湖南走马坪多金属成矿区矿化特征及成因探讨

湖南走马坪矿区是以钨、锡、铅、锌、银矿化为主的多金属成矿区，文章对其矿化特征作了总结，在此基础上分析其成因，并提出了找矿方向。     

云南老王寨金矿区煌斑岩中碳酸盐的化学成分及其意义

本文报道了云南老王寨金矿区非矿化、矿化煌斑岩中不同产状碳酸盐的化学成分，结果表明本区煌斑岩中为次生碳酸盐，原生碳酸盐含量不超过１％；煌斑岩蚀变、矿化为不同阶段的产物；碳酸盐脉活动发生在成矿作用之后。     

Synthesis and characterization of zeolite X obtained from kaolin for adsorption of Zn（Ⅱ）

This study deals with the synthesis and characterization of low-silica zeolite X, from calcined Kalabsha kaolin, for adsorption of Zn(Ⅱ) ions from aqueous solution. The synthesis processes is performed under hydrothermal treatment in alkaline solutions. The obtained zeolite samples are characterized using X-ray diffraction, grain size distribution, surface area, and SEM. The critical molar ratios of both SiO2/Al2O3 and K2O/Na2O are about 2.9 and 0.16, respectively. Those ratios are needed to give individual low silica zeolite X in a minimum reaction time. The adsorption capacity of the synthesized products is determined by adsorption of Zn(Ⅱ) ions from solution. The results suggest that the zeolite obtained could be converted to a beneficial product, which will be used in future as an ion exchanger in removing heavy metals from wastewaters.     

The magmatic–hydrothermal transition—evidence from quartz phenocryst textures and endoskarn abundance in Cu–Zn skarns at the Empire Mine, Idaho, USA

Information about the magmatic to hydrothermal transition is preserved in late-stage features of quartz phenocrysts and endoskarn alteration in some Cu–Zn skarn deposits such as the Empire Mine in Idaho. Important features include: (1) quartz phenocrysts with strong resorption textures such as vermicular zones of igneous groundmass cutting primary quartz cathodoluminescence banding, (2) anomalous amounts of endoskarn (more than 50% of mineralized rock), (3) high F activities as evidenced by fluorite as an accessory mineral in igneous rocks, in alteration assemblages, and in fluid inclusions and by high F in hydroxyl sites in igneous biotite and amphibole, and (4) direct association of Zn, which normally is deposited distally at low temperature, with Cu in proximal locations and in endoskarn. These features are explained by the following model: (1) F lowers the solidus temperature of the magma, thus changing the timing, temperature, and duration of hydrothermal fluid exsolution. (2) Upon magmatic vapor saturation the F-rich hydrothermal fluids form bubbles that adhere to quartz phenocrysts and chemically corrode/tunnel into the quartz forming vermicular resorption textures. (3) F-rich hydrothermal fluids also promote the formation of endoskarn; silicic rocks are attacked by F-rich fluids in the same sense that carbonate wall rocks are dissolved by weakly to moderately acidic hydrothermal fluids. (4) Low fluid exsolution temperature facilitated by high F activity promotes high Zn/Cu ratios in proximal locations due to the solubility of Zn relative to Cu at lower temperatures. This model may be applicable at other localities such as the world-class Cu–Zn skarn Antamina mine, as well as some tin and rapakivi granites.     

金属矿床的同位素直接定年方法

矿床的直接定年就是直接对成矿流体或矿石矿物进行同位素定年 ,这样确定的年龄就直接代表了成矿年龄。目前主要有石英和闪锌矿中流体包裹体的Rb Sr同位素定年、黄铁矿和石英中包裹体的Ar Ar同位素定年、金属硫化物的Rb Sr同位素定年、金属硫化物和氧化物的Sm Nd同位素定年、金属硫化物的Re Os同位素定年 ,以及单个矿石矿物的Pb逐步淋滤法定年     

