Metamorphic and structural evolution of the Early Proterozoic Puolankajärvi Formation, Finland – I. Structural and textural relations

The amphibolite facies Puolankajärvi Formation (PjF) occupies the western margin of the Early Proterozoic Kainuu Schist Belt (KSB) of northern Finland. The lower and middle parts of the PjF consist of turbiditic psammites and pelites and tempestitic semipelites. This report concentrates on the pelitic lithologies which include quartz–two-mica–plagioclase schists with variable amounts of garnet, staurolite, andalusite and biotite porphyroblasts as well as sillimanite and cordierite segregations. The KSB forms a major north–south-trending synclinorium between two Archaean blocks. It contains both autochthonous and allochthonous units and is cut by faults and shear zones. The PjF lies on the western side of the KSB and is probably allochthonous. The formation has undergone six major deformation phases (D₁, D₂, D_3a, D_3b, D₄ and D₅). During D_3a-D₅ the maximum principal stress (σ₁) changed in a clockwise direction from south-west to north-east. Between D₂ and D₃ the intermediate principal stress (σ₂) changed from horizontal to vertical and the interval between D₂ and D₃ marks a transition from thrust to strike-slip tectonics. Relict structures in the porphyroblasts indicate the following mineral growth–deformation evolution in the PjF. (1) Throughout the PjF there was a successive crystallization of garnet (syn-D₁), poryphyroblastic biotite (inter-D_3/4) and staurolite (inter-D_3/4) during the pre-D₄ stage. (2) A syn-D₄-inter-D_4/5 crystallization of kyanite, sillimanite (fibrolite), porphyroblastic tourmaline, magnetite, rutile, cordierite and muscovite–biotite–plagioclase pseudomorphs after staurolite was most localized at and near D₄ shear zones. (3) A syn- to post-D₅ generation of andalusite, ilmenohematite and sheet silicates after staurolite and after cordierite occurred near D₅ faults. The evolution outlined here permits the relative dating of the PjF parageneses, which is used in the second part of the study (Tuisku & Laajoki, 1990), and, together with the knowledge of the pressure–temperature conditions during various growth events, makes it possible to compile pressure–temperature–deformation paths for the PjF.     

Synchronous peak Barrovian metamorphism driven by syn-orogenic magmatism and fluid flow in southern Connecticut, USA

Recent work in Barrovian metamorphic terranes has found that rocks experience peak metamorphic temperatures across several grades at similar times. This result is inconsistent with most geodynamic models of crustal over‐thickening and conductive heating, wherein rocks which reach different metamorphic grades generally reach peak temperatures at different times. Instead, the presence of additional sources of heat and/or focusing mechanisms for heat transport, such as magmatic intrusions and/or advection by metamorphic fluids, may have contributed to the contemporaneous development of several different metamorphic zones. Here, we test the hypothesis of temporally focussed heating for the Wepawaug Schist, a Barrovian terrane in Connecticut, USA, using Sm–Nd ages of prograde garnet growth and U–Pb zircon crystallization ages of associated igneous rocks. Peak temperature in the biotite–garnet zone was dated (via Sm–Nd on garnet) at 378.9 ± 1.6 Ma (2σ), whereas peak temperature in the highest grade staurolite–kyanite zone was dated (via Sm–Nd on garnet rims) at 379.9 ± 6.8 Ma (2σ). These garnet ages suggest that peak metamorphism was pene‐contemporaneous (within error) across these metamorphic grades. Ion microprobe U–Pb ages for zircon from igneous rocks hosted by the metapelites also indicate a period of syn‐metamorphic peak igneous activity at 380.6 ± 4.7 Ma (2σ), indistinguishable from the peak ages recorded by garnet. A 388.6 ± 2.1 Ma (2σ) garnet core age from the staurolite–kyanite zone indicates an earlier episode of growth (coincident with ages from texturally early zircon and a previously published monazite age) along the prograde regional metamorphic T–t path. The timing of peak metamorphism and igneous activity, as well as the occurrence of extensive syn‐metamorphic quartz vein systems and pegmatites, best supports the hypothesis that advective heating driven by magmas and fluids focussed major mineral growth into two distinct episodes: the first at c. 389 Ma, and the second, corresponding to the regionally synchronous peak metamorphism, at c. 380 Ma.     

