北方某经济开发区地下水污染调查评价

本文应用污染指数法,对北方某经济开发区及周边地下水水质进行了污染评价,结果表明研究区地下水水质以轻污染和中污染为主,局部地区出现较重污染,主要指标为硝酸盐氮、三氯甲烷和三氯乙烯。通过对工业废水、再生水、河水水质的检测,发现研究区地表水水质与污水处理厂再生水排放密切相关,地下水污染很可能与开发区企业排污有关。由于开发区所处位置的环境敏感性和脆弱性,建议今后在开发区及附近继续开展相关研究,进一步查明地下水的硝酸盐氮及有机污染物来源、污染途径,建立完善的监测体系,以便及时切断污染源,保障城市及当地供水安全。     

Main technical innovations of Songke Well No.2 Drilling Project

Songke Well No.2, one of the main part of the scientific drilling project in Songliao Basin, which was drilled 7018 m and acquired the part of cores continuously from the Low Cretaceous to the Carboniferous and the Permian from the 2843 m deep, can be considered as the deepest continental drilling project in Asia. Aiming at the features of longer well sections, larger diameters and multiple spud-ins for coring of Songke Well No.2, this project broke through the “coring in small diameter and reaming in large diameter” spud-in drilling-completion procedures which are always used in large-diameter-well coring for continental scientific drilling projects in domestic and overseas and the drilling method of short-single-cylinder roundtrip footage. At the same time, “coring in the same diameter and completing drilling at one single diameter” was achieved at all φ311 mm and φ216 mm coring sections of more than one thousand meters long, high-efficient operation with “drilling long footage with drill tools combined in multi-cylinders” was achieved at deep coring section. Four world drilling records were created which include more than a thousand meters continuous coring at φ311 mm, and the footage per roundtrip footage at φ311 mm, φ216 mm and φ152 mm is all more than 30 m, all of these breakthroughs reduced at least 300 days for this project; moreover, considering the characteristics of formations that the geothermal gradient is high in the drilled sections and the inside-well temperature is over 240°C after drilling completion, a formate-polymer water-based mud system was developed by compounding attapulgite and sodium bentonite and by adding independently developed high-temperature stabilizer, which can provide critical technical support for successful well completion at 7018 m in the super-high-temperature environment It is the first time that the water-based mud is operated at the working temperature higher than 240°C in China; Besides, considering the high-quality requirement on cores imposed by the project, the method “mechanical cored is charge” to discharge core nondestructively on the ground was worked out, and more than 4000 m scatheless cores were discharged out of the drill pipes while maintaining original stratum structures.     

Temporal and spatial changes of dunes in the Changjiang (Yangtze) estuary,China

The response of subaqueous dunes to the variation of riverine sediment supply in an estuary is rarely reported. Five sets of field measurements of bed sediments and topography were made in the Changjiang estuary, China during dry and flood seasons for the past 9 years. Results show that dunes were mainly three-dimensional (3D) during flood seasons and two-dimensional (2D) dunes during dry seasons. Dunes were also much larger in flood seasons. Dunes mainly occurred within the main channels of the estuary although they extended 11.7 km seaward of their normal extent in the South Channel during dry seasons from 2002 to 2006. This extension of the dune field is likely due to a sharp decline of sediment discharge caused by large reservoirs such as Three Gorges.     

Determination of residence time and mixing processes of the Ubatuba,Brazil, inner shelf waters using natural Ra isotopes

Coastal waters contain elevated dissolved activities of short-lived radium isotopes, ²²³Ra and ²²⁴Ra, having half-lives of 11.4 and 3.66 days, respectively. The input of these isotopes near the coast must be balanced by decay and mixing into the open ocean, where excess activities are zero. Since the decay rate is known, in the ideal case the mixing rate may be determined from the offshore distribution of these isotopes. This study found that samples collected in June 2000 followed the expected exponential decrease with distance offshore. We assign a dispersion coefficient of 28–39 m² s⁻¹ for this study. During January 2002 and November 2003, there was not a consistent decrease of activity with distance offshore. This is likely due to the ruggedness of the coastline, where many bays and small islands interrupt simple mixing patterns. To estimate exchange rates during 2002 and 2003, we used a model based on the decrease in the ²²⁴Ra/²²³Ra activity ratio (AR) with time for samples isolated from fresh inputs of Ra. This model yielded residence times of 1–2 weeks for samples collected within 20 km of the coast. We used this residence time to calculate the flux of ²²⁸Ra (half-life = 5.7 years) to the study area necessary to maintain the enrichment relative to ocean water. This enrichment is a factor of ten greater than the flux of ²²⁸Ra expected from submarine groundwater discharge (SGD) occurring within 50 m of shore.     

