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161.
Hydrogeochemistry and strontium isotopes in the Arno River Basin (Tuscany, Italy): Constraints on natural controls by statistical modeling 总被引:2,自引:0,他引:2
B. Nisi A. Buccianti O. Vaselli G. Perini F. Tassi A. Minissale G. Montegrossi 《Journal of Hydrology》2008,360(1-4):166-183
In this paper the chemistry of major and trace elements and, for the first time, strontium isotopic ratios measured in running waters from the Arno River Basin (Tuscany, central-northern Italy) and thermal springs discharging in the same hydrographic system are presented and discussed. Classical graphical methods (e.g. mixing diagrams) have here been improved to identify, in a correct statistical sample space, extreme chemical compositions attributable to the action of geochemical processes and/or inherited from specific lithologies (namely contributions or components 1, 2 and 3) to be used in inverse modeling procedures, due to the absence of clear end-members. A linear least squares problem, with non-negativity constraints and distances, as required for compositional data (convex linear mixing) was solved by considering the contribution of the most discriminant variables given by the 87Sr/86Sr isotopic ratios and the concentration of Ca2+, Mg2+, Sr and Rb. Following such approach, it can be assumed (p < 0.05) that component 1, characterized by a Ca2+(Mg2+)– radiogenic-rich (87Sr/86Sr = 0.71274; Rb/Sr = 0.039), represents a dominant feature at basin scale, with a weight ranging from 69% to 100%. Much lower percentages are related to component 2, represented by a Ca2+(Mg2+)– facies with intermediate 87Sr/86Sr (0.70874) and low Rb/Sr (2.8 × 10−4) ratios and component 3, identified by Ca2+– facies with less radiogenic 87Sr/86Sr (0.70827) and low Mg2+/Ca2+ (0.011) ratios. These components are mainly dominated by the dissolution of evaporitic rocks and/or mixing with thermal waters in the southern part of the Arno River Basin and by dissolution of the carbonatic fraction, kinetically favored with respect to that of the silicatic minerals, in the upper reaches of the main course and its tributaries, respectively. 相似文献
162.
Sotillo MG Fanjul EA Castanedo S Abascal AJ Menendez J Emelianov M Olivella R García-Ladona E Ruiz-Villarreal M Conde J Gómez M Conde P Gutierrez AD Medina R 《Marine pollution bulletin》2008,56(4):686-703
The ESEOO Project, launched after the Prestige crisis, has boosted operational oceanography capacities in Spain, creating new operational oceanographic services and increasing synergies between these new operational tools and already existing systems. In consequence, the present preparedness to face an oil-spill crisis is enhanced, significantly improving the operational response regarding ocean, meteorological and oil-spill monitoring and forecasting. A key aspect of this progress has been the agreement between the scientific community and the Spanish Search and Rescue Institution (SASEMAR), significantly favoured within the ESEOO framework. Important achievements of this collaboration are: (1) the design of protocols that at the crisis time provide operational state-of-the-art information, derived from both forecasting and observing systems; (2) the establishment, in case of oil-spill crisis, of a new specialized unit, named USyP, to monitor and forecast the marine oceanographic situation, providing the required met-ocean and oil-spill information for the crisis managers. The oil-spill crisis scenario simulated during the international search and rescue Exercise "Gijón-2006", organized by SASEMAR, represented an excellent opportunity to test the capabilities and the effectiveness of this USyP unit, as well as the protocols established to analyze and transfer information. The results presented in this work illustrate the effectiveness of the operational approach, and constitute an encouraging and improved base to face oil-spill crisis. 相似文献
163.
Maria V. Pastor Josep L. Pelegrí Alonso Hernández-Guerra Jordi Font Jordi Salat Mikhail Emelianov 《Continental Shelf Research》2008
A historical data set is used to describe the coastal transition zone off Northwest Africa during spring 1973 and fall 1975, from 17° to 26°N, with special emphasis on the interaction between subtropical (North Atlantic Central Waters) and tropical (South Atlantic Central Waters) gyres. The near-surface geostrophic circulation, relative to 300 m, is quite complex. Major features are a large cyclonic pattern north of Cape Blanc (21°N) and offshore flow at the Cape Verde front. The large cyclone occurs in the region of most intense winds, and resembles a large meander of the baroclinic southward upwelling jet. The Cape Verde frontal system displays substantial interleaving that may partly originate as mesoscale features at the coastal upwelling front. Property–property diagrams show that the front is an effective barrier to all properties except temperature. The analysis of the Turner angle suggests that the frontal system is characterized by large heat horizontal diffusion as a result of intense double diffusion, which results in the smoothing of the temperature horizontal gradients. Nine cross-shore sections are used to calculate along-shore geostrophic water-mass and nutrient transports and to infer exchanges between the coastal transition zone and the deep ocean (import: deep ocean to transition zone; export: transition zone to deep ocean). These exchanges compare well with mean wind-induced transports and actual geostrophic cross-shore transport estimates. The region is divided into three areas: southern (18–21°N), central (21–23.5°N), and northern (23.5–26°N). In the northern area geostrophic import is roughly compensated with wind-induced export during both seasons. In the central area geostrophic import is greater than wind-induced export during spring, resulting in net import of both water (0.8 Sv) and nitrate (14 kmol s−1), but during fall both factors again roughly cancel. In the southern area geostrophy and wind join to export water and nutrients during both seasons, they increase from 0.6 Sv and 3 kmol s−1 during fall to 2.9 Sv and 53 kmol s−1 during spring. 相似文献
164.
