K-Ar法地质年龄标准物质ZBJ角闪石的定值结果

为了满足K-Ar定年中K和⁴⁰Ar^*分析的质量监控及Ar-Ar法样品在反应堆照射时中子通量监测的需要,我国氩同位素年代学工作者研制了一个K-Ar法年龄标准物质ZBJ角闪石,它采自北京房山花岗闪长岩体。它的⁴⁰Ar-³⁹Ar阶段加热分析结果表明:⁴⁰Ar^*在矿物晶格中保存均匀稳定,年龄谱平坦,³⁹Ar析出量高达97%。这些证据充分表明该黑云母结晶以后未受过热扰动,40K-⁴⁰Ar^*同位素计时体系封闭良好。坪年龄为133.3±0.6Ma,总气体年龄为134.4±1.4Ma,³⁶Ar/⁴⁰Ar-³⁹Ar/⁴⁰Ar反等时线年龄为133.2±0.8Ma,⁴⁰Ar/³⁶Ar初始值为297.6±4.8,此值与(⁴⁰Ar/³⁶Ar)a大气氩丰度比(295.5±0.5)处于同一范围,表明样品不含过剩氩。这几个年龄值的一致性,说明该样品具有良好的均匀性和稳定性,它作为K-Ar和Ar-Ar法地质年龄标准物质是适合的。ZBJ角闪石均匀性检验结果表明:在0.05显著性水平下经统计学方法检验,证明K和⁴⁰Ar^*的F分布值小于F临界值,说明该样品是均匀的。国内8个实验室参加了ZBJ角闪石K含量和⁴⁰Ar^*含量的定值分析,经统计学方法检验,结果显示全部定值数据都服从正态分布并具等精度。在置信概率为0.95时,⁴⁰Ar*和K含量的相对标准偏差都小于1%。两个特性量值定值分析结果的一致值(认定值)和不确定度分别为:⁴⁰Ar^*=(2.464±0.018)×10^-10mol/g,K=(1.027±0.008)%,K-Ar年龄(标准值)=133.3±1.5Ma(2σ)。此标准物质纯度为98.1%,粒度为0.15～0.30mm,总重量为740g,缩分成最小样品单元共100瓶,每瓶7.4g,可供我国K-Ar和Ar-Ar法同位素年代学实验室使用37年。     

Hornblende geothermometry of amphibolite layers of the Popple Hill gneiss, north-west Adirondack Lowlands, New York, USA

The exchange reaction tschermakite+2 diopside+2 quartz=tremolite+2 anorthite (HPCQ), in combination with the thermodynamic database TWQ (version 1.02, Berman, 1991), has been evaluated for its usefulness as a geothermometer. This reaction, which is both water conserving (independent of water fugacity) and which does not require the presence of garnet, is well suited for studying pyroxene‐bearing amphibolites. As an application of this geothermometer, we have re‐examined the amphibolites occurring in the Popple Hill gneiss of the Adirondack Lowlands of New York, USA, to better understand the magnitude of temperature variation preserved in the amphibolites themselves in this classic locality. At an assumed constant pressure of 7 kbar, the temperatures range from 619 to 682 °C from Edwards to Pierrepont and are uncorrelated with either distance along the strike of the region or with modal mineralogical variations. Hornblende exhibits a narrow compositional range suggesting that there has been little or no thermal gradient along the strike of the Lowlands. Temperatures recorded just north of Colton are, however, distinctly higher (694–758 °C). Although it is likely that the Popple Hill gneiss amphibolites experienced some effects of progressive metamorphism, particularly in the vicinity of Colton, the variations in modal mineralogy are most likely the result of such factors as local variations in the bulk chemistry of the protolith and in the fugacity of H₂O due to infiltration of diluting species (e.g. CO₂, CH₄), rather than a regional temperature variation. Temperatures recorded by the HPCQ geothermometer reported here are similar in magnitude and geographic trend to those reported for graphite–calcite carbon‐isotope thermometry by Kitchen & Valley (1995), suggesting that peak metamorphism in the Adirondack Lowlands involved laterally extensive and fairly uniform isotherms.     

