湘南荷花坪锡多金属矿床成矿年代研究

荷花坪锡多金属矿床是本世纪初在南岭中段湘南地区新发现的一个大型矿床,区内的锡多金属矿化产在王仙岭岩体东南内、外接触带,已发现有Ⅰ、Ⅱ、Ⅲ和Ⅳ号4个主要锡多金属矿体。其中,Ⅰ、Ⅱ和Ⅳ号矿体由早期矽卡岩型和晚期蚀变碎裂岩型矿石组成,Ⅲ号矿体则由独立产出的蚀变碎裂岩型矿石组成,且包含有部分碎裂花岗斑岩。以往研究已对Ⅳ号矿体中的矽卡岩型矿石和Ⅲ号矿体中含矿斑岩脉分别采用辉钼矿Re-Os法和锆石SHRIMP U-Pb法进行了测年,获得的年龄分别为224.0±1.9Ma和142±2Ma。本文补充了晚期蚀变碎裂岩型矿石的~(40)Ar/~(39)Ar测年,结果显示,Ⅱ号矿体中蚀变碎裂岩型矿石白云母样品和石英样品的坪年龄分别为151.88±1.58Ma和155.39±7.04Ma;Ⅳ号矿体中蚀变碎裂岩型矿石石英样品的坪年龄为156.94±1.64Ma。结合前人研究资料综合分析,认为荷花坪矿区存在印支晚期(224Ma)、燕山早期(151~156Ma)和燕山晚期(142Ma)三期成矿作用,分别与区内印支期中粗粒含电气石黑云母花岗岩、燕山早期中粗粒黑云母花岗岩和燕山晚期花岗斑岩脉有关,不同期成岩、成矿作用的构造环境均为岩石圈的拉张伸展。湘南地区印支期(205~224Ma)基性岩浆活动及荷花坪矿床印支期成岩、成矿过程中均有幔源物质的参与,它们共同指示南岭地区中生代构造体制的转换或岩石圈伸展减薄可能始于印支主期(230~244Ma)之后的224Ma左右,即晚三叠世。     

朝鲜半岛古元古代摩天岭群的碎屑锆石U-Pb年龄及其地质意义

克拉通内部活动带变质沉积建造蕴藏了早期超大陆形成中地体聚-散动力学过程的重要信息,碎屑锆石年代学则是揭示这种信息的最佳工具之一。针对华北(中-朝)克拉通最具代表性的古元古代活动带(辽-吉-朝活动带)中巨量沉积建造精细表征方面的空白区域,本文开展了朝鲜半岛检德地区摩天岭群的碎屑锆石年代学研究。SIMS U-Pb定年结果显示,北大川组变火山碎屑岩样品的锆石年龄谱记录了约2.53Ga的主要年龄峰值和约2.19Ga的最年轻峰值,说明北大川组开始沉积的时代应该晚于2.2Ga。南大川组变沉积岩样品碎屑锆石记录的最年轻峰值年龄为约2.02Ga,说明南大川组的沉积时代应该不早于2.02Ga;其锆石年龄谱记录了一个主要年龄峰值区域(2.02~2.18Ga)、一个次要年龄峰值(约2.46Ga)和一些2.78~3.30 Ga的古老年龄,指示其物质源区主要为同区古元古代地质体和邻近地体上的太古宙变质基底。区域对比表明,摩天岭群与中国境内辽吉活动带中的辽河群及集安群/老岭群具有基本一致的碎屑锆石年龄谱,说明它们不仅是同一时代的产物,而且分享类似的物质源区。这些时代一致、物源相近的沉积建造可以为甄别古元古代辽-吉-朝活动带的大地构造属性提供重要参考。与沉积年龄相近的碎屑锆石占据主导的碎屑锆石年龄谱反映了汇聚板块边缘各类盆地的典型特征,而相悖于大部分碎屑锆石年龄远大于地层沉积年龄的裂谷型盆地。     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

