北京地区百花山、东灵山表土花粉的特征分析

本文分析了北京地区百花山、东灵山两个垂直带谱不同植被类型的表土花粉，通过表土花粉百分比和浓度图式分析，结合垂直带谱的植被特征，初步回答了某些植物科属表土花粉与其植被的特征关系，并试图结合植物科属花粉产量的特征、散布能力、保存条件及地形特征对表土花粉中一些植物科属的代表性作了探讨，从而为依据化石孢粉恢复北京地区乃至华北地区的历史植被和环境提供了重要参考资料。     

线性模型下的不完全样本

设有线性模型Y=xβ+ε,这里Y是一个m维随机向量,x是一个已知m×p阵,ε是一个m维随机误差向量,E_ε=0,V_(αγε)=σ~2Im,β和σ~2>0都是未知的。设我们得到子样Y_1,Y_2,…,Y_n,由于某些原因,Y_i(i=1,2,…,n)的某些分量得不到,我们称此为不完全样本。本文得到了所有β的可估线性函数、所有叶估线性函数的LSE以及基于残差的σ~2的无偏估计在完全样本与不完全样本下相同的充要条件。     

Characterisation of the carbonate content of atmospheric aerosols

A programme of aerosol sampling by dichotomous sampler has been undertaken with analysis of soluble ions plus carbonate. The technique for carbonate involved release of CO₂ by HCl vapour and quantitative measurement of the CO₂ by FTIR spectroscopy. The method is suitable for amounts down to below 10g CO₃ ^2- per filter. The prevailing atmospheric levels in an urban area were found to be below 1g m^-3. Information on the particle size from the dichotomous sampler was supplemented by use of a cascade impactor. Although CaCO₃ is clearly the dominant species initial analyses demonstrated higher carbonate levels than could be accounted for on the basis of the concentrations of calcium and magnesium ions which are the most likely cations in mineral carbonates. Analysis with and without heating to 100°C in a vacuum oven demonstrates the presence of carbonate in volatile form. This could be due to carbon dioxide adsorbed onto particulate matter such as soot.     

Seismic hazard in East Africa: An example of the application of incomplete and uncertain data

Earthquake hazard parameters maximum regional magnitude M _max and annual activity rate , and the b parameter of the Gutenberg-Richter relation have been evaluated for parts of East Africa. The applied maximum likelihood method permits the combination of both historical and instrumental data available (the catalog used here covers the interval 1880–1979). In addition, the uncertainty involved in magnitude determination and thresholds of completeness were taken into account. The hazard-parameter determination was performed for two study areas corresponding to segments of the eastern and western branches of the East African rift system. The results for these areas show differences that can be partly explained through the characteristics of the data.     

磷酸沉淀分离-电感耦合等离子体质谱法测定化探样品中的痕量银

应用电感耦合等离子体质谱法(ICP-MS)分析化探样品中的痕量银,通常在标准模式下用干扰校正法或动能歧视模式进行测定。银的两个稳定同位素均受锆和铌的氧化物或氢氧化物的质谱干扰,对于干扰元素锆、铌含量较高而银含量低的样品,测定误差较大,需要将干扰元素与银分离。本方法采用硝酸、氢氟酸、高氯酸消解样品,浓盐酸复溶提取,加入磷酸使大部分溶出的干扰元素锆、铌转化为难溶的磷酸盐化合物,通过沉淀与待测元素银分离。ICP-MS测定时以~(103)Rh为内标,用~(90)Zr~(16)O~+同质量数的同位素~(106)Pd间接校正~(91)Zr~(16)O~+、~(90)Zr~(16)O~1H~+对~(107)Ag的质谱干扰。经国家一级标准物质验证,分析结果在标准值的允许误差范围内,相对标准偏(n=12)为4.3%～12.1%,方法检出限(3SD)为0.0072μg/g。本方法适合土壤、水系沉积物及岩石等化探样品中痕量银的分析。样品处理中引入的磷酸不影响其他常规元素,可用同一份消解液进行测定。     

P507负载泡塑分离ICPMs测定地质样品中的痕量银

结合前人研究工作,利用P507可有效分离银ICPMS测定的Zr,Nb等干扰元素,对P507负载泡塑分离ICPMs测定地质样品中的痕量银进一步验证讨论,以便该方法在行业内领域得以广泛应用,促进行业内地质样品中Ag及微量元素测试的效率与测试技术的提高,实现地质样品中痕量银及微量元素ICPMS同步快速准确分析。     

钾长石矿物在全新世样品光释光测年中的应用与校正问题

使用钾长石进行释光测年时,由于长石的释光信号存在异常衰减,会导致沉积事件年龄的低估。对中国北方4个全新世样品分别使用石英和钾长石矿物组分释光测年,通过测量钾长石的衰退系数(g值)对钾长石使用再生剂量法获得的表征年龄进行了校正。发现对于本文所研究的年轻样品钾长石表征年龄与石英年龄相比系统偏小约2％～9％,钾长石校正年龄与石英年龄相比则严重偏大约16％～40％,表明使用g值无法校正年轻样品的钾长石年龄。对于年轻样品,钾长石IRSL信号异常衰减现象对测年结果的影响是可以忽略的。     

Electron Probe Microanalysis of Environmental Samples: Preparation of Reference Materials, Correction for Particle Size Effects and Representative Results on Sediments Recovered from Snow, Power Station Fly Ash and Bone Samples

In this paper we report the results of electron probe X-ray microanalysis (EPMA) that was used to study environmental materials. The mode of preparation and certification of reference samples based on a basaltic glass matrix for environmental applications of EPMA is described. These samples were prepared containing scandium, strontium and barium (from 0.03 up to 7% m/m) and an evaluation was made of homogeneity, their stability to local heating, followed by analysis by independent methods for certification of composition. Matrix correction procedures for the EPMA technique have been developed for particles having a size commensurable with the volume of X-ray generation. An analytical equation for the size factor is proposed and two techniques for selecting optimum conditions for the analysis of environmental samples by EPMA are reported. These procedures provided satisfactory results when utilized in analysing sediments recovered from snow, coal fly ash and the bones of animals and fish, results from which can be used as indicators for evaluating the pollution level of the lower atmosphere, surface and ground water, as well as revealing pollution mechanisms.     

在线萃取－火焰原子吸收测定地质样品中的痕量金

利用流动注射在线萃取技术，以ＭＩＢＫ为萃取剂，用火焰原子吸收分析方法测定地质样品中的痕量金，取得了满意的效果。该法精密度好，无污染，操作简便，测定迅速，且样品不需分离。方法检出限Ａｕ为０．７８×１０－９，精密度为２．３０％。     

探测受压岩样破裂区域的CT试验方法

本文对应用SYC 系列声波仪探测室内受压岩样破裂区域的试验技术进行了分析,提出了一种在稳压阶段及卸荷后测量声波走时的试验方法,并通过试验对时间因素及卸荷产生的走时误差进行了初步探讨,证明这种试验方法是可行的。