斑岩型钼矿床研究进展与问题

本文在简要介绍全球重要成矿带斑岩型钼矿床品位、储量、时空分布以及构造背景的基础上,着重归纳了斑岩型钼矿床中Mo在岩浆—热液演化过程中的地球化学行为特征以及Mo在成矿流体中的迁移与沉淀机制两个方面的研究进展。取得了以下认识:形成斑岩型钼矿床成矿岩浆氧逸度(f_(O2))变化范围较大,但一般大于铁橄榄石—磁铁矿—石英(FMQ)缓冲体系。斑岩钼矿床形成的主要受岩浆房的大小,大体积的岩浆流体能否高效聚集到浅部岩株或岩脉,岩浆中的挥发分(例如F)含量等因素的控制,但与成矿花岗岩和出溶流体中Mo的含量高低无直接关系。成矿流体的氧逸度与p H降低对辉钼矿沉淀具有关键作用。除此之外,温度与盐度降低对辉钼矿沉淀也有重要作用。流体的多阶段沸腾可能对提高Mo品位具有重要意义。此外,应加强岩浆结晶分异过程、岩浆热液转化过程Mo的地球化学行为研究。     

土地质量地球化学评估与绿色产能评价研究:以吉林大安市为例

做好土地资源数量管控,加强耕地质量管理和生态管护是当前的一项非常重要的工作。选择吉林省大安市东南区域为研究对象,进行土地质量地球化学评估,并融合污染元素进行农用地分等研究。结果表明研究区内评定为三等及以上的土壤占全区总面积的72.61%,研究区土地质量总体较好,优质和优良土地分布面积较大,主要为黑钙土,差等的土地主要为盐碱土或盐化草甸土。尝试性地将农用地分等成果中的产能评价和土地质量地球化学评估中的元素含量评价结合,开展了绿色产能评价。     

新疆蒙库地区华力西中期花岗岩及其构造环境意义的研究

新疆蒙库地区位于阿尔泰山南麓,南接准噶尔盆地。该地区花岗岩分布广泛,主要为华力西中、晚期花岗岩。对蒙库地区华力西中期（石炭纪）花岗岩进行分析和研究认为,该区花岗岩处于华力西期大陆边缘造山带环境中,具有汇聚、造山期花岗岩的特征。岩浆沿断裂带上侵就位,为板块俯冲作用、陆—陆碰撞构造环境下形成的活动大陆边缘岩浆弧。深入研究蒙库地区花岗岩有助于我们了解这一时期该地区区域构造、岩浆演化的规律。     

冬季青藏高原大气热状况分析Ⅱ：年际变化

通过诊断3套再分析资料的非绝热加热场,研究冬季青藏高原上空大气的热力特征.结果表明,与夏季为强热源的特征不同,冬季高原上空不是欧亚大陆上最强的冷源中心.冬季高原上空整体是偏弱的冷源,在高原西侧及东南地区上空甚至出现非绝热加热正值区,这一分析对以往研究提出的高原是冷源的特性给出了修正.各种非绝热加热分量的诊断表明,冬季高原上空这种总的非绝热加热分布主要是由于高原主体的长波辐射冷却较周边地区弱,以及西侧至东南地区凝结潜热释放造成的.为了说明再分析的非绝热加热资料对冬季高原上空大气的这种热力特征描述的可信性,文中还利用了地表辐射能量、TRMM及PREC/L降水、垂直速度等资料进一步辅助分析,证实了由于高原位势较高造成大气整层温度偏低,向外长波辐射偏少,以及高原地势的隆起造成局地较强的上升运动,高原西侧至东南角降水大值区潜热偏大,最终造成高原上空总非绝热加热负值偏小.最后理想高原隆起的水球试验结果说明,冬季,高原的存在减弱了陆地上空的冷却效应,因而其上为弱冷源,再次证实了资料分析的结果.     

扬子克拉通北缘新元古代岛弧花岗岩类成分极性及成因的地球化学探讨

对扬子克拉通北缘新元古代岛弧花岗岩类成分极性的地球化学研究表明,在SiO_2含量相近的条件下,由北向南岩石中K_2O、K_2O+Na_2O、K_2O/Na_2O逐渐增加,而CaO逐渐降低;从北向南,微量元素Rb、Ba、Th、Zr、Nb、Ta、 ∑REE及Rb/Th、Rb/Nb、∑LREE/∑HREE、(La/Yb)_N 逐渐增加或具增加趋势,而 Sr、Co、Ni和Sr/Ba具逐渐降低或具降低趋势;同位素组成由北向南δ~18O、εs_r(t)系统增高,而ε_(Nd)(t)逐渐降低。这些组分的空间变化规律与环太平洋带位于俯冲带上盘向陆一侧的岛弧或大陆边缘岩浆中出现的成分极性规律相一致.分析认为,大陆壳物质以不同比例的加入是影响俯冲带岛弧花岗质岩浆成分极性的一个重要因素,向陆一侧岩浆中陆壳物质所占的比例逐渐增高,而幔源物质所占比例逐渐降低。     