中国盐湖沉积年代学研究进展

盐湖沉积记录了区域的气候和水文变化,是重要的古气候研究对象。年代学是盐湖古气候研究最重要的一项内容,是后续几乎所有工作的基础。盐湖沉积最常用的定年方法有₁₄C定年、铀系定年、光释光(OSL)定年、古地磁定年。受各种定年方法自身的局限性以及盐湖沉积特有的沉积特征,存在不同方法测出的年龄差异较大的现象。准确测定盐湖沉积的年代还较为困难,一定程度制约了盐湖古气候研究的发展。由于盐湖沉积有机质含量低,易受现代碳的污染,其₁₄C年代老于30 cal ka BP时,测出的年龄可能已饱和,需要谨慎对待。未来需要加强铀系定年和光释光定年等方法在盐湖沉积中的基础研究,并开发新的更好的测年方法,提高盐湖沉积测年的准确度,为深入开展盐湖古气候变化及成盐成矿规律研究提供坚实基础。     

内蒙古艾勒格庙强过铝质花岗岩定年、地球化学特征及其地质意义

内蒙古艾勒格庙二长花岗岩岩体分布在锡林浩特-艾勒格庙前寒武纪微陆块的西部,利用LA-MC-ICP-MS锆石UPb法测得其形成年龄为418.5±1.1Ma,侵入时代为晚志留世末期。岩石地球化学特征显示高硅(SiO_2 74.22%~75.51%),富钾(K_2O 5.41%~5.78%),铝饱和指数A/CNK在1.17~1.21之间,属于高钾钙碱性强过铝质花岗岩类。微量元素特征为富集Rb、Th、U、Pb、K和重稀土元素(Yb 3.74×10~(-6)~9.65×10~(-6)),强烈亏损Nb、Ta、P、Ti等元素。该岩体形成于后碰撞构造环境,是地壳增厚后折返减压部分熔融的产物。它的存在揭示,艾勒格庙苏左旗北部造山带在晚志留世之前已经发生弧陆碰撞,之后的顶志留世—中泥盆世为后碰撞-后造山的伸展背景。     

Isotope Geochronologic and Geochemical Constraints on the Magmatic Associations of the Collisional Orogenic Zone in the West Kunlun Orogen,China

The Jiajiwaxi pluton in the southern portion of the West Kunlun Range can be divided into two collision–related intrusive rock series, i.e., a gabbro–quartz diorite–granodiorite series that formed at 224±2.0 Ma and a monzonitic granite–syenogranite series that formed at 222±2.0 Ma. The systematic analysis of zircon U-Pb geochronology and bulk geochemistry is used to discuss the magmatic origin(material source and thermal source), tectonic setting, genesis and geotectonic implications of these rocks. The results of this analysis indicate that the parent magma of the first series, representing a transition from I-type to S-type granites, formed from thermally triggered partial melting of deep crustal components in an early island–arc–type igneous complex, similar to an I-type granite, during the continental collision orogenic stage. The parent magma of the second series, corresponding to an S-type granite, formed from the partial melting of forearc accretionary wedge sediments in a subduction zone in the late Palaeozoic–Triassic. During continued collision, the second series magma was emplaced into the first series pluton along a central fault zone in the original island arc region, forming an immiscible puncture-type complex. The deep tectonothermal events associated with the continent–continent collision during the orogenic cycle are constrained by the compositions and origins of the two series. The new information provided by this paper will aid in future research into the dynamic mechanisms affecting magmatic evolution in the West Kunlun orogenic belt.     

内蒙古科尔沁右翼中旗协和尔斯德中生代火山沉积地层时代研究

内蒙古科尔沁右翼中旗协和尔斯德一带出露一套中生代地层,岩石组合主要为酸性火山碎屑岩、火山碎屑沉积岩夹碎屑沉积岩及酸性火山熔岩。1∶50000区调依据在该套地层上部层位发现的木化石组合确定其时代为中—晚侏罗世,结合岩石组合,将该套地层划分为上侏罗统满克头鄂博组。为了准确厘定该套地层时代,为木化石延限研究及区域生物地层划分对比提供依据,本次研究在低于产木化石层位的酸性火山碎屑岩中采取了锆石测年样品(LA-ICP-MS),获得锆石U-Pb年龄(165±1)Ma,时代为中侏罗世。同时采取了侵入该套地层的斑状细晶闪长岩测年样品,获得锆石年龄(131±1)Ma,限定了地层形成的上限年龄。根据岩性组合的区域对比、测年结果、木化石组合时限、地层产状特征,认为该套地层应划为中侏罗统新民组,是突泉火山-沉积盆地充填物的一部分。     

