Carbon isotopic studies of individual lipids in organisms from the Nansha sea area, China

Sediments contain abundant lipid compounds in general, which are used as biomarker compounds to study organic matter sources and reconstruct the pa-laeoenvironments[1—7]. However, lipid compounds in sediments are generally a mixture of various genetic components so that it is difficult to correctly decouple their biological sources only by the results of bio-chemical researches. Carbon isotopic studies of indi-vidual sedimentary lipid compounds can discover their genetic information, which pr…     

考虑边界反射作用河流污染混合区的简化算法

以排污口为坐标原点,通过数学推证了岸边排放时P(x,y)点与中心排放时Q(x/4,±y/2)点的污染物浓度对应相等.通过计算实验和曲线拟合,分别给出了中宽河流污染混合区最大长度、最大宽度和相应的纵坐标、面积等参数以及河流中心线和两岸线沿程浓度分布的实用化公式,给出了污染混合区的近似外边界曲线方程.对中宽河流污染混合区范围的计算和环境敏感点的浓度预测,具有重要实用价值,为工程技术人员提供了准确、简便、快捷的实用化方法.     

一种融合空间拓扑关系的室内无线定位方法

针对仅利用无线信号源和其发射信号强度定位会丢失待测位置与信号源之间固有空间关系的问题,提出了利用已知位置接收信号源发射的无线信号强度测量未知点的低成本室内定位方法。该方法深入分析了待定位点和无线信号源以及信号覆盖范围之间的空间关系,充分利用RCC-8空间关系模型进行无线定位。实验结果表明,采用这种融合空间拓扑关系的基于无线信号强度的室内定位方案能够优化定位流程,并在测得位置中反映待测点和信号源之间的相对空间关系。     

THE FREE-WILSON PARADIGM REDUX:SIGNIFICANCE OF THE FREE-WILSON COEFFICIENTS,INSIGNIFICANCE OF COEFFICIENT ‘UNCERTAINTIES’ AND STATISTICAL SINS

The Free-Wilson paradigm is an established and powerful tool for quantitatively relating activity withchemical structure.Current implementations of the paradigm,however,are flawed both conceptually andin execution.As part of an attempt to more fully realize the promise of the paradigm,it was necessaryto examine these limitations in detail.This report introduces a robust,theory-founded Free-Wilson implementation:stepwise principalcomponents regression analysis(SPCRA).SPCRA is computationally superior to previousimplementations but does not in itself correct their conceptual flaws.The development of SPCRA did,however,facilitate derivation of a simple and chemically significantinterpretation of the Free-Wilson structure-activity model.A number of statistical aspects of this modelcommonly misused in previous applications are discussed at length.These discussions provide criticalbackground for the development of an alternative implementation of the Free-Wilson paradigm.     

Assessing cause and effect of multiple stressors on marine systems

An operational framework is developed to serve as a guideline for investigating causal relationships between environmental stressors and effects on marine biota. Because of the complexity and variability of many marine systems, multiple lines of evidence are needed to understand relationships between stressors and effects on marine resources. Within this framework, a weight of evidence approach based on multiple lines of evidence are developed and applied in a sequential manner by (1) characterizing the study system which involves determining if target biota are impaired, assessment of food and habitat availability, and measuring contaminant levels in the environment, (2) assessing direct effects of contaminant exposure on target biota using biomarkers and assessing indirect effects of exposure using suites of bioindicators, and (3) applying standard causal criteria based on epidemiological principles and diagnostic health profiling techniques to assess potential causes. Use of multiple lines of evidence should also reduce the risk of false positives (Type I error or falsely concluding that there is a causal relationship when there is none) and false negatives (Type II error or falsely concluding there is not a causal relationship when there actually is). Understanding causal relationships and the mechanistic processes between environmental stressors and effects on biota is important in the effective management and restoration of impaired marine ecosystems.     

Treatment of ground-motion predictive relationships for the reference seismic hazard map of Italy

In the framework of the 2004 reference seismic hazard map of Italy the amplitude of the strong-motion (expressed in terms of Peak Horizontal Acceleration with 10% probability of non-exceedence in 50 years, referred to average hard ground conditions) was computed using different predictive relationships. Equations derived in Italy and in Europe from strong-motion data, as well as a set of weak and strong-motion based empirical predictive relationships were employed in a logic tree procedure, in order to capture the epistemic uncertainty affecting ground-motion attenuation. This article describes the adjustments and conversions required to eliminate the incompatibilities amongst the relations. Particularly significant are distance conversions and style-of-faulting adjustments, as well as the problems related to the use of regional relations, such as the selection of a reference depth, the quantification of random variability and the strong-motion prediction. Moreover, a regional attenuation relationship specific for volcanic areas was also employed, allowing a more realistic evaluation of seismic hazard, as confirmed by the attenuation of macroseismic intensities.     