华南花岗岩型铀矿床成矿机理研究进展

本文介绍了华南花岗岩型铀矿床地质特征,系统总结了前人对其成矿热液来源、物质来源,铀的迁移沉淀机制、碱交代及花岗岩与成矿的关系等方面的研究成果。指出铀源体中的晶质铀矿及富铀矿物在深部相对还原的环境中被氧化而进入成矿热液中起主要作用的可能是大量幔源F和放射性衰变诱发产生的氧及碱交代溶蚀作用,热液中的大部分U6 主要被S2-和Fe2 等还原剂在浅部相对氧化的环境中还原成矿;给出了一种较简易的物质来源定量方法和铀成矿模式。     

河南千鹅冲钼矿地球化学异常特征及找矿模型

河南省光山县千鹅冲钼矿是近年在大别山北麓发现的特大型隐伏斑岩钼矿床。通过梳理该矿床从发现到突破近30年的找矿历程,研究矿床成矿地质特征及与矿床相关的元素区域异常、局部异常和原生异常特征,总结了该钼矿地球化学找矿标志及找矿模型。该矿床的找矿实践又一次证明了斑岩型钼矿化探具有较好的找矿效果,无论是1∶20万、1∶5万水系沉积物测量,还是1∶1万土壤测量或钻孔岩石测量等方法,均能揭示斑岩型钼矿的指示元素,并具有良好的找矿指示作用。     

灰岩碳氧同位素特征与隐伏花岗岩的关系——以栗木水溪庙矿区为例

对栗木水溪庙矿区泥盆系上统融县组灰岩的碳氧同位素进行了研究,该地区灰岩的碳氧同位素组成可提供隐伏花岗岩隆起及其相关流体的重要信息。受隐伏花岗岩侵入驱动的流体与上覆融县组灰岩发生反应的温度在110℃左右,流体的初始同位素组成为δ18OSMOW=-3‰,δ13CPDB≤-7‰,反应的水岩比值（w/r）可能小于5。这种岩浆水与大气降水的混合流体与围岩之间的水岩反应使得地表灰岩的δ18O和δ13C值降低,产生负异常。研究表明,围岩的δ18O值降低受反应的水岩比值和温度控制;δ13C值降低主要与反应的水岩比值有关。反应的温度越高,w/r值越大,灰岩的碳氧同位素负异常越明显。因此,水溪庙矿区地表出露的碳酸盐地层中的碳氧同位素变化可在地球化学勘查中用于指示下伏花岗岩岩脊的隐伏位置。     

狼山-渣尔泰山成矿带铁铜铅锌多金属硫化物矿床特征研究

狼山-渣尔泰山多金属成矿带位于华北地台北缘西段的中元古代被动陆缘裂陷槽内,其产出的多处大型-超大型铜、铅、锌、铁多金属硫化物矿床的矿床特征具相似性和可对比性。通过分析该成矿带的区域地质背景、含矿建造特征及其产出的典型矿床（东升庙、炭窑口、霍各乞、甲生盘）的矿床地质特征,得出该成矿带内铜铅锌铁多金属硫化物矿床的以下特征：①盆地控矿特征十分明显;②成矿过程中伴有与成矿作用关系密切的同生断裂活动和同沉积期火山活动;③成矿元素具分带性和规律性组合的特征;④各典型矿床具鲜明的“时控”、“层控”和“岩控”特点;⑤成矿作用具有间歇性和多期演化成矿的特征;⑥含矿建造具有典型地球化学剖面结构序列特征;⑦矿体的产状与含矿岩系一致,且相应类型的矿石对应相应的容矿岩性。     

兰坪—思茅盆地红层铜矿成矿规律

兰坪—思茅地洼盆地中新生代红层铜矿可分为三个成因类型:沉积型,沉积-改造型和改造型。它们呈“层—梯”式产出。在成因上与热卤水活动有关。在分布上受澜沧江断裂和中轴断裂控制。微量和稀土元素及同位素地球化学研究表明,成矿物质以壳源为主。成矿热动力与成矿期区域性幔热异常和强烈的构造活动有关。矿床形成于两个时期,即地洼初动期的沉积—成岩矿化期(T_3-E_1)和地洼激烈期的改造成矿期(E_2)。其中,改造成矿是本区铜矿最重要的成矿过程。