全文获取类型
收费全文 | 1046篇 |
免费 | 211篇 |
国内免费 | 371篇 |
专业分类
测绘学 | 9篇 |
大气科学 | 26篇 |
地球物理 | 144篇 |
地质学 | 1115篇 |
海洋学 | 185篇 |
天文学 | 5篇 |
综合类 | 50篇 |
自然地理 | 94篇 |
出版年
2024年 | 5篇 |
2023年 | 34篇 |
2022年 | 45篇 |
2021年 | 37篇 |
2020年 | 58篇 |
2019年 | 58篇 |
2018年 | 63篇 |
2017年 | 60篇 |
2016年 | 72篇 |
2015年 | 61篇 |
2014年 | 64篇 |
2013年 | 79篇 |
2012年 | 66篇 |
2011年 | 71篇 |
2010年 | 55篇 |
2009年 | 70篇 |
2008年 | 65篇 |
2007年 | 70篇 |
2006年 | 73篇 |
2005年 | 63篇 |
2004年 | 47篇 |
2003年 | 49篇 |
2002年 | 49篇 |
2001年 | 59篇 |
2000年 | 47篇 |
1999年 | 50篇 |
1998年 | 29篇 |
1997年 | 19篇 |
1996年 | 23篇 |
1995年 | 14篇 |
1994年 | 17篇 |
1993年 | 18篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1628条查询结果,搜索用时 174 毫秒
21.
Janet M. Hergt L. Paul Bédard Etienne Deloule Klaus Peter Jochum Kathryn L. Linge Paul J. Sylvester Matthias Willbold Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142
In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields. 相似文献
22.
This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials. 相似文献
23.
CHEN Tianhu XU Huifang WANG Yifeng QING Chengsong FAN Mingde CHEN Gang 《《地质学报》英文版》2006,80(2):170-174
Although hydrotalcite, or layered double hydroxides (LDHs), is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of (Mg, Al)-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like (Mg, Al)-oxide is transformed into a composite with periclase (MgO) and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition. 相似文献
24.
High-frequency (≥2 Hz) Rayleigh wave phase velocities can be inverted to shear (S)-wave velocities for a layered earth model up to 30 m below the ground surface in many settings. Given S-wave velocity (VS), compressional (P)-wave velocity (VP), and Rayleigh wave phase velocities, it is feasible to solve for P-wave quality factor QP and S-wave quality factor QS in a layered earth model by inverting Rayleigh wave attenuation coefficients. Model results demonstrate the plausibility of inverting QS from Rayleigh wave attenuation coefficients. Contributions to the Rayleigh wave attenuation coefficients from QP cannot be ignored when Vs/VP reaches 0.45, which is not uncommon in near-surface settings. It is possible to invert QP from Rayleigh wave attenuation coefficients in some geological setting, a concept that differs from the common perception that Rayleigh wave attenuation coefficients are always far less sensitive to QP than to QS. Sixty-channel surface wave data were acquired in an Arizona desert. For a 10-layer model with a thickness of over 20 m, the data were first inverted to obtain S-wave velocities by the multichannel analysis of surface waves (MASW) method and then quality factors were determined by inverting attenuation coefficients. 相似文献
25.
26.
地下管线探测工程的资料自动化整理 总被引:1,自引:0,他引:1
地下管线探测工程一般分为野外探测和室内资料整理两阶段。内业整理包括成果表的编制、管线综合分布平面图和管线数据库。由于管线探测工程数据多,为了充分利用外业探测成果,应用Visual Basic 6.0(VB6)开发了一套地下管线管理信息系统(UTMIS),该系统实现了地下管线探测工程内业整理的自动化,极大地提高了工作效率数据精确度。 相似文献
27.
28.
Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses 总被引:9,自引:0,他引:9
Stephen M. Eggins 《Geostandards and Geoanalytical Research》2003,27(2):147-162
A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis. 相似文献
29.
William J. Chazey III Clive R. Neal Jinesh C. Jain William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192
The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1). 相似文献
30.
The rate of the reversible homogeneous disproportionation of polysulfides was studied by following the optical absorbance of polysulfide solutions in a continuous plug flow reactor equipped with an on-line photometric detector. In order to avoid heterogeneous slow reactions involving sulfur colloids or precipitate, the reaction was initiated by an abrupt pH change from an undersaturated solution containing predominantly tetrasulfide species to a pH where pentasulfide is the dominant species. The disproportionation was found to follow first order reversible reaction dynamics. At environmentally relevant conditions the characteristic time of the disproportionation reaction is of the order of 10 s. This characteristic time implies that necessary conditions for speciation of the different polysulfide species by chromatography or another separation and subsequent quantification scheme should be of the order of 1 s. 相似文献