国内外泥浆材料的现状及发展趋势

系统介绍了泥浆材料的现状及发展趋势，重点叙述了水基泥浆、油基泥浆及合成基泥浆这3大类泥浆材料的现状及发展趋势。     

吉林省油页岩勘探中聚合物钻井液防塌机理的试验研究与应用

在试验研究的基础上对比了无机聚合物硅酸盐和有机聚合物聚乙烯醇(PVA)、部分水解聚丙烯酰胺(PHPA)和非水解聚丙烯酰胺(PAM)的防塌能力;由试验得出吸附成膜的速度和保护膜的致密程度是决定钻井液体系防塌能力的关键因素;钻井液体系的防塌能力是无机聚合物和有机聚合物协同作用的结果;部分水解聚丙烯酰胺钻井液体系的防塌能力较非水解聚丙烯酰胺钻井液体系的防塌能力强。研制的无固相聚合物钻井液在吉林农安、伊通、舒兰和梅河口4个矿区近3 000 m的钻探施工中,孔壁稳定,孔内事故少,岩芯采取率达98%以上。     

Kinetics of bubble collision and attachment to hydrophobic solids: I. Effect of surface roughness

Influence of surface roughness of the Teflon plates on kinetics of the bubble attachment was studied. Phenomena occurring during collisions of the air bubble, rising in clean water, with Teflon plates, differing only in their surface roughness, were recorded and analysed using a high-speed camera. Variations of the local velocity of the bubble during the collisions and the time of the bubble attachment were determined. It was found that the Teflon surface roughness was the parameter of a crucial importance for the attachment time of the colliding bubble. Depending on degree of the surface roughness the time of the attachment varied by over order of magnitude (from 3 to over 80 ms). In the case the Teflon surfaces having roughness below 1 μm there were recorded four to five “approach–bounce” cycles prior to the bubble attachment. Moreover, after the first collision the rapid pulsations of the bubble shape (within fraction of millisecond) were recorded. For surfaces of roughness ca. 50 μm and larger the attachment always occurred during the first collision—there was no bouncing observed and the time of the attachment was below 3 ms. It was documented that presence of a micro-bubble at the surface facilitated attachment of the colliding bubble.     

旋挖钻机聚合物泥浆施工技术浅探

通过对聚合物泥浆护壁机理的分析,简要叙述了聚合物泥浆的性能特点,为在旋挖钻孔工艺中应用聚合物泥浆,总结了聚合物泥浆的制备、回收、净化、排放方法,优化了施工时泥浆循环系统的布置方案。结合工程实践,指出了旋挖钻进时应注意的问题和对一些易出现问题的处理方法,对旋挖钻机应用聚合物泥浆施工时具有一定的指导意义。     

Molecularly imprinted polymers for selective extraction of crystal violet from natural seawater coupled with high-performance liquid chromatographic determination

Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%.     

Uplift of symmetrical anchor plates by using grid-fixed reinforced reinforcement in cohesionless soil

Uplift response of symmetrical anchor plates with and without grid fixed reinforced （GFR） reinforcement was evaluated in model tests and numerical simulations by Plaxis. Many variations of reinforcement layers were used to reinforce the sandy soil over symmetrical anchor plates. In the current research, different factors such as relative density of sand, embedment ratios, and various GFR parameters including size, number of layers, and the proximity of the layer to the symmetrical anchor plate were investigated in a scale model. The failure mechanism and the associated rupture surface were observed and evaluated. GFR, a tied up system made of fiber reinforcement polymer （FRP） strips and end balls, was connected to the geosynthetic material and anchored into the soil. Test results showed that using GFR reinforcement significantly improved the uplift capacity of anchor plates. It was found that the inclusion of one layer of GFR, which rested directly on the top of the anchor plate, was more effective in enhancing the anchor capacity itself than other methods. It was found that by including GFR the uplift response was improved by 29%. Multi layers of GFR proved more effective in enhancing the uplift capacity than a single GFR reinforcement. This is due to the additional anchorage provided by the GFR at each level of reinforcement. In general, the results show that the uplift capacity of symmetrical anchor plates in loose and dense sand can be significantly increased by the inclusion of GFR. It was also observed that the inclusion of GFR reduced the requirement for a large L/D ratio to achieve the required uplift capacity. The laboratory and numerical analysis results are found to be in agreement in terms of breakout factor and failure mechanism pattern.     