滇西马厂箐铜钼多金属矿床成矿流体来源及演化过程——来自石榴子石原位微量元素及H- O同位素组成的限定

滇西马厂箐铜钼多金属矿床位于三江特提斯成矿域,是一个与喜马拉雅期富碱斑岩侵入有关的多金属矿床。前人研究表明,马厂箐铜钼多金属矿床形成于斑岩-矽卡岩成矿系统,但由于缺乏系统矿物学研究,目前对矽卡岩矿化过程和成矿效应仍不清楚,限制了对该矿床成矿过程的全面认识。因此,本文以马厂箐矿床矽卡岩型矿化中的石榴子石为研究对象,利用H-O同位素、电子探针(EPMA)以及LA-ICP-MS原位微区技术开展了同位素及成分分析,限定成矿流体来源以及反演成矿流体演化过程。石榴子石可分为早期自形石榴子石(Grt I)和晚期他形石榴子石(Grt II)。Grt I与辉石共生,并伴有黄铁矿、黄铜矿等金属矿物组合,属于钙铝-钙铁榴石固溶体(And_{49.37～99.58}Gro_0～49.79);Grt II更富Fe,属钙铁榴石系列(And_{67.50～99.85}Gro_0～31.84)。两期石榴子石均富含Th、U、Nd,亏损Ba、Sr、Hf、Nb,富轻稀土。基于石榴子石矿物化学特征认为,Grt I可能是在弱酸性、氧化、低水岩比(W/R)条...     

Geochemical characterization of Archaean amphibolites from the eastern part of Anshan–Benxi iron producing area,northeastern China: implication for tectonic setting of BIFs

The Anshan–Benxi iron producing area, which is located at the northeastern margin of the North China Craton, is the main distribution area of Archaean BIFs in China. In their eastern part, including the Gongchangling and Waitoushan deposits, BIFs mainly are hosted in the Archaean middle Anshan Group. Amphibolites are widely distributed in the iron‐bearing rock series, reflecting the tectonic setting of BIFs. Amphibolites not only have MORB‐like compositional characteristics, but also have island arc‐like ones, and they are consistent with back‐arc basin basalts (BABB). In the study area, the protolith of amphibolites belongs to Okinawa‐type BABB; it indicates that tectonic setting of BIFs is the intra‐continental back‐arc basin. In the study area, the formation of sedimentary basins for BIFs had been associated with oceanic plate subduction. Amphibolites from Gongchangling deposit are characterized by relative enrichments in LILE and LREE, and depletions in HFSE. This indicates that they had a relatively large influence of subduction in their formation. Amphibolites from Waitoushan deposit are characterized by relative enrichments in LILE without conspicuous depletions in HFSE, indicating relatively low subduction rates. Copyright © 2015 John Wiley & Sons, Ltd.     

Mineralogical and Petrological Characteristics of the Neoproterozoic Orthoamphibolite and Orthogneisses in the Mutki Area, the Bitlis Massif, Southeast Turkey

<正>The rocks form as amphibolite±garnet±epidote and orthogneisses in the Pan-African basement of the Bitlis Massif.The petrochemical data of the studied metamorphic rocks suggest different igneous protoliths ranging from calcalkaline basalt to andesite in composition. Petrochemically,the rocks can be classified as group 1(low Zr and La) and group 2(high Zr and La), all showing various enrichments in large ion lithophiles and light rare earth elements,and a depletion in high-field strength elements,suggestive of a destructive plate margin setting.The protoliths of the all samples might have formed mostly by the partial melting of an enriched source,possibly coupled with the fractional crystallization of plagioclase,apatite,and titaniferous magnetite±olivine±clinopyroxene±amphibole in relation with subduction-related magmatism neighboring the Andeantype active margins of Gondwana.The group 2 samples could,however,be generated by a relatively lower degree of the partial melting of an inhomogeneous source with a preponderance of a high-level, fractional crystallization process in comparison to group 1.The protoliths of the samples were metamorphosed up to amphibolite facies conditions,which destroys original igneous texture and mineral assemblages.Geothermobarometric calculations show that the metamorphic rocks are finally equilibrated between 540 and 610℃and～5 kbars,following a clockwise P-T-t path.     