高分子材料固化滨海盐渍土的强度与微结构研究 总被引:6,自引:2,他引:4
高分子材料SH固土剂与生石灰粉共同固化滨海盐渍土具有很高的抗压强度、抗拉强度和水稳性。由于SH固土剂对土颗粒的包裹作用及在土颗粒间和孔隙内形成的丝网状联接结构,使得固化土的强度和水稳性较单一石灰固化土提高很多,正弦波压缩疲劳作用降低了固化土的抗压强度。在一定的荷载值及幅值条件下,随疲劳次数的增加,抗压强度下降。30×103疲劳次数是强度下降的另一个起始点。固化土的微结构形貌照片显示,SH固土剂在两周固化龄期时形成了稳固的丝网状联接结构,四周龄期时结构已相当稳定。浸水后丝网状联接结构依然存在,表明SH固土剂的固化反应具有不可逆性。 相似文献
165.
The crater lake of Kawah Ijen volcano contains extremely low pH (<0.4) waters with high SO4 (70000 mg/kg), Cl (21000 mg/kg), F (1500 mg/kg), Al (5000 mg/kg), Fe (2000 mg/kg) and trace metal (Cu 0.5, Zn 4, Pb 3 mg/kg) contents. These brines seep outward through the western crater rim and reappear on the other side as streamlets, which form the headwaters of the Banyupahit stream. The Banyupahit first mixes with fresh rivers and thermal springs in the Ijen caldera and then irrigates a coastal agricultural plain which is 30 km from the summit crater.We discuss the downstream composition changes affecting the Banyupahit waters by using stable isotope, chemical and mineralogical data collected from sites along the stream length. The saturation of the stream waters with respect to minerals was evaluated with SOLVEQ and WATEQ4F and compared with the geochemical observations. An aluminous mineralogy (alunogen, pickeringite, tamarugite and kalinite) develops in the upper part of the Banyupahit due to concentration of the headwaters by evaporation. Downstream attenuation of dissolved element concentrations results principally from dilution and from mineral precipitation. The stream pH changes from 0 at the source to >4 close to the mouth. The δD and δ18O values and the relative SO4–Cl–F contents of the Banyupahit waters indicate that the tributaries are mostly meteoric. Dissolved SO4 in the acidic stream come only from the crater lake seepages and are not involved later in microbially mediated reactions, as shown by their δ34S and δ18O values. Re-equilibration of the stream SO4 oxygen-isotope composition with H2O from tributaries does not occur.Calcium, SiO2, Al, Fe, K and SO4 behave non-conservatively in the stream waters. Gypsum, silica (amorphous or poorly ordered), a basic aluminum hydroxysulfate (basaluminite?), K-jarosite and amorphous ferric hydroxide may exert a solubility control on these elements along the entire stream length, or in certain stream sections, consistent with the thermochemical model results. Downstream concentration trends and mineral saturation levels suggest that precipitation of Sr-, Pb-rich barite and celestite consume Ba, Sr and Pb, whereas dissolved Cu, Pb and Zn may adsorb onto solid particles, especially after the junctions of the acidic stream with non-acidic rivers. We calculated that significant fluxes of SO4, F, Cl, Al, SiO2, Ti, Mn and Cu may reach the irrigation system, possibly causing serious environmental impacts such as soil acidification and induration. 相似文献
166.
167.
厦门海域渔业资源评估 总被引:7,自引:0,他引:7
以初级生产力和渔业统计资料为材 ,分别应用Tait沿岸海域生态系能流分析法、营养动态法和Cushing等 3种模式 ,估算厦门沿岸海域的渔业资源自然生产量。同时 ,分别应用Schaefer和Fox两种剩余产量模式估算最大持续产量和最大持续捕捞力量。前 3种模式估算该海域的资源生产量分别为 2 0 1 0 5t,1 8463t和 1 7489t,平均 1 8686t。后两种模式估算最大持续产量平均值分别为 9639t和 91 0 4t。估算的最大持续捕捞力量 :5种作业综合总功率为 1 5976kW ;以厦门机定置渔船单位功率渔捞效率为标准估算的总功率为 2 7351kW ;以厦门机刺网渔船单位功率渔捞效率为标准估算的总功率为 432 1 3kW。 1 997年实际渔获量和捕捞力量均超过了估算的最大持续产量和最大持续捕捞力量。文中还讨论了捕捞力量的调整问题。 相似文献
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