聚合物钻井液在河北广宗勘探区深孔施工中的应用

在河北广宗勘探区深孔施工中,由于地表钻探用水水质影响及原钻井液体系不合适,造成钻井液性能指标达不到要求,性能难以控制,尤其失水量严重超标,接连发生孔内事故。针对存在的问题,经过分析和实验,采用化学方法处理钻探用水,选用聚合物钻井液,解决了深部钻孔施工存在的难点,收到了较好的效果,单孔深度达到1937.35m,并刷新了本单位及局属单位的钻探记录。     

玻璃纤维增强聚合物抗浮锚杆抗拔性能试验研究与机制分析

抗浮锚杆作为一种竖向锚固技术在我国许多地区广泛应用,锚杆作为抗浮结构的核心其性能受到极大关注。但因钢材易腐蚀,传统金属锚杆的耐久性受到质疑,特别是地铁等地下工程存在杂散电流,限制了金属抗浮锚杆的应用。玻璃纤维增强聚合物(GFRP)抗浮锚杆是一种由树脂基体和玻璃纤维复合而成的新材料,与金属锚杆相比,它具有耐腐蚀、抗拉强度高、自重轻等优良特性。通过植入式裸光纤传感测试技术对GFRP抗浮锚杆的界面应力分布、荷载传递规律及破坏机制进行了研究,论证了GFRP抗浮锚杆使用的适宜性。试验表明,GFRP抗浮锚杆破坏以杆体基体材料剪切破坏为主,?28 mm锚杆极限抗拔力为250 kN,能够满足工程需要;杆体轴力沿深度方向逐渐递减,并且超过一定长度后杆体不再受力。结果显示,中风化岩地区,当锚固段长度为3.95⁶.95 m时,轴力影响深度范围约为3.7 m,说明GFRP抗浮锚杆同样存在临界锚固深度问题。锚杆界面剪应力呈不均匀分布,剪应力峰值随荷载的增加逐渐向下转移,同时0值点也向杆体深部转移。研究成果可为GFRP抗浮锚杆应用于工程实际提供依据。     

高聚物外包盾构隧道离心机振动台试验研究

为了验证非水反应聚氨酯高聚物(后文简称高聚物)外包盾构隧道具有减震性能,对高聚物外包盾构隧道模型和无外包隧道模型,采用离心机振动台进行对比试验。针对中密砂土围岩,在不同阵型特征的地震波输入下,对比有无高聚物外包隧道加速度、频谱、隧道动力响应和地表沉降,分析高聚物的减震性能。试验结果表明:在不同地震激励的工况下,对于有无高聚物外包的隧道模型,其加速度和频谱差别不大;二者隧道各点上的动应变平均相差31.32%;高聚物外包层隧道模型地表的最终沉降分别比无外包隧道模型和自由场地表沉降约小20%和50%。试验证明高聚物对盾构隧道有减震作用,此试验研究为高聚物在今后的工程应用提供参考依据。     

凝胶堵漏技术在阳山矿区漏失地层中的应用

甘肃省文县阳山矿区地质构造复杂,地层破碎蚀变强烈,多层位漏失,钻探施工漏失现象普遍。在研究地层漏失机理的基础上试验应用了聚合物凝胶堵漏技术。ZK2232孔的现场应用表明,聚合物凝胶堵漏剂与其他惰性桥堵剂配合使用,能很好地解决钻进过程中的恶性漏失问题,堵漏效果较好。在堵漏施工中,聚合物凝胶堵漏不受漏失通道的限制,能够通过挤压变形进入裂缝和孔洞空间,最终达到封堵漏层的目的。