热采条件下储集岩的软化及其防治

许多储集岩经蒸汽和热水处理后,可产生明显的软化作用。这种软化作用主要是由于白云石、高岭石和石英的部分破坏和生成蒙脱石。在这种情况下,软化作用是相当大的,直至足以引起储集岩中支撑裂隙的显著愈合,因而,能导致钻井产能的显著减少。已经发现把一些物质（ＲＡ） 添加到热液中,不仅能够防止岩石软化,而且能使岩石硬化。这一效果来源于岩石中原始粘土矿物的改变和新生矿物相的重结晶和重新取向     

下寺湾油田柳洛峪地区长8储层配伍性实验研究

柳洛峪地区长8地层水属CaCl2型,地层结垢伤害主要为BaSO4垢引起。注入水为长2地层水,水型及组成与长8地层水类似。配伍实验结果表明:单一水样在不同温度和压力下表现为随着温度、压力的升高,出现CaCO3结垢趋势变大,而BaSO4结垢趋势减弱。注入水与磨碎的岩心混合后生成的白色沉淀物主要为BaSO4和CaCO3。不同比例混配水样实验结果显示,提高注入水的比例可以有效地减少混合液产生的沉淀量。同时,随着注入水的不断注入,岩心渗透率变化较小,表明混配水几乎不会对储层造成伤害。     

A new look at pulsar statistics — Birthrate and evidence for injection

We make a statistical analysis of the periodsP and period-derivativesP of pulsars using a model independent theory of pulsar flow in theP-P diagram. Using the available sample ofP andP values, we estimate the current of pulsars flowing unidirectionally along theP-axis, which is related to the pulsar birthrate. Because of radio luminosity selection effects, the observed pulsar sample is biased towards lowP and highP. We allow for this by weighting each pulsar by a suitable scale factor. We obtain the number of pulsars in our galaxy to be 6.05_−2.80 ^+3.32 × 10⁵ and the birthrate to be 0.048_−0.011 ^+0.014 pulsars yr⁻¹ galaxy⁻¹. The quoted errors refer to 95 per cent confidence limits corresponding to fluctuations arising from sampling, but make no allowance for other systematic and random errors which could be substantial. The birthrate estimated here is consistent with the supernova rate. We further conclude that a large majority of pulsars make their first appearance at periods greater than 0.5 s. This ‘injection’, which runs counter to present thinking, is probably connected with the physics of pulsar radio emission. Using a variant of our theory, where we compute the current as a function of pulsar ‘age’ (1/2P/P), we find support for the dipole braking model of pulsar evolution upto 6 × 10⁶ yr of age. We estimate the mean pulsar braking index to be 3.7_−0.8 ^+0.8.     

人为因素导致的地面沉降

天然气、石油、地下水、地热热水和卤水等流体运移出地下储存地层时,地层耗尽了流体而产生压缩变形,这些变形传递到地表表面就形成了人为的地面沉降。在本文中:(1)列举了世界上主要的地面沉降区域;(2)论述了引发地面沉降的力学机制,这些可以量测的地面沉降发生在地下含水层体系、天然气气田和石油油田之上;(3)描述了目前可以用于地面沉降测量和岩石变形原位测试的技术手段;(4)简要介绍了几个地面沉降预测的数值模型;(5)说明了用于控制地面沉降发展和减轻相关环境影响的几种防治措施。     

流动注射-光度法测定地质样品中痕量碘

利用I~-对4,4′-四甲基二氨基二苯甲烷(4,4′-TMB-DPM)与氯胺T反应的催化作用,建立了流动注射-分光光度测定地质样品中痕量碘的方法。采用不等流速合并带法,分析速度快、节省试剂、灵敏度高。与高温水解法释放I~-相结合,使样品处理简单、干扰离子少。对于含I~-10μg/L的水样,其RSD(n=19)为1.1％,检出限为0.3ng/ml。用于水系沉积物、土壤分析时,含碘1.6×10~(-6)的样品RSD(n=10)为6.1％,检出限为0.08×10~(-6)。测量速度50N/h。     

FEM for stability analysis against overturning of portal water injection sheet pile

Portal water injection sheet pile （PWISP）, as a retaining wall, appeared in seashore engineering in 2000. Although there have been many systematic methods addressing the issue, there are very few focusing on the new structure because of the difficulties in defining the earth pressure between the two piles. A new method is proposed in this paper to obtain the earth pressure between the PWISPs. Stability analysis against overturning follows as a consequence. Using Finite Element Analysis （FEA） software ANSYS, both the nonlinear characteristics of the soil and those of the contact elements are taken into account to obtain the earth pressure distribution on the contact surface. Based on the results of the FEA, Rankin＇s theory and the slip plane theory, the formula of the earth pressure on the inner surfaces between the piles is given. Assuming the PWISP as the analysis object and the earth pressure as an outside force acting upon it, the equation of stability against overturning of the PWISP is presented. Finally, some parameters are discussed about the stability of the PWISP against overturning, such as the embedded depth of the front pile, the distance between the two rows of piles, the internal friction angle and the cohesion of the earth. The results show that the increase of the cohesion and the internal friction angle will decrease the distance and the embedded depth, and therefore enhance the stability against overturning. Specifically, when the distance is 1/3-2/3 of the maximal excavation depth, the two rows of piles give the best performance in stability.     