内蒙石板井—小黄山与蛇绿岩相伴的变质岩及其演化

在内蒙古石板井－小黄山蛇绿岩带发现了具典型热变质特征的红柱石堇 青石角岩和以兰绿色角闪石、硬绿泥石、黑硬绿泥石等矿物代表的中高压区域变质角闪片岩。据变质作用时序和相拓朴图两个方面的研究,表明石板井和小黄山两地的变质岩属同一构造混杂岩,其中的变质岩先经过与火成作用有关的热变质作用,反又叠架了中高压变质作用,即经历过一反时钟PT轨迹。它的热高峰为620℃,压力高峰近0．65GPa。     

Solidification depth and crystallization age of the Shiaidani Granodiorite: Constraints to the average denudation rate of the Hida Range,central Japan

Solidification pressure and crystallization age of the ~5 Ma Shiaidani Granodiorite (Hida Mountain Range, central Japan) are determined based on Al-in-hornblende geobarometry and U–Pb zircon dating. Al-poor patchy replacements developed in amphiboles are common in this granite and petrographic study revealed that the replacements include chloritized biotite and albitic plagioclase. These are probably the hydrothermally recrystallized domains, and should not be used for solidification pressure estimates. Magmatic rim of amphibole is characterized by Si < 7.3 a.p.f.u. (Al_IV > 0.7 a.p.f.u.), and utilized in solidification pressure estimate that yielded 0.17–0.29 GPa. The solidification age of the granite is estimated as ~5.6–5.2 Ma using U–Pb zircon dating. From these data, the lower limit of an average denudation rate after ~5.6–5.2 Ma for the area where Shiaidani Granodiorite is exposed is estimated as 0.93–2.5 mm/year.     

Mineral chemistry and geothermobarometry of Moshirabad pluton,Qorveh, Kurdistan,western Iran

The Moshirabad pluton is located southwest of the Sanandaj–Sirjan Metamorphic Belt, Qorveh, western Iran. The pluton is composed of diorite, monzodiorite, quartz diorite, quartz monzodiorite, tonalite, granodiorite, granite, aplite, and pegmatite. In this study 31 samples from various rocks were chosen for whole‐rock analyses and 15 samples from different lithologies were chosen for mineral chemical studies. The compositions of minerals are used to describe the nature of magma and estimate the pressure and temperature at which the Moshirabad pluton was emplaced. Feldspar compositions are near the binary systems in which plagioclase compositions range from An₅ to An₅₃ and alkali‐feldspar compositions range from Or₉₁ to Or₉₇. Mafic minerals in the plutonic rocks are biotite and hornblende. Based on the composition of biotites and whole‐rock chemistry, the Moshirabad pluton formed from a calc‐alkaline magma. Amphiboles are calcic amphiboles (magnesio‐hornblende or edenite). Temperatures of crystallization, calculated with the hornblende–plagioclase thermometer, range 550–750°C. These temperatures indicate that plutonic rocks have undergone some retrogressive changes in their mineral compositions. Aluminum‐in‐hornblende geobarometry indicates that the Moshirabad pluton was emplaced at pressures of 2.3–6.0 kbar, equal to depths of 7–20 km, but with consideration of regional geology, lower pressures than the above pressure range are more probable. Alteration of amphiboles can be the reason for some overestimation of pressures.     

Zircon U–Pb ages of plutonic rocks in the southern Abukuma Mountains: Implications for Cretaceous geotectonic evolution of the Abukuma Belt

Plutonic rocks in the southern Abukuma Mountains include gabbro and diorite, fine‐grained diorite, hornblende–biotite granodiorite (Ishikawa, Samegawa, main part of Miyamoto and Tabito, Kamikimita and Irishiken Plutons), biotite granodiorite (the main part of Hanawa Pluton and the Torisone Pluton), medium‐ to coarse‐grained biotite granodiorite and leucogranite, based on the lithologies and geological relations. Zircon U–Pb ages of gabbroic rocks are 112.4 ±1.0 Ma (hornblende gabbro, Miyamoto Pluton), 109.0 ±1.1 Ma (hornblende gabbro, the Hanawa Pluton), 102.7 ±0.8 Ma (gabbronorite, Tabito Pluton) and 101.0 ±0.6 Ma (fine‐grained diorite). As for the hornblende–biotite granodiorite, zircon U–Pb ages are 104.2 ±0.7 Ma (Ishikawa Pluton), 112.6 ±1.0 Ma (Tabito Pluton), 105.2 ±0.8 Ma (Kamikimita Pluton) and 105.3±0.8 Ma (Irishiken Pluton). Also for the medium‐ to fine‐grained biotite granodiorite, zircon U–Pb ages are 106.5±0.9 Ma (Miyamoto Pluton), 105.1 ±1.0 Ma (Hanawa Pluton) and the medium‐ to coarse‐grained biotite granodiorite has zircon U–Pb age of 104.5 ±0.8 Ma. In the case of the leucogranite, U–Pb age of zircon is 100.6 ±0.9 Ma. These data indicate that the intrusion ages of gabbroic rocks and surrounding granitic rocks ranges from 113 to 101 Ma. Furthermore, K–Ar ages of biotite and or hornblende in the same rock samples were dated. Accordingly, it is clear that these rocks cooled down rapidly to 300 °C (Ar blocking temperature of biotite for K–Ar system) after their intrusion. These chronological data suggest that the Abukuma plutonic rocks in the southern Abukuma Mountains region uplifted rapidly around 107 to 100 Ma after their intrusion.     