Seismic ground motion relationship in southern China based on stochastic finite-fault model

The characteristics of seismic ground motions in southern China are difficult to determine statistically due to a lack of strong ground motion data. In this study, a stochastic finite-fault ground motion model was adopted to simulate the seismic ground motions at bedrock for southern China, based on parameters derived from small and medium earthquakes that have occurred in the region. From these, the response spectra was estimated. A set of ground motion attenuation relations hipswas then developed based on simulated peak ground motions and response spectral parameters through regression, which would be applicable for use in engineering practice. Through comparisons, it was demonstrated that the proposed ground motion relationships are generally consistent with those obtained from other reported ground motion attenuation models for southern China.     

Relationships among some locally conservative discretization methods which handle discontinuous coefficients

This paper presents the relationships between some numerical methods suitable for a heterogeneous elliptic equation with application to reservoir simulation. The methods discussed are the classical mixed finite element method (MFEM), the control-volume mixed finite element method (CVMFEM), the support operators method (SOM), the enhanced cell-centered finite difference method (ECCFDM), and the multi-point flux-approximation (MPFA) control-volume method. These methods are all locally mass conservative, and handle general irregular grids with anisotropic and heterogeneous discontinuous permeability. In addition to this, the methods have a common weak continuity in the pressure across the edges, which in some cases corresponds to Lagrange multipliers. It seems that this last property is an essential common quality for these methods. T.F. Russell: Partially supported by the National Science Foundation Grant Nos. DMS-0084438 and DMS-0222300.     

Rutile inclusions in garnet from a dissolution‐reprecipitation mechanism

Metamorphic garnet commonly contains needle‐like rutile inclusions as well as equant rutile inclusions that surround quartz inclusions and range in size from submicrometer to nanometer. Although the origin of these equant rutile inclusions, that is, exsolution or non‐exsolution, has important implications for petrological and tectonic processes, the crystallographic characteristics of these inclusions have rarely been studied because of the small sizes and analytical difficulties involved. Here, we report the crystallographic characteristics pertinent to the genetic origin of minute equant rutile inclusions in cloudy, nearly spherically shaped garnet domains with Ti‐depleted compositions surrounding quartz inclusions in ultrahigh‐pressure garnet from several diamondiferous Erzgebirge quartzofeldspathic gneissic rock samples. TEM analyses show that the equant rutile crystals in cloudy garnet domains are partially bounded by the low‐energy {100}_rt ± {110}_rt ± {101}_rt facets and have rather random crystallographic orientation relationships (CORs) with the garnet host, with preferential alignment of low‐energy lattice planes, for example, {100}_rt//{112}_grt, for some rutile crystals. Although the rather random CORs are unlikely to be attributed to solid‐state exsolution subjected to the stringent topotactic garnet lattice constraints, the characteristic subhedral {100}_rt ± {110}_rt ± {101}_rt crystal forms of rutile can be rationalized by a metasomatic dissolution‐reprecipitation mechanism via a fluid phase. In this scenario, the quartz+fluid inclusions in garnet were first subjected to decompression microcracking during rock exhumation, followed by dissolution of Ti‐bearing garnet matrix at the crack tips or along the crack surfaces and subsequent reprecipitation of rutile, apatite, gahnite, akdalaite, and Ti‐depleted garnet. The rapid coalescence between rutile and garnet crystals in fluid or direct attachment of rutile crystals onto the dissolving crack surfaces would then yield the rather random CORs as reported here. These results, along with previous work on rutile needles, indicate rather diverse genesis of rutile inclusions in various crystal forms, thus shedding light on the controversial exsolution origin for other inclusion suite/microstructure in minerals.     

PHYSICO‐GEOCHEMICAL AND MINERAL COMPOSITION OF NEEM TREE SOILS AND RELATION TO ORGANIC PROPERTIES

The Neem tree, the oil of which has a long history of pesticide, fertilizer and medicinal use in India, has been studied extensively for its organic compounds. Here we present a physical, mineralogical and geochemical database resulting from the analyses of two Neem soil profiles (epipedons) in India. Neem tree derivatives are used in the manufacture of a variety of products, from anti‐bacterial drugs and insecticides to fertilizers and animal feeds. A preliminary geochemical and mineralogical analysis of Neem soils is made to explore the potential for chemical links between Neem tree derivatives and soils. Physical soil characteristics, including colour, texture and clay mineralogy, suggest the two pedons formed under different hydrological regimes, and hence, are products of different leaching environments, one well‐drained site, the other poorly drained. Geochemically, the two Neem soils exhibit similarities, with elevated concentrations of Th and rare earth elements. These elements are of interest because of their association with phosphates, especially monazite and apatite, and the potential link to fertilizer derivatives. Higher concentrations of trace elements in the soils may be linked to nutritional derivatives and to cell growth in the Neem tree.