无因次等孔隙体积配产配注方法研究与应用

为了改善注水开发效果差的情况,对无因次等孔隙体积配产配注理论改善注水开发效果的方法进行了研究。针对高30断块油藏,分别使用无因次等孔隙体积法和传统的kh值计算其合理配产配注量,接着采用油藏数值模拟进行了无因次等孔隙体积配产配注法和传统的kh法在该断块油藏注水开发的对比预测。结果表明,相比kh法,无因次等孔隙体积法使油田有效开发时间延长27年,采出程度由22．46％提高到27．94％,提高5．48％,增产原油19．88×10^4t。所以采用无因次等孔隙体积配产配注法比传统kh配产配注法更加符合油藏实际,使有效开发年限更长,最终水驱采收率更高。该方法可以为同类注水开发油藏的合理配产配注提供参考。     

聚合物驱组合段塞分注实验研究

萨尔图油田南二区东部140号断层以东地区葡11—4油层,以多段多韵律和正韵律沉积为主,平均孔隙度30．0％,平均空气渗透率1980×10^-3μm2。水驱结束时该油层平均含水92％,采出程度39．5％。计划对该区块实施聚合物驱开采。以往经验认为,组合段塞调整注聚技术能够有效改善流度控制作用。然而对组合注入情况下如何进一步提高驱油效果、注入井分注时机、层段注入强度对开发效果有何影响却很少探讨。通过室内驱油实验,在聚驱的组合段塞注入不同时机（水驱空白阶段、含水下降阶段、含水稳定阶段、含水回升阶段）下调整注入强度实施分注以及在含水回升分注基础上进一步调整注入强度,同时对比不分注实验,评价各方案驱油效果。实验表明：不实施分注时聚驱采收率在水驱基础上提高了19．07个百分点,而组合段塞注入时实施分注均能够在不分注基础上进一步提高驱油效果;空白水驱时实施分注采收率提高幅度最大,为26．55个百分点;随着分注时机的滞后采收率提高幅度增加值依次递减,分注时机越早越好。     

基于微地震技术的油田裂缝监测及模拟

研制了1套以三分量MEMS检波器为核心硬件的微地震监测系统,并结合GPS系统对监测过程进行精确授时.同时编制数据化记录和处理软件,实现网络化自动监测功能;通过开发计算机判别标准和实时定位理论系统,对数据和微震源进行自动化处理和计算.利用该系统对东辛油田营11进行了6个月现场注水微震监测,对监测数据的处理表明营11注水区域裂缝发育方向基本上为NE90°-NE125°,与地应力裂缝模拟结果相符较好,两者结合给出了这个地区合理开发部署建议.     

A laboratory study on capillary sealing efficiency of Iranian shale and anhydrite caprocks

Caprock has the most important role in the long term safety of formation gas storage. The caprocks trap fluid accumulated beneath, contribute to lateral migration of this fluid and impede its upward migration. The rapid upward passage of invasive plumes due to buoyancy pressure is prevented by capillary pressure within these seal rocks. In the present study, two main seal rocks, from the Zagros basin in the southwest of Iran, a shale core sample of Asmari formation and an anhydrite core sample of Gachsaran formation, were provided. Absolute permeabilities of shale and anhydrite cores, considering the Klinkenberg effect, were measured as 6.09 × 10⁻¹⁸ and 0.89 × 10⁻¹⁸ m², respectively. Capillary sealing efficiency of the cores was investigated using gas breakthrough experiments. To do so, two distinct techniques including step by step and residual capillary pressure approaches were performed, using carbon dioxide, nitrogen and methane gases at temperatures of 70 and 90 °C, under confining pressures in the range 24.13–37.92 MPa. In the first technique, it was found that capillary breakthrough pressure of the cores varies in the range from 2.76 to 34.34 MPa. Moreover, the measurements indicated that after capillary breakthrough, gas effective permeabilities lie in range 1.85 × 10⁻²¹ – 1.66 × 10⁻¹⁹ m². In the second technique, the minimum capillary displacement pressure of shale varied from 0.66 to 1.45 MPa with the maximum effective permeability around 7.76 × 10⁻²¹ – 6.69 × 10⁻²⁰ m². The results indicate that anhydrite caprock of the Gachsaran formation provides proper capillary sealing efficacy, suitable for long term storage of the injected CO₂ plumes, due to its higher capillary breakthrough pressure and lower gas effective permeability.