气象要素对太阳能电池板温度的影响

温度升高会引起光伏电池发电效率下降,电池板温度是确定温度折减系数的必要条件,目前我国尚没有充足的外场实测电池板温度数据。该文基于北京南郊太阳能试验站2010年全年逐时电池板温度、气温、地表温度、斜面和水平辐照度实测数据,分析了电池板温度随时间的变化及其与各气象要素的关系。结果表明:电池板温度与气温和斜面辐照度的综合相关或与地表温度的线性相关最好,但实测数据不易获得;电池板温度与气温的线性相关较好,数据较易获得且质量有保证,从现实可行性考虑,是推算电池板温度最实用的相关方程;电池板温度与气温和水平辐照度的综合相关可以作为辅助方程,用于推算气温较高情况下的电池板温度。基于2010年电池板温度实测数据和加权计算的方法,得到北京地区年平均光伏发电温度折减系数约为2%,最高可达到13.3%。     

四川盆地震旦系灯影组葡萄状白云岩成因

四川盆地震旦系灯影组发育巨厚的白云岩,其中灯影组二段和四段发育大量具有各种形态的葡萄状白云岩,其直径最长可达75cm,有的平行于层面,有的穿层。剖面资料表明,葡萄状白云岩发育多期等厚环边胶结物,中部残留大量未充填的不规则洞穴,这成为与岩溶喀斯特作用相关的地下溶蚀作用的证据。围岩泥晶白云石为早期海水中原生结晶的产物,后来的胶结物可划分为4期: (1)自泥晶化白云石(部分样品中可见)作为最早的一期胶结物,由于各种生物化学作用和生物作用的影响而紧贴着围岩发育;(2)第2期胶结物纤维状白云石可能为海水中直接沉淀的产物,经历后期成岩作用后,具有完全有序的结构,晶胞参数接近理想值;(3)细—中晶白云石为第3期胶结物,包含纤维状白云石溶蚀残余,形成于构造抬升之后的近地表大气淡水环境;(4)第4期胶结物中—粗晶白云石为埋藏环境下直接结晶的产物,充填了孔洞中心,残留部分未充填孔洞。灯影组受到了岩溶喀斯特作用、胶结作用以及白云石化作用等成岩作用的影响,其中与葡萄状白云岩有关的岩溶喀斯特作用对于灯影组储集层的发育至关重要。对灯影组葡萄状白云岩的研究,不仅有助于深入探讨灯影组储集层成因和演化及灯影组白云岩的成因,而且有助于指导四川盆地前寒武系油气勘探。     

微波消解—冷原子荧光光谱法测定植物样品中的汞

为了简化测量植物中汞含量的方法,提高灵敏度及结果的可信度,实验采用微波消解植物样品的办法,使样品经氯化亚锡还原,再用冷原子荧光测定出植物样品中汞的含量。确定了消解样品的方法和微波消解样品的条件,优化了仪器的最佳工作参数。方法检出限0.30×10-9(稀释因子100倍),精密度(n=12)在2.09%~6.05%,加标回收率94.1%~105.5%,方法经生物国家一级标准物质验证方法准确可靠。     

Experiment and Pitzer Model Prediction for the Solid + Liquid Equilibria of the Ternary System LiCl–CaCl2–H2O

正1 Introduction Lithium resources are widely distributed in the oilfield brine from the Nanyishan district in the Qaidam Basin(Fan et al.,2007).The investigation of the thermodynamics and phase diagram of the brine system is valuable in providing the theoretic foundation and scientific guidance in the comprehensive exploitation of the mixture salts effectively.Comprehensive     

手机信令数据支撑下广州市过剩通勤及其空间分异格局

利用手机信令数据构建居委会尺度下的职住联系数据库,分析广州过剩通勤及其空间分异格局。研究发现,广州市过剩通勤为76.01%,与国内和西方国家城市相比处于较高水平,说明广州市职住空间组织效率偏低。过剩通勤的空间分异特征主要表现为：功能相对单一的郊区大型工业或房地产集聚区过剩通勤率偏高;传统市中心虽然就业机会集中,但因为高居住成本也出现较高的过剩通勤率;近郊区的特定功能区域,如大学城、偏农业发展型城郊村等区域出现较低的过剩通勤率;快速轨道交通（地铁）建设因降低了居民对通勤距离的敏感度而导致过剩通勤水平的提升,高过剩通勤率空间分布与地铁沿线和地铁站点分布存在一定的空间一致性。提升大城市的职住空间组织效率除需重点考虑提升区域职住空间平衡外,优化城市功能结构、降低住房成本区域差异等也需予以重点考虑。     