Phase Equilibria of Hornblende‐Bearing Eclogite in the Western Dabie Mountain,Central China

The high-pressure (HP) eclogite in the western Dabie Mountain encloses numerous hornblendes, mostly barroisite. Opinions on the peak metamorphic P-T condition, PT path and mineral paragenesis of it are still in dispute. Generally, HP eclogite involves garnet, omphacite, hornblendes and quartz, with or without glaucophane, zoisite and phengite. The garnet has compositional zoning with XMg increase, XCa and XMn decrease from core to rim, which indicates a progressive metamorphism. The phase equilibria of the HP eclogite modeled by the P-T pseudosection method developed recently showed the following: (1) the growth zonation of garnet records a progressive metamorphic PT path from pre-peak condition of 1.9–2.1 GPa at 508°C–514°C to a peak one of 2.3–2.5 GPa at 528°C–531°C for the HP eclogite; (2) the peak mineral assemblage is garnet+omphacite+glaucophane+quartz±phengite, likely paragenetic with lawsonite; (3) the extensive hornblendes derive mainly from glaucophane, partial omphacite and even a little garnet due to the decompression with some heating during the post-peak stage, mostly representing the conditions of about 1.4–1.6 GPa and 580°C–640°C, and their growth is favored by the dehydration of lawsonite into zoisite or epidote, but most of the garnet, omphacite or phengite in the HP eclogite still preserve their compositions at peak condition, and they are not obviously equilibrious with the hornblendes.     

内蒙古呼和浩特北二道凹岩群黑云角闪片岩SHRIMP锆石U-Pb定年

二道凹岩群是20世纪70年代初1∶200000区域地质调查时在呼和浩特市北二道凹地区命名的,其岩石组合为变质砾岩、各种片岩、大理岩等。依据最新1∶250000区调成果,自下而上分了三个岩组,即红山口岩组、哈拉更沟岩组、东梁岩组。为进一步研究二道凹岩群的地质时代,本文对东梁岩组的黑云角闪片岩中锆石进行了高精度SHRIMP U-Pb测年研究,其时代为1890±8 Ma,认为该年龄值系黑云角闪片岩原岩的形成时代,即代表了二道凹岩群上部中基性火山岩的形成年龄,结合已有的年龄数据,进一步佐证了二道凹岩群形成于古元古代(1800~2400Ma)。     

THE DEFORMATION BEHAVIOUR OF HORNBLENDE IN THE FLORENCE SHEAR ZONE,CENTRAL AUSTRALIA

角闪石在低温变形中通常显示脆性变形行为,通过对中澳洲Ｆｌｏｒｅｎｃｅ剪切带的铁镁质糜棱岩的观察研究表明,角闪石在这些高温变形环境形成的糜棱岩中显示出显著的塑性变形行为,表现在角闪石遭强应变后,无碎裂出现,而具明显的晶内塑性应变现象和强烈的晶体优选定向,角闪石的细粒化是由边界重结晶迁移所致。本文探讨了引起角闪石塑性变形的一些因素,认为岩石发生糜棱岩化时的高温环境增强了角闪石的韧性,几何软化对角闪的塑性变形行为也起到一定的作用。     

Trace element partitioning during high-P partial melting and melt-rock interaction; an example from northern Fiordland, New Zealand

Pods of granulite facies dioritic gneiss in the Pembroke Valley, Milford Sound, New Zealand, preserve peritectic garnet surrounded by trondhjemitic leucosome and vein networks, that are evidence of high‐P partial melting. Garnet‐bearing trondhjemitic veins extend into host gabbroic gneiss, where they are spatially linked with the recrystallization of comparatively low‐P two‐pyroxene‐hornblende granulite to fine‐grained high‐P garnet granulite assemblages in garnet reaction zones. New data acquired using a Laser Ablation Inductively Coupled Plasma Mass Spectrometer (LA‐ICPMS) for minerals in various textural settings indicate differences in the partitioning of trace elements in the transition of the two rock types to garnet granulite, mostly due to the presence or absence of clinozoisite. Garnet in the garnet reaction zone (gabbroic gneiss) has a distinct trace element pattern, inherited from reactant gabbroic gneiss hornblende. Peritectic garnet in the dioritic gneiss and garnet in trondhjemitic veins from the Pembroke Granulite have trace element patterns inherited from the melt‐producing reaction in the dioritic gneiss. The distinct trace element patterns of garnet link the trondhjemitic veins geochemically to sites of partial melting in the dioritic gneiss.