seismic activity in the western Korean peninsula and the development of the Yellow Sea sedimentary basin.     

应力路径对饱和软黏土割线模量的影响

在基坑、隧道开挖等过程中,不同部位的土体会经历不同的应力路径,在不同的应力路径下,土体可能表现出截然不同的静力学特性。同时,在工程实际中,土体的工作应变经常处于小应变范围,而在小应变情况下,土体的静力特性表现出更强的非线性和应力路径依赖性。基于广泛分布于东部地区,并且表现出诸多不良工程特性的软黏土,进行一系列不排水和排水条件下的应力路径静力试验,以研究应力路径对饱和软黏土静力特性,尤其是小应变情况下割线模量的影响。试验结果表明,不管在不排水还是在排水条件下,应力路径都对饱和软黏土的静强度产生巨大的影响,表现为围压增加的加载应力路径增大了静强度,而围压减小的卸载应力路径降低了静强度。同时,应力路径对割线弹性模量产生了更大的影响,围压增加的加载应力路径降低了割线模量,而围压减小的卸载应力路径增大了割线模量。应力路径对割线模量的影响在小应变时表现的更加明显,而这种影响主要原因是应力路径方向改变造成的土体各向异性。     

一步彩虹全息术的成象位置分析

本文从标量衍射理论出发,结合一定的物理意义,直接导出了一步彩虹全息术的成象位置公式;并根据可观察再现象的条件,从理论上导出了较为完整的成象位置关系表;并从中选出一部分成象位置关系进行了实验验证。     

Remarks on the Definition and Estimation of Friction Velocity

One of the mainscaling parameters in similarity theory of the atmospheric boundary layer is friction velocity. Unfortunately, several definitions of friction velocity exist in the literature. Some authors use the component of the horizontal Reynolds stress vector in the direction of the mean wind vector to define friction velocity. Others define the friction velocity by means of the absolute value of the horizontal Reynolds stress vector. The two definitions coincide only if the direction of the mean wind vector is parallel to the horizontal Reynolds stress vector. In general, the second definition gives larger values for the friction velocity. Over complex terrain the situation is further complicated by the fact that the terrain following flow is not necessarily horizontal. Thus, several authors have proposed to use terrain following coordinate systems for the definition of friction velocity. By means of a large dataset of fast-response wind measurements with an ultrasonic anemometer the friction velocities resulting from the different definitions are compared. Furthermore, it is shown that friction velocity can be well estimated from horizontal wind speed, and even better from simple horizontal or vertical turbulence parameters.     

Model and parameter uncertainty in IDF relationships under climate change

Quantifying distributional behavior of extreme events is crucial in hydrologic designs. Intensity Duration Frequency (IDF) relationships are used extensively in engineering especially in urban hydrology, to obtain return level of extreme rainfall event for a specified return period and duration. Major sources of uncertainty in the IDF relationships are due to insufficient quantity and quality of data leading to parameter uncertainty due to the distribution fitted to the data and uncertainty as a result of using multiple GCMs. It is important to study these uncertainties and propagate them to future for accurate assessment of return levels for future. The objective of this study is to quantify the uncertainties arising from parameters of the distribution fitted to data and the multiple GCM models using Bayesian approach. Posterior distribution of parameters is obtained from Bayes rule and the parameters are transformed to obtain return levels for a specified return period. Markov Chain Monte Carlo (MCMC) method using Metropolis Hastings algorithm is used to obtain the posterior distribution of parameters. Twenty six CMIP5 GCMs along with four RCP scenarios are considered for studying the effects of climate change and to obtain projected IDF relationships for the case study of Bangalore city in India. GCM uncertainty due to the use of multiple GCMs is treated using Reliability Ensemble Averaging (REA) technique along with the parameter uncertainty. Scale invariance theory is employed for obtaining short duration return levels from daily data. It is observed that the uncertainty in short duration rainfall return levels is high when compared to the longer durations. Further it is observed that parameter uncertainty is large compared to the model uncertainty.     

夏季黄海、东海鞭毛虫的丰度与悬浮颗粒物的关系

对2001年8月黄海中部和南部以及东海北部海洋鞭毛虫的丰度及其与悬浮颗粒物的数量关系进行了研究,发现调查区域内的鞭毛虫丰度为44~12 600个/cm3,它们在悬浮颗粒中所占的比例可达60%以上.悬浮颗粒物的粒径谱可以分为平缓型、驼峰型、浮游生物型和混合型.鞭毛虫丰度的变化与悬浮颗粒物的数量分布具有相似的变化趋势,整体上来说,两者数量的相关性显著,而不同的粒径谱类型中,两者的关系有不同的特点.对两者的数量关系进行了初步的探讨,并为今后海域生态调查中鞭毛虫丰度的快速估计提供一条新的途径.     

全球化背景下的南京港城关联发展效应分析

运用灰色关联分析法,通过计算港城关联发展的均值关联度,对近10年南京港城关联发展效应进行了定量测度。研究结果表明:南京港城关联发展效应总体上比较显著,但具有明显的阶段性,其中: 1990年到1994年,港城关联发展效应呈弱化状态,1994年到1998年呈强化态势,1998年以后则呈现明显的弱化趋势。城市产业结构的变动、港口功能的演变、周围港口的激烈竞争以及港口管理体制和国际贸易的发展是导致上述动态特征的成因机制。     

西太平洋Y3海山对营养盐的影响及其生态环境效应

作为大洋典型地貌特征的海山,其邻近的海洋生境并不被人熟知。依据2014年冬季对热带西太平洋Y3海山及其邻近海域的综合调查,首次探讨了该海山区海水中营养盐的分布特征及其与生态环境的耦合关系。结果表明Y3海山区是典型的热带寡营养海域。在50~125 m的深度,温跃层和高盐区双重作用对底部高浓度营养盐向上输送的阻碍,是导致真光层上部营养盐浓度较低的重要原因;同时,浮游植物和异养细菌的消耗也加剧了该区域营养盐的缺乏。Y3海山突出的地形地貌对营养盐的分布产生重要的影响,海山对流经的海流产生阻碍,形成上升流,使底部高浓度的营养盐突破温跃层和高盐区的阻碍向上输送,从而使海山周围营养盐的平均浓度高于远离海山的海域。相关性分析显示,Y3海山区真光层中营养盐浓度与温度、盐度、叶绿素a浓度和异养细菌丰度分别呈负相关、正相关、负相关(除NO₂-N外)和负相关关系。海山区特殊的营养盐分布及其与生态环境的耦合是其成为一种独特的大洋生态系统的重要因素。