273.15 到 308.15 K下二元体系（LiCl-H2O 和 MgCl2-H2O）和三元体系（LiCl-MgCl2-H2O）的体积性质研究

用高精度振动管在 273.15 至 308.15 K 的温度范围内以 5 K 的间隔对两个二元系统（LiCl-H2O 和 MgCl2-H2O）和三元系统（LiCl-MgCl2-H2O）的密度进行了实验测定密度计。基于 Vogel-Fulcher-Tamman (VFT) 方程,对 LiCl(aq) 和 MgCl2(aq) 密度与温度和摩尔浓度的相关方程的系数进行了参数化。 Young的理想混合规则被成功地应用于基于相关的二元解性质关联三元系统的密度。根据二元和三元体系的体积特性数据,根据 Pitzer 离子相互作用理论,得到 Pitzer 单盐参数和混合离子相互作用参数。在本工作中确定了三元体系在恒定离子强度下的混合体积 (ΔVm)。     

三元体系CaCl2?SrCl2?H2O的相平衡及其在钙锶分离中的应用

采用等温溶解平衡法研究了三元体系CaCl₂?SrCl₂?H₂O温度从323.15 K到353.15 K范围内的相平衡。基于该三元体系多温下的相平衡数据,设计开展了实验室模拟南翼山油田卤水中氯化钙和氯化锶在温度323.15 K下的分离实验。实验室模拟钙锶分离实验结果表明,在323.15 K下时分离一次固相产品中的钙锶摩尔比可以从25.46:1降至1.73:1,SrCl₂的回收率为52.47 %,所得一次固相产品在323.15 K下溶解并再次蒸发。钙和锶的摩尔比从1.73:1降至1.1:1,SrCl₂的回收率为78.67 %。     

不同蛋白源饲料对褐点石斑鱼幼鱼血细胞发生的影响

以全鱼粉作为唯一蛋白源(D1),用豆粕替代10%、20%鱼粉(D2、D3),玉米蛋白粉替代10%鱼粉(D4),啤酒酵母替代10%鱼粉(D5),配制5组等氮等能饲料,每种饲料设置3个实验组,进行56 d的养殖实验。通过血液和组织涂(印)片、细胞染色和显微观察,研究人工培育的褐点石斑鱼幼鱼外周血液白细胞的分类组成,头肾、脾脏、体肾和肝脏等4种组织中各类血细胞的发生情况,以及不同蛋白源饲料对褐点石斑鱼血细胞发生的影响。结果表明:褐点石斑鱼外周血液中的白细胞由淋巴细胞(53.30%±4.66%)、血栓细胞(35.69%±3.85%)、嗜中性粒细胞(10.34%±3.14%)、单核细胞(0.28%±0.36%)、浆细胞(0.24%±0.34%)和嗜酸性粒细胞(0.15%±0.27%)组成;组织印迹片中,未成熟的红细胞、淋巴细胞和粒细胞主要在头肾印迹片中出现,未成熟的单核细胞主要在头肾和脾脏印迹片中出现,血栓细胞在肝脏印迹片中数量最多,推断褐点石斑鱼幼鱼主要的造血组织是头肾,其次是脾脏;在4种组织中均观察到浆细胞,在体肾印迹片中观察到嗜碱性粒细胞,在肝脏印迹片中观察到巨噬细胞,在头肾印迹片中还观察到巨大原红细胞。显微观察和数据统计分析的结果都表明,投喂5种蛋白源不同的配合饲料,未对褐点石斑鱼4种组织中血细胞的发生情况造成显著影响。     

Capturing the essential spatial variability in distributed hydrological modelling: Infiltration parameters

Selecting the correct resolution in distributed hydrological modelling at the watershed scale is essential in reducing scale-related errors. The work presented herein uses information content (entropy) to identify the resolution which captures the essential variability, at the watershed scale, of the infiltration parameters in the Green and Ampt infiltration equation. A soil map of the Little Washita watershed in south-west Oklahoma, USA was used to investigate the effects of grid cell resolution on the distributed modelling of infiltration. Soil-derived parameters and infiltration exhibit decreased entropy as resolutions become coarser. This is reflected in a decrease in the maximum entropy value for the reclassified/derived parameters vis a vis the original data. Moreover, the entropy curve, when plotted against resolution, shows two distinct segments: a constant section where no entropy was lost with decreasing resolution and another part which is characterized by a sharp decrease in entropy after a critical resolution of 1209 m is reached. This methodology offers a technique for assessing the largest cell size that captures the spatial variability of infiltration parameters for a particular basin. A geographical information system (GIS) based rainfall-runoff model is used to simulate storm hydrographs using infiltration parameter maps at different resolutions as inputs. Model results up to the critical resolution are reproducible and errors are small. However, at resolutions beyond the critical resolution the results are erratic with large errors. A major finding of this study is that a large resolution (1209 m for this basin) yields reproducible model results. When modelling a river basin using a distributed model, the resolution (grid cell size) can drastically affect the model results and calibration. The error structure attributable to grid cell resolution using entropy as a spatial variability measure is shown.     

Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: field measurements and theoretical analysis

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.