煤田地质超深孔钻探工艺

在对深部煤田地质钻孔钻进工艺研究的基础上,有针对性选择使用聚合物泥浆,解决了基浆配制用水及泥浆抗地表水水质污染问题。通过改变双管钻具长度和改换取心钻头的切削具,满足软硬互层对钻头钻进效率的影响。在煤系地层钻进中,除采用常规的单管钻具钻进外,在见煤预告下过后,采用加长双管取心钻具,既可保证了回次进尺,又可保证岩心的采取。多项措施落实,不仅解决了生产中的一些难题,收到了较好的效果,而且创造了河北省煤田地质局煤田地质单孔钻探深度2 009.12m的新纪录,为今后深部钻孔的施工积累了经验。     

CFRP布约束增强高强混凝土柱抗震性能数值分析

采用地震工程开源模拟软件OpenSees（Open System for Earthquake Engineering Simulation）对CFRP（Carbon Fiber Reinforced Polymer,碳纤维增强复合材料）布加固高强钢筋混凝土方柱的抗震性能进行了数值分析。采用Steel02Material和Concrete02Material材料本构模型模拟了CFRP布加固高强混凝土方柱的抗震性能;在此基础上,进一步研究了轴压比和剪跨比这2个因素对试件抗震性能的影响。将所得数值分析结果与相同条件下的试验结果对比后发现：基于Steel02 Material和Concrete02 Material材料本构,利用OpenSees,可以较好地模拟CFRP布加固高强混凝土方柱的抗震性能,并且与试验结果（滞回曲线、骨架曲线、水平承载力和位移延性系数）能够较好地吻合,从而说明该数值分析方法还可以准确地反映出轴压比和剪跨比对高强混凝土柱抗震性能的影响规律。     

基于性能的碳纤维抗震加固设计

本文探讨了基于性能的加固设计的基本思路和设计过程,并给出了一个基于性能的碳纤维加固设计的工程实例,采用pushover静力推覆分析的方法分析对比了结构加固前后的性能,表明原结构的抗震性能不足,经碳纤维加固后的结构抗震性能明显提高,满足8度抗震设防烈度要求。     

纳微米聚合物微球的水化膨胀封堵性能

为改善聚合物微球的深度调剖效果,利用蒸馏沉淀聚合法制备纳微米聚合物微球,并利用激光粒度分析仪、微孔滤膜装置和驱替装置对纳微米聚合物微球的粒径、水化膨胀能力和变形封堵能力进行测试分析.结果表明:纳微米聚合物微球为较规则均匀的球形,粒径分布集中,具有良好的水化膨胀性能;随着盐矿化度增大,纳微米聚合物微球膨胀性能变差;随着温度升高,微球的膨胀性能变强;在氯化钙和氯化镁水型中,微球膨胀性能变差;在酸性和碱性环境中,微球膨胀性能变差;随着水化时间增长,微球的封堵性能和变形能力逐渐增强,对孔道产生有效封堵的同时又能变形通过孔道,在渗透率较低的岩心中具有更好的深度调剖效果.     

高温高盐高黏油藏缔合聚合物-表面活性剂二元驱技术

针对大港油田孔南地区高温、高盐、中低渗、稠油等制约化学驱提高采收率的瓶颈技术问题,以官109 1断块枣Ⅴ油组为目标油藏,在优选适合缔合聚合物和表面活性剂基础上,进行聚合物-表面活性剂二元驱技术室内实验和现场应用研究。通过室内实验优选,缔合聚合物AP P7和表面活性剂BHS 01二元体系溶液与常规体系相比,具有较好的耐温抗盐性,拓展了常规二元驱适用油藏的温度和矿化度范围;缔合聚合物经过岩心剪切后仍能够有效建立阻力系数和残余阻力系数;通过岩心驱替实验,体系能有效提高稠油油藏的采收率,拓宽了聚合物驱适用的原油黏度范围;矿场单井试注后,注入井注入压力和启动压力升高,纵向吸水剖面得到改善,说明该体系在高温高盐条件下仍能保持较高黏度,能够有效改善水油流度比,效果明显。     

Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

The Effects of Hydrophilic Polymer and Soil Salinity on Corn Growth in Sandy and Loamy Soils

The interaction effects of different applied ratios of a hydrophilic polymer (Superab A200) (0, 0.2, 0.6% w/w) under various soil salinity levels (initial salinity, 4 and 8 ms/cm) were evaluated on available water content (AWC), biomass, and water use efficiency for corn grown in loamy sand and sandy clay loam soils. The results showed that the highest AWC was measured at the lowest soil salinity. The application of 0.6% w/w of the polymer at the lowest salinity level increased the AWC by 2.2 and 1.2 times greater than those of control in the loamy sand and sandy clay loam soils, respectively. The analysis of variance of data showed that the effect of salinity was significant on biomass and water use efficiency of corn in the loamy sand and sandy clay loam soils. The highest amounts of these traits were measured in soils with the lowest salinity level. Application of polymer at the rate of 0.6% in the loamy sand soil and at the rate of 0.2% in the sandy clay loam soil resulted in the highest aerial and root biomass and water use efficiency for corn. At these polymer rates the amounts of water use efficiency for corn were 2.6 and 1.7 times greater than those of control in the loamy sand and sandy clay loam soils, respectively. Thus, the use of hydrophilic polymer in soils especially in the sandy soils increases soil water holding capacity, yield, and water use efficiency of plant. On the other hand, decreases the negative effect of soil salinity on plant and helps for irrigation projects to succeed in arid and semi‐arid areas.     

注聚调驱井聚合物堵塞物的矿物复合结构形貌及组成特征

胜利油田渤19区块注交联聚合物开采多年后,因注入水的水质不达标导致聚合物过度交联形成强凝胶,造成聚合物注入区块许多油水井的堵塞。对现场聚合物垢样品所做的化学组分、表面元素能谱及红外光谱的研究表明,垢的主体结构由交联的聚丙烯酰胺组成,交联体吸收了大量水分,在交联体内小环境中因富集而形成氯化物矿物晶体无机垢结构,而在成垢的过程中又将地层内的一些粘土矿物包裹于交联体内,形成具有聚合物-矿物复合结构的强胶凝态物质,严重影响聚合物注入—调剖—驱油过程中的聚合物溶液的流动。     

水敏性地层钻探用接枝淀粉聚合物泥浆体系研究

以接枝淀粉共聚物为降失水荆,选择抑制荆、防塌剂、润滑剂、包被剂、膨润土等处理剂,优化设计了水敏性地层用接枝淀粉聚合物泥浆体系。经过测试,该体系的API失水为7ml,相对膨胀降低率84．2％,岩屑回收率92％,摩阻系数0．07。该体系在水敏性地层的钻探施工中取得了良好的使用效果。