Numerical study on salinity stratification in the Pamlico River Estuary

The variations of current circulation, salt intrusion, and vertical stratification under different river flow and wind conditions in the Pamlico River Estuary (PRE) were investigated in this paper using a three-dimensional numerical model. The model was calibrated and verified against water level variation, temperature, and salinity variations during 2003 and 2001, respectively. Eight sensitivity tests were conducted with different river flow and wind conditions specified in the model. Model results show that salinity intruded further upstream under scenarios with low flow, downriver local wind, and remote-wind-caused water level set-up conditions. In contrast, the responses of salinity stratification to different environmental forcing functions were different in different portions of the estuary. Salinity stratification was enhanced under high flow condition at the lower part of the estuary, under upriver wind near the river mouth, under downriver wind at the upstream to middle portion of the estuary, and under remote-wind-caused water level set-up condition at the majority of the estuary except near the river mouth. Model results also show that across-channel wind tended to reduce salt intrusion and salinity stratification in the PRE through increased vertical mixing.     

Isotopic,trace element and nutrient characterization of coastal waters from Ubatuba inner shelf area,south-eastern Brazil

Stable isotopes, tritium, radium isotopes, radon, trace elements and nutrients data were collected during two sampling campaigns in the Ubatuba coastal area (south-eastern Brazil) with the aim of investigating submarine groundwater discharge (SGD) in the region. The isotopic composition (δD, δ¹⁸O, ³H) of submarine waters was characterised by significant variability and heavy isotope enrichment. The stable isotopes and tritium data showed good separation of groundwater and seawater groups. The contribution of groundwater in submarine waters varied from a few % to 17%. Spatial distribution of ²²²Rn activity concentration in surface seawater revealed changes between 50 and 200 Bq m⁻³ which were in opposite relationship with observed salinities. Time series measurements of ²²²Rn activity concentration in Flamengo Bay (from 1 to 5 kBq m⁻³), obtained by in situ underwater gamma-spectrometry showed a negative correlation between the ²²²Rn activity concentration and tide/salinity. This may be caused by sea level changes as tide effects induce variations of hydraulic gradients, which increase ²²²Rn concentration during lower sea level, and opposite, during high tides where the ²²²Rn activity concentration is smaller. The estimated SGD fluxes varied during 22–26 November between 8 and 40 cm d⁻¹, with an average value of 21 cm d⁻¹ (the unit is cm³/cm² per day). The radium isotopes and nutrient data showed scattered distributions with offshore distance and salinity, which implies that in a complex coast with many small bays and islands, the area has been influenced by local currents and groundwater–seawater mixing. SGD in the Ubatuba area is fed by coastal contaminated groundwater and re-circulated seawater (with small admixtures of groundwater), which claims for potential environmental concern with implications on the management of freshwater resources in the region.     

Seasonal changes in submarine groundwater discharge to coastal salt ponds estimated using Ra and Ra as tracers

Submarine groundwater discharge (SGD) to coastal southern Rhode Island was estimated from measurements of the naturally-occurring radioisotopes ²²⁶Ra (t_1/2 = 1600 y) and ²²⁸Ra (t_1/2 = 5.75 y). Surface water and porewater samples were collected quarterly in Winnapaug, Quonochontaug, Ninigret, Green Hill, and Pt. Judith–Potter Ponds, as well as nearly monthly in the surface water of Rhode Island Sound, from January 2002 to August 2003; additional porewater samples were collected in August 2005. Surface water activities ranged from 12–83 dpm 100 L^− 1 (60 dpm = 1 Bq) and 21–256 dpm 100 L^− 1 for ²²⁶Ra and ²²⁸Ra, respectively. Porewater ²²⁶Ra activities ranged from 16–736 dpm 100 L^− 1 (2002–2003) and 95–815 dpm 100 L^− 1 (2005), while porewater ²²⁸Ra activities ranged from 23–1265 dpm 100 L^− 1. Combining these data with a simple box model provided average ²²⁶Ra-based submarine groundwater fluxes ranging from 11–159 L m^− 2 d^− 1 and average ²²⁸Ra-derived fluxes of 15–259 L m^− 2 d^− 1. Seasonal changes in Ra-derived SGD were apparent in all ponds as well as between ponds, with SGD values of 30–472 L m^− 2 d^− 1 (Winnapaug Pond), 6–20 L m^− 2 d^− 1 (Quonochontaug Pond), 36–273 L m^− 2 d^− 1 (Ninigret Pond), 29–76 L m^− 2 d^− 1 (Green Hill Pond), and 19–83 L m^− 2 d^− 1 (Pt. Judith–Potter Pond). These Ra-derived fluxes are up to two orders of magnitude higher than results predicted by a numerical model of groundwater flow, estimates of aquifer recharge for the study period, and values published in previous Ra-based SGD studies in Rhode Island. This disparity may result from differences in the type of flow (recirculated seawater versus fresh groundwater) determined using each technique, as well as variability in porewater Ra activity.     

Uncertainties associated with Ra and Ra measurements in water via a Delayed Coincidence Counter (RaDeCC)

The short-lived radium isotopes, ²²³Ra (T_1/2 = 11.4 days) and ²²⁴Ra (T_1/2 = 3.66 days), have been successfully used as tracers of several environmental processes, e.g., submarine groundwater discharge, coastal mixing processes, and water residence times. In this paper, the uncertainties associated with ²²³