Evaluation of a Quality Control Monitor Material for the Routine Electron Probe Microanalysis of Kimberlite Exploration Garnets

Election probe microanalysis of indicator minerals is extensively used in the exploration for kimberlite deposits, the evaluation of specific kimberlite occurrences for their diamond bearing potential and to classify grains into different chemical and lithological mantle associations. Kimberlite exploration programmes can involve several tens of thousands of indicator mineral analyses. Procedures for monitoring data quality and consistency of analyses across large data sets are commonly absent. Suitable monitor minerals should be used to verify the data quality of kimberlite exploration and evaluation data sets. This material should have a suitable composition, be homogenous, be available in sufficient quantities and have a similar appearance to the unknown samples. Garnet P1, a megacryst garnet from the Premier kimberlite, was found to have a suitable composition as a monitor for kimberlite garnet analyses. Data were collected on the monitor material at regular intervals during routine analyses, over an extended period, both as a fixed grain mounted on the sample holder and as separate grains set within batches of routine samples. The data were evaluated to assess the quality and consistency in the analyses of large data sets over time. The monitor material was also analysed at independent laboratories using their routine analytical set-up and calibration procedures for comparative purposes. Values are given for the mean ± 2s range, which can serve as guide values for acceptable analyses for all elements.     

五河杂岩的变质岩石学及P-T条件分析钻孔的研究

五河杂岩是华北克拉通东部陆块东南缘最重要的岩石单元。然而,直至今日,人们对于该组杂岩一直缺乏足够的研究,特别是对于其形成的变质条件分歧较大。本文通过对蒙城南ZK02钻孔中五河杂岩的构成和地质特征详细研究表明五河杂岩分为上、下两段。上段主要为一套由云母片岩、大理岩和花岗片麻岩组成的变质表壳岩系,下段为一套基性变质岩,主要岩性为斜长角闪岩、角闪岩、石榴斜长角闪岩和少量的混合岩。同时,针对下段特征岩石（石榴斜长角闪岩）,进行了较为详细的岩相学和矿物化学分析,并应用不同的温压计进行P-T条件评价和比较,结合岩相学限定和前人的研究成果,认为五河杂岩的主体普遍经历了高压角闪岩相变质作用,其温压范围为：T=671 ℃～700 ℃和P=0.82～0.95 GPa,地温梯度约为25～28 ℃/km,与典型陆壳地温梯度类似。与同邻区主要岩石单元的变质级别相比,五河杂岩应当形成于板内变质环境,并不具备造山带变质特征。     

Garnet re‐equilibration by coupled dissolution–reprecipitation: evidence from textural,major element and oxygen isotope zoning of ‘cloudy’ garnet

The analysis of texture, major element and oxygen isotope compositions of cloudy garnet crystals from a metapelite sampled on Ikaria Island (Greece) is used to assess the model of growth and re‐equilibration of these garnet crystals and to reconstruct the pressure–temperature–fluid history of the sample. Garnet crystals show complex textural and chemical zoning. Garnet cores (100–200 μm) are devoid of fluid inclusions. They are characterized by growth zoning demonstrated by a bell‐shaped profile of spessartine component (7–3 mol.%), an increase in grossular from 14 to 22 mol.% and δ¹⁸O values between 9.5 ± 0.3‰ and 10.4 ± 0.2‰. Garnet inner rims (90–130 μm) are fluid inclusion‐rich and show a decreasing grossular component from 22 to 5 mol.%. The trend of the spessartine component observed in the inner rim allows two domains to be distinguished. In contrast to domain I, where the spessartine content shows the same trend as in the core, the spessartine content of domain II increases outwards from 2 to 14 mol.%. The δ¹⁸O values decrease towards the margins of the crystals to a lowest value of 7.4 ± 0.2‰. The outer rims (<10 μm) are devoid of fluid inclusions and have the same chemical composition as the outermost part of domain II of the inner rim. Garnet crystals underwent a four‐stage history. Stage 1: garnet growth during the prograde path in a closed system for oxygen. Garnet cores are remnants of this growth stage. Stage 2: garnet re‐equilibration by coupled dissolution–reprecipitation at the temperature peak (630 < T < 650 °C). This causes the creation of porosity as the coupled dissolution–reprecipitation process allows chemical (Ca) and isotopic (O) exchange between garnet inner rims and the matrix. The formation of the outer rim is related to the closure of porosity. Stage 3: garnet mode decreases during the early retrograde path, but garnet is still a stable phase. The resulting garnet composition is characterized by an increasing Mn content in the inner rim’s domain II caused by intracrystalline diffusion. Stage 4: dissolution of garnet during the late retrograde path as garnet is not a stable phase anymore. This last stage forms corroded garnet. This study shows that coupled dissolution–reprecipitation is a possible re‐equilibration process for garnet in metamorphic rocks and that intra‐mineral porosity is an efficient pathway for chemical and isotopic exchange between garnet and the matrix, even for otherwise slow diffusing elements.     