长江中下游宣城水东地区早白垩世酸性火山岩年代学、地球化学及岩石成因

位于长江中下游的宣城水东地区发育一套酸性火山岩,主要由流纹质角砾岩、流纹岩和珍珠岩组成。本文对该套火山岩进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Nd-Hf同位素研究。LA-ICP MS锆石U-Pb定年结果显示3种岩性的火山岩年龄分别为133.2±0.8、133.4±0.8和131.5±0.9 Ma。主量元素组成上,这套酸性火山岩具高硅(72.51%~81.79%)、富钾(K_2O/Na_2O=2.04~14.93,平均6.72)、贫钙镁(Ca O=0.19%~1.57%,Mg O=0.06%~0.29%)的特征,属于弱过铝质(A/CNK=1.02~1.24)的高钾钙碱性-钾玄岩系列岩石。微量元素方面,轻重稀土元素分馏明显[(La/Yb)_N=5.43~9.17],具明显的负铕异常(Eu/Eu~*=0.44~0.60),富集大离子亲石元素(LILE)Rb、Th、K和Pb等,亏损Ba、Sr、Nb、P和Ti等元素,表现出壳源的特征。全岩Sr-Nd和锆石Hf同位素组成变化范围相对较小,(~(87)Sr/~(86)Sr)_i为0.707 3~0.708 8,εNd(t)值为-7.05~-5.56,εHf(t)为-8.6~-1.3。结合区域地质研究成果,认为宣城水东地区酸性火山岩可能是在约135 Ma古太平洋板块俯冲作用之后的伸展-拉伸环境下,由新元古代早期新生地壳重熔而成。     

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

Middle Jurassic–Early Cretaceous tectonic evolution of the Bayanhushuo area,southern Great Xing’an Range,NE China: constraints from zircon U–Pb geochronological and geochemical data of volcanic and subvolcanic rocks

This study presents new zircon U–Pb geochronology, geochemistry, and zircon Hf isotopic data of volcanic and subvolcanic rocks that crop out in the Bayanhushuo area of the southern Great Xing’an Range (GXR) of NE China. These data provide insights into the tectonic evolution of this area during the late Mesozoic and constrain the evolution of the Mongol–Okhotsk Ocean. Combining these new ages with previously published data suggests that the late Mesozoic volcanism occurred in two distinct episodes: Early–Middle Jurassic (176–173 Ma) and Late Jurassic–Early Cretaceous (151–138 Ma). The Early–Middle Jurassic dacite porphyry belongs to high-K calc-alkaline series, showing the features of I-type igneous rock. This unit has zircon ε_Hf(t) values from +4.06 to +11.62 that yield two-stage model ages (T_DM2) from 959 to 481 Ma. The geochemistry of the dacite porphyry is indicative of formation in a volcanic arc tectonic setting, and it is derived from a primary magma generated by the partial melting of juvenile mafic crustal material. The Late Jurassic–Early Cretaceous volcanic rocks belong to high-K calc-alkaline or shoshonite series and have A₂-type affinities. These volcanics have ε_Hf(t) and T_DM2 values from +5.00 to +8.93 and from 879 to 627 Ma, respectively. The geochemistry of these Late Jurassic–Early Cretaceous volcanic rocks is indicative of formation in a post-collisional extensional environment, and they formed from primary magmas generated by the partial melting of juvenile mafic lower crust. The discovery of late Mesozoic volcanic and subvolcanic rocks within the southern GXR indicates that this region was in volcanic arc and extensional tectonic settings during the Early–Middle Jurassic and the Late Jurassic–Early Cretaceous, respectively. This indicates that the Mongol–Okhotsk oceanic plate was undergoing subduction during the Early–Middle Jurassic, and this ocean adjacent to the GXR may have closed by the Late Middle Jurassic–Early Late Jurassic.