柴达木盆地西部地区咸化湖盆天然气地球化学特征及成因类型判识指标——以古近系—新近系为例

根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。     

Geochemical and isotopic characterization of trace fossil infillings: New insights on tracemaker activity after the K/Pg impact event

Geochemical and isotopic analyses of the Cretaceous–Paleogene (K/Pg) boundary deposits were conducted at the Caravaca section (External Subbetic, southeast of Spain) in order to evaluate the recovery of the macrobenthic tracemaker community and the bioturbational disturbance. Samples from the infilling material of several lower Danian dark-colored trace fossils (Chondrites, Planolites, Thalassinoides and Zoophycos) located in the uppermost 8-cm of the light upper Maastrichtian strata, as well as samples from the host sedimentary rock of these trace fossils, were analyzed and compared with data from the lower Danian deposits. The values of element ratios indicative of extraterrestrial contamination (Cr/Al, Co/Al and Ni/Al) are higher in the infilling trace fossil material than in the upper Maastrichtian and lower Danian deposits, which suggests a contribution of the ejecta layer. Regarding the isotope composition, the δ¹³C values are lower in the infilling material than in the Maastrichtian host sedimentary rocks surrounding the traces, while the δ¹⁸O are higher in the infilling material. The geochemical and isotopic compositions of the infilling material evidence the unconsolidated character of the sediment, including the red boundary layer. Softground conditions confirm a relatively rapid recovery by the macrobenthic tracemaker community, starting a few millimeters above the K/Pg boundary layer. The mixture of the infilling material of the trace fossils moreover reveals a significant macrobenthic tracemaker activity affecting K–Pg boundary transition sediments that may have significantly altered original signatures.     

Laboratory Simulation of the Formation Process of Surface Geochemical Anomalies Applied to Hydrocarbon Exploration

The formation mechanisms and processes of geochemical anomalies used as proxies in surface geochemistry exploration (SGE) have not been well understood. Previous studies cannot realize 3D measurement of microseeping hydrocarbons from reservoirs to the surface, which made it difficult to understand the features and pathways of deep hydrocarbon microseepages. Understanding the processes of hydrocarbon microseepages will contribute to the acceptance and effectiveness of surface geochemistry. Based on a simplified geological model of hydrocarbon microseepages, including hydrocarbon reservoir, direct caprock, overlying strata and Quaternary sediments, this work established a 3D experimental system to simulate the mechanisms and processes of deep hydrocarbon microseepes extending to the surface. The dispersive halos of microseeping hydrocarbons in the subsurface were adequately described by using this 3D experimental system. Results indicate that different migration patterns of hydrocarbons above the point gas source within the simulated caprock and overlying strata can be reflected by the ratio of i-butane to n-butane (i-C4/n-C4), which follow diffusion and infiltration (buoyancy) mechanisms. This is not the case for vertical measurement lines far from the point gas source. A vertical gas flow in the form of a plume was found during hydrocarbon microseepage. For sampling methods, the high-density grid sampling is favorable for delineating prospecting targets. Hydrocarbon infiltration or buoyancy flow occurs in the zones of infiltration clusters, coupling with a diffusion mechanism at the top of the water table and forming surface geochemical anomalies. These results are significant in understanding hydrocarbon microseepage and interpreting SGE data.     

地幔不均一性与地幔循环的多维表征和原因思考

地幔早先经核- 幔- 壳分异形成,后受不同尺度对流和循环的影响,因而具有不均一性特征。近三十年来,地幔化学通过研究大洋玄武岩发现了多样地幔端元和非放射性同位素证据并证明了地幔不均一性,逐渐建全了地幔地球化学体系。然而,地幔不均一性如何对应于时空尺度的地幔循环,以及地球演化如何影响地幔不均一性等,仍不清楚。此外,地球物理研究显示,岩石圈厚度差异、中下地幔的波速异常体以及俯冲板片形态的观测为纵横向对流系统提供了空间不均一性证据支持。联合地球化学和地球物理手段对研究地幔不均一性至关重要,用好透视地幔成分与结构的“双目镜”已成为共识。本文从地幔不均一性结合地球化学场、地球物理的不同表现形式,以及现今及历史时期的洋陆格局的对比,多维度联系地幔循环和演化,思考了超大陆旋回与地幔不均一化的内在逻辑。强调了从全球演化角度看地幔不均一性的重要性和提出多手段联合建立地幔循环驱动模型的展望。