P–T–t evidence for mechanisms of vertical tectonic motion in a contractional orogen: north-western US and Canadian Cordillera

The >1800 km long Coast Mountains–North Cascades orogen of the Canadian Cordillera and north-western US developed as a continental magmatic arc. Metamorphic rocks in the orogen contain widespread evidence for burial of supracrustal rocks to depths of c. 40 km, followed by nearly isothermal decompression to depths of <10 km. Near many shallowly-emplaced, mid-Cretaceous plutons, low-pressure contact metamorphic effects were overprinted by high-pressure regional metamorphic minerals and textures, as evidenced by kyanite±staurolite pseudomorphs after andalusite in metapelitic rocks. Therefore, near-pluton rocks record the loading history of the orogen. Metapelitic rocks not associated with plutons only preserve evidence for high-pressure conditions and/or high-temperature decompression, as indicated, for example, by sillimanite and cordierite after kyanite and garnet, respectively. Petrological evidence for burial and decompression is therefore recorded in different rocks. Various regions of the orogen differ in timing of metamorphism, the overall shape of P–T paths and the relative timing and regional extent of the high-pressure event, but most of these data and observations are consistent with thrusting and/or pure shear thickening as primary loading mechanisms throughout the orogen, as opposed to magma-dominated loading. This interpretation is further supported by comparison with thermal models, which demonstrate that the P–T paths are consistent with simultaneous thrusting and folding at a high initial geothermal gradient (35–40 °C km^?1) in much of the orogen. A high geothermal gradient supports tectonic models invoking intra-arc contraction and suggests that magmatism played an important role in regional temperature-time paths. This tectonic-thermal history may be typical of other contractional orogens and illustrates the importance of large vertical displacement of crust in magmatic arcs.     

Petrology and geothermobarometry of granulite facies metapelites from the Hisøy-Torungen area, south Norway: new data on the Sveconorvegian P–T–t path of the Bamble sector

ABSTRACT The high-grade rocks (metapelite, quartzite, metagabbro) of the Hisøy-Torungen area represent the south-westernmost exposures of granulites in the Proterozoic Bamble sector, south Norway. The area is isoclinally folded and a metamorphic P–T–t path through four successive stages (M1-M4) is recognized. Petrological evidence for a prograde metamorphic event (M1) is obtained from relict staurolite + chlorite + albite, staurolite + hercynite + ilmenite, cordierite + sillimanite, fine-grained felsic material + quartz and hercynite + biotite ± sillimanite within metapelitic garnet. The phase relations are consistent with a pressure of 3.6 ± 0.5 kbar and temperatures up to 750–850°C. M1 is connected to the thermal effect of the gabbroic intrusions prior to the main (M2) Sveconorwegian granulite facies metamorphism. The main M2 granulite facies mineral assemblages (quartz+ plagioclase + K-feldspar + garnet + biotite ± sillimanite) are best preserved in the several-metre-wide Al-rich metapelites, which represent conditions of 5.9–9.1 kbar and 790–884°C. These P–T conditions are consistent with a temperature increase of 80–100°C relative to the adjacent amphibolite facies terranes. No accompanying pressure variations are recorded. Up to 1-mm-wide fine-grained felsic veinlets appear in several units and represent remnants of a former melt formed by the reaction: Bt + Sil + Qtz→Grt + lq. This dehydration reaction, together with the absence of large-scale migmatites in the area, suggests a very reduced water activity in the rocks and XH₂O = 0.25 in the C–O–H fluid system was calculated for a metapelitic unit. A low but variable water activity can best explain the presence or absence of fine-grained felsic material representing a former melt in the different granulitic metapelites. The strongly peraluminous composition of the felsic veinlets is due to the reaction: Grt +former melt ± Sil→Crd + Bt ± Qtz + H₂O, which has given poorly crystalline cordierite aggregates intergrown with well-crystalline biotite. The cordierite- and biotite-producing reaction constrains a steep first-stage retrograde (relative to M2) uplift path. Decimetre- to metre-wide, strongly banded metapelites (quartz + plagioclase + biotite + garnet ± sillimanite) inter-layered with quartzites are retrograded to (M3) amphibolite facies assemblages. A P–T estimate of 1.7–5.6 kbar, 516–581°C is obtained from geothermobarometry based on rim-rim analyses of garnet–biotite–plagioclase–sillimanite–quartz assemblages, and can be related to the isoclinal folding of the rocks. M4 greenschist facies conditions are most extensively developed in millimetre-wide chlorite-rich, calcite-bearing veins cutting the foliation.