水合物分解对桩基础应力和变形影响的研究

赋存于海底沉积物中的天然气水合物与固体颗粒相互胶结,增加了沉积物的强度,一旦水合物分解,会引起沉积物剪切强度降低,如果在含有水合物层上面或附近存在桩基础,必然影响其稳定性。本文采用应力释放法,通过数值计算,分别讨论了桩基础底部位于含水合物地层不同深度时,水合物分解对桩基础应力和变形的影响规律。计算结果表明,随着水合物分解过程中的模量软化和强度衰减,桩基础的水平和竖向位移增大,由于地基水平,土体没有驱动剪应力,水平位移增加不大,地基和桩基础主要表现为竖向沉降;桩底部位于水合物层中间的桩基础的沉降变形,比桩底穿过水合物层的桩基础大,在桩基础及其附近的土体产生较大的应力。     

Distribution and expression of gas seeps in a gas hydrate province of the northeastern Sakhalin continental slope, Sea of Okhotsk

Multidisciplinary surveys were conducted to investigate gas seepage and gas hydrate accumulation on the northeastern Sakhalin continental slope (NESS), Sea of Okhotsk, during joint Korean–Russian–Japanese expeditions conducted from 2003 to 2007 (CHAOS and SSGH projects). One hundred sixty-one gas seeps were detected in a 2000 km² area of the NESS (between 53°45′N and 54°45′N). Active gas seeps in a gas hydrate province on the NESS were evident from features in the water column, on the seafloor, and in the subsurface: well-defined hydroacoustic anomalies (gas flares), side-scan sonar structures with high backscatter intensity (seepage structures), bathymetric structures (pockmarks and mounds), gas- and gas-hydrate-related seismic features (bottom-simulating reflectors, gas chimneys, high-amplitude reflectors, and acoustic blanking), high methane concentrations in seawater, and gas hydrates in sediment near the seafloor. These expressions were generally spatially related; a gas flare would be associated with a seepage structure (mound), below which a gas chimney was present. The spatial distribution of gas seeps on the NESS is controlled by four types of geological structures: faults, the shelf break, seafloor canyons, and submarine slides. Gas chimneys that produced enhanced reflection on high-resolution seismic profiles are interpreted as active pathways for upward gas migration to the seafloor. The chimneys and gas flares are good indicators of active seepage.     

海底天然气渗漏形成水合物量的线性动力学模型:以墨西哥湾GC185区块Bush高地为例

世界许多地区如墨西哥湾，存在着大量天然气渗漏并形成水合物的现象，出于科学，生态，气候和安全的需要。人类有必要弄清存在于海底以水合成形式存在的天然气的比例。因此，构建了水合物形成量的线性动力学模型，以分析墨西哥湾GC185块区Bush高地海底渗漏天然气的地质过程和行为。Bush高地渗漏的天然气来源于附近的Jolliet气藏，结果表明，渗漏天然气中约有9％的海底形成了水合物。     

Authigenic carbonates from the eastern Black Sea as an archive for shallow gas hydrate dynamics – Results from the combination of CT imaging with mineralogical and stable isotope analyses

Authigenic carbonates associated with cold seeps provide valuable archives of changes in the long-term seepage activity. To investigate the role of shallow-buried hydrates on the seepage strength and fluid composition we analysed methane-derived carbonate precipitates from a high-flux hydrocarbon seepage area (“Batumi seep area”) located on the south-eastern Black Sea slope in ca. 850 m. In a novel approach, we combined computerized X-ray tomography (CT) with mineralogical and isotope geochemical methods to get additional insights into the three-dimensional internal structure of the carbonate build-ups.     

南海北部东沙天然气水合物区浮游植物生物量和生产力粒级结构特征及其环境影响分析

本文讨论了2013年5月南海东沙天然气水合物区浮游植物生物量和生产力粒级结构特征及其环境影响因素。结果表明,研究海域表现出典型的低营养盐、低叶绿素a、低生产力特征,浮游植物叶绿素a和初级生产力具有明显的次表层最大值现象。东沙海域生物量和初级生产力粒级结构差异性显著,从生物量和生产力贡献度来看,表现为微微型浮游植物> 微型浮游植物> 小型浮游植物。生物量的垂直分布结果表明,春季不同粒级类群浮游植物在真光层内的分布存在明显不同,比如小型浮游植物在真光层内分布较均匀;微型浮游植物则主要分布于近表层或真光层中部,而微微型浮游植物则主要分布于真光层中部和底部。微微型浮游植物在纬度较低的热带贫营养海区之所以能够占主导优势,最主要的原因是其极小的细胞体积和较大的表面积使其有利于营养竞争。相关性分析表明,南海东沙浮游植物各粒级生物量与温度、pH显著正相关,与硅酸盐、磷酸盐显著负相关;浮游植物各粒级生产力与温度显著正相关,与盐度、磷酸盐显著负相关。磷酸盐含量是影响东沙海域浮游植物粒级结构差异的重要因素之一,同时,光辐照度和水体的真光层深度对东沙天然气水合物区不同粒径浮游植物的垂直分布起着更为重要的调控作用。     

Analysis of formation pressure test results in the Mount Elbert methane hydrate reservoir through numerical simulation

