Atmospheric,weathering and biological contributions in the chemical signature of stream water: the upper Iskar Reka watershed,Bulgaria

Abstract

The chemical signature of stream water is influenced by several factors: atmospheric input, weathering of bedrock and soils, biological uptake, soil storage, and decomposition of organic matter. The importance of weathering and biological activity, according to season, can be assessed by subtracting atmospheric input. In the upper Iskar Reka watershed, Bulgaria, results show that Na and Ca are mainly exported out of the basin (weathering is dominant), while nitrate and sulphate are consumed/stored. The behaviour of K suggests that biological activity is dominated by vegetation uptake in spring and by bacterial activity in autumn. In summer, the weathering load of Mg is compensated by reactions with clays. The low nutrient input from weathering due to low reserves in the soil may lead to a biomass production closely linked to a rapid internal cycle and also to a relative sensitivity of the ecosystem to any change in vegetation cover and atmospheric input.

Editor Z.W. Kundzewicz

Citation Gassama, N. and Violette, S., 2012. Atmospheric, weathering and biological contributions in the chemical signature of stream water: the Upper Iskar Reka watershed, Bulgaria. Hydrological Sciences Journal, 57 (3), 535–546.     

Baseline metals pollution profile of tropical estuaries and coastal waters of the Straits of Malacca

The status report on metal pollution in tropical estuaries and coastal waters is important to understand potential environmental health hazards. Detailed baseline measurements were made on physicochemical parameters (pH, temperature, redox potential, electrical conductivity, salinity, dissolved oxygen, total dissolved solid), major ions (Na, Ca, Mg, K, HCO₃, Cl, SO₄ and NO₃) and metals concentrations (²⁷Al, ⁷⁵As, ¹³⁸Ba, ⁹Be, ¹¹¹Cd, ⁵⁹Co, ⁶³Cu, ⁵²Cr, ⁵⁷Fe, ⁵⁵Mn, ⁶⁰Ni, ²⁰⁸Pb, ⁸⁰Se, ⁶⁶Zn) at estuaries and coastal waters along the Straits of Malacca. Principal component analysis (PCA) was employed to reveal potential pollution sources. Seven principal components were extracted with relation to pollution contribution from minerals-related parameters, natural and anthropogenic sources. The output from this study will generate a profound understanding on the metal pollution status and pollution risk of the estuaries and coastal system.     

Hydrochemical characterization of an acid mine drainage-affected reservoir: the Sancho Reservoir,Huelva, southwest Spain

Abstract

The objectives of this study were to discover the relationship between variables in a water reservoir and the hydrochemical variations related to acid mine drainage (AMD), and to describe the horizontal stratification related to vertical salinity and variations in metals present in the region. The information obtained may be used for establishing risk evaluation criteria and to design future remediation strategies, which could be useful for new dams. The hydrochemical characterization was based on a sampling campaign performed in October 2011. A total of 28 samples, at 1-m-deep intervals, were obtained. The hydrogeochemical study of the polluted reservoir shows that the dilution effect is not sufficient to neutralize AMD contributions from mining activity. Sampling carried out from the surface water to the deepest points reveals stratification of the reservoir that allows it to be included in the group of monomictic and holomitic lakes.

Editor D. Koutsoyiannis; Associate editor M.D. Fidelibus     

Major human Hepatitis A virus genotype in Hong Kong marine waters and detection by real-time PCR

Marine waters from seven sites around Hong Kong with varying levels of sewage pollution were analyzed for Hepatitis A virus (HAV) by PCR cloning and DNA sequencing of the highly variable VP1/2A junction of the HAV genome. Phylogenetic analysis of 10 PCR clones from each of the HAV-positive marine sites indicated that human HAV genotype IB is the most widely distributed type in Hong Kong waters. A sensitive and quantitative TaqMan-based PCR method targeting the 5′-noncoding region (5′-NCR) of HAV was used to quantify HAV particles in marine water samples along with the total Escherichiacoli counts being enumerated on TBX medium for comparison. Our results showed that no correlation of any significance between HAV and E. coli counts was observed which underscores the inadequacy in using E. coli as a sanitary standard to predict the levels of HAV in marine waters.     

Coastal defence through low crested breakwater structures: jumping out of the frying pan into the fire?

The Adriatic coast of Punta Marina (Ravenna) is protected by 3-km long low crested breakwater structures (LCSs). Through a 3-years long multidisciplinar study, we assessed the impact of such defensive structures on environmental and biological condition. LCSs create pools where conditions are very different from the surrounding nearshore system. Mechanical disturbance by currents and waves varied greatly in intensity and frequency between seaward and landward sides of the structures. Sedimentary budget was positive at the landward side, but it was due to a gain on the seafloor and not on the emerged beach. The budget at seaward was negative. LCSs determine differences in benthic assemblages, alter the seasonal pattern of communities, and modify seasonal fluctuations of animal assemblages. Landward sheltered areas can be seen as “lagoonal island” surrounded by a “sea of marine habitat”. Differences in ecological quality status, obtained through M-AMBI, are due to the sum of these factors.     

Ecological status of seagrass ecosystems: An uncertainty analysis of the meadow classification based on the Posidonia oceanica multivariate index (POMI)

Quantifying the uncertainty associated with monitoring protocols is essential to prevent the misclassification of ecological status and to improve sampling design. We assessed the Posidonia oceanica multivariate index (POMI) bio-monitoring program for its robustness in classifying the ecological status of coastal waters within the Water Framework Directive. We used a 7-year data set covering 30 sites along 500 km of the Catalonian coastline to examine which version of POMI (14 or 9 metrics) maximises precision in classifying the ecological status of meadows. Five factors (zones within a site, sites within a water body, depth, years and surveyors) that potentially generate classification uncertainty were examined in detail. Of these, depth was a major source of uncertainty, while all the remaining spatial and temporal factors displayed low variability. POMI 9 matched POMI 14 in all factors, and could effectively replace it in future monitoring programs.     

Morphological and genetic comparison of two strains of a Prorocentrum species isolated from Zhejiang coastal water of China and Masan Bay of Korea

In this paper, we examined the detailed morphology of two strains of Prorocentrum isolated from the coastal waters of Zhejiang (Wenling area), China, and Masan Bay of Korea. A taxonomic comparison was made among strains on the basis of morphological and molecular data. The cellular dimensions of the Chinese Wenling strain (LAMB090508) and Korean strain (PDKS0206) were similar and the cells of both strains were of asymmetric and elongated shape. The posterior end of most cells was rounded. Megacytic zones of aged cells were broader with dense tiny knobs. The roundish nucleus was located in the posterior part of the cell. A few irregular shaped chloroplasts were distributed within the cell. The nucleotide similarity of the two strains, determined from the 5.8S rDNA-ITS sequences, was 99.83%. The comparative results of morphology and molecular analysis suggest that both strains isolated from China and Korea were the identical species, Prorocentrum donghaiense Lu.     

Phaeocystis globosa Scherffel, a harmful microalga, and its production of dimethylsulfoniopropionate

The production of dimethylsulfoniopropionate (DMSP) and its cleavage products (DMS) are well studied in phytoplankton worldwide. However, less is known about their sources, distributions, and impacts in the coast of China. We examined the production of DMSP and DMS in Phaeocystis globosa Scherffel and other benthic macroalgae from the South China coast in relation to environmental conditions. P. globosa was a harmful marine microalgal species and its bloom took place in the eutrophic waters along the South China Sea frequently. It also produced high content of DMSP at different growth stages, with the highest concentration usually observed in the stationary period. Moreover, the production of DMSP in P. globosa was significantly affected by salinity and temperature with the highest contents associated with high salinity (e.g. 40) and low temperature (e.g. 20°C). In field benthic macroalgae, there was also a marked difference in the DMSP of various species or different samples of the same species. Chlorophyll a contents were also determined for each macroalgal species. The highest chlorophyll a (238.7 ng/g fresh weight) was recorded in Chlorophyta Ulva lactuca at Guishan Island (Zhuhai), while the lowest value (1.5 ng/g fresh weight) was found in Rhodophyta Gracilaria tenuistipitata in Zhanjiang. Further correlation analysis indicated that there was no significant relationship between the content of DMSP and chl-a in macroalgae samples (P > 0.05). All the results suggested that the production of DMSP in marine algae was not only species- and stage-related, but also greatly affected by various environmental factors.     

秘鲁外海茎柔鱼渔场时空分布分析

秘鲁外海茎柔鱼是重要的经济性种类,掌握其渔场时空分布规律有助于资源的合理利用。本文根据2003—2004年和2006—2009年我国鱿钓船在秘鲁外海的生产统计和海洋表面温度(SST)等资料,使用空间距离和聚类分析的方法,对其各年间渔场时空分布进行分析比较。结果表明,各年产量重心的分布都存在一定差异,产量重心在经度上随月份整体上呈现向西移动的趋势,在纬度方向上1～6月整体上呈向北移动的趋势,7～12月则表现出向南移动的趋势。聚类分析表明,2003、2006和2008年;2004、2007和2009年空间分布格局各为一类。空间距离分析表明,2006和2009年产量重心差异最大,其中前者平均产量重心为82°23′W、12°53′S,后者为81°47′W、14°27′S,南北相差约1.5个纬度。研究认为,渔场分布的月间变化是由茎柔鱼南北洄游所引起的,年间渔场分布差异与SST等海洋环境关系密切。     

混合光谱分解算法的太湖水体组分浓度反演分析

二类水体组份的遥感定量反演一直是水色遥感的难点和热点问题,原因在于其水体组分(纯水、叶绿素、悬浮物及CDOM)之间复杂的相互作用.本文引入光谱分解算法,通过Hydrolight软件模拟叶绿素、悬浮物和CDOM的标准反射率光谱,解决光谱分解算法中“纯端元”难以获取的问题.在此基础上建立了二类水体组分光谱分解反演模型.模型...