Targeting the methane hydrate (MH) bearing units C and D at the Mount Elbert prospect on the Alaska North Slope, four MDT (Modular Dynamic Formation Tester) tests were conducted in February 2007. The C2 MDT test was selected for history matching simulation in the MH Simulator Code Comparison Study. Through history matching simulation, the physical and chemical properties of the unit C were adjusted, which suggested the most likely reservoir properties of this unit. Based on these properties thus tuned, the numerical models replicating “Mount Elbert C2 zone like reservoir”, “PBU L-Pad like reservoir” and “PBU L-Pad down dip like reservoir” were constructed. The long term production performances of wells in these reservoirs were then forecasted assuming the MH dissociation and production by the methods of depressurization, combination of depressurization and wellbore heating, and hot water huff and puff. The predicted cumulative gas production ranges from 2.16 × 10⁶ m³/well to 8.22 × 10⁸ m³/well depending mainly on the initial temperature of the reservoir and on the production method.This paper describes the details of modeling and history matching simulation. This paper also presents the results of the examinations on the effects of reservoir properties on MH dissociation and production performances under the application of the depressurization and thermal methods.     

基于叠前深度偏移的AVO反演在神狐海域试采区的应用

为了更好地研究神狐海域试采区天然气水合物的展布形态和赋存状况,基于高精度层析速度反演后的叠前深度偏移地震资料进行AVO反演技术研究。为在天然气水合物富集区有效地进行AVO研究,AVO处理前运用叠前深度偏移技术,通过高精度层析反演不断迭代速度模型;然后通过偏移来改善资料的质量,结合实测钻井资料进行AVO正演分析、反演可行性分析、属性交会分析;最后将具有高横向分辨能力的地震资料和高垂向分辨能力的测井资料与地质相结合进行叠前同时反演。该方法可反演出纵、横波阻抗等属性,直接进行岩性和流体识别,结果表明,在AVO反演中引入叠前深度偏移技术,为反演提供了较高质量的叠前共反射点道集和精细的层速度模型,改善了AVO技术在试采区的应用效果,提高了反演的可靠性。反演出的各种属性为AVO分析提供了丰富的信息,能够比较准确地反映地下水合物矿体的展布情况,可用于后续水合物储层的分析及综合研究,对未来的水合物勘探开采具有重要的现实意义。     

尖峰北盆地含气流体运聚疏导组合特征及对水合物成藏的控制作用

南海北部陆坡尖峰北盆地发育良好的气源及含气流体运聚疏导条件,具备较好的天然气水合物成藏潜力。为深入揭示尖峰北盆地水合物的成藏地质特征,基于高精度三维多道地震、浅地层剖面、多波束资料,深入分析了研究区深、浅部含气流体运聚疏导通道的地质、地球物理特征及对水合物成藏的控制作用。详细刻画了研究区深、浅部主要含气流体疏导通道的形态特征、发育规模、分布特点及对含气流体运聚的控制作用;重点剖析了深、浅部含气流体疏导通道组合特征及与水合物分布的耦合关系,最后结合水合物成藏地质条件,探讨了研究区水合物的成藏模式及影响因素。研究结果表明：尖峰北盆地的含气流体疏导通道主要以断裂型为主,亮点反射、反射空白带、BSR、声空白、声浑浊等含气流体运聚及水合物赋存指示标志多出现在沟源断层、古隆起伴生断层、多边形断层的顶部及邻近区域。以T3反射界面为界,其下伏沟源断层、古隆起伴生断层与上覆多边形断层构成的深、浅部含气流体疏导通道在垂向上相连通,沟通了深部气源层与浅层水合物稳定域,形成了“沟源断层—多边形断层”与“古隆起伴生断层—多边形断层”两种含气流体运移与水合物成藏模式。多边形断层的存在一方面促进了含气流体向浅层发生“中继疏导”,控制水合物富集成藏;另一方面,在多边形断层密集发育段,强烈的流体充注会引起局部温压平衡破坏和水合物分解、渗漏,导致“断续型”BSR的产生。浅层气体的渗漏和扩散可以持续作用至海底并对海底形态进行改造,导致海底滑塌、断裂、麻坑、丘状体等一系列海底微地貌的形成。     

Raman spectra of methane hydrate up to 86 GPa

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.     

氮气、氧气和空气水合物的合成及其拉曼光谱特征

在-20℃和不同的压力下,在实验室内分别合成了氮气水合物(16MPa)、氧气水合物(13MPa)和空气水合物(15MPa),并对其N—N和O—O键伸缩振动的拉曼光谱特征进行了研究。结果表明,人工合成的水合物中的N—N和O—O键的拉曼位移与天然的空气水合物中的数据十分接近。在氮气水合物和空气水合物中,N—N键的拉曼峰值均为2322.4cm-1;O—O键的拉曼峰值在氧气水合物和空气水合物保持一致,均为1547.8cm-1。空气水合物分解的拉曼谱图表明,它不是氮气水合物和氧气水合物组成的混合物,而是由氮分子和氧分子共同生成的单一水合物,氮分子和氧分子同时进入水合物的大笼和小笼中。与空气中的氮、氧比例相比,水合物中氧分子明显富集,氮分子和氧分子的比例为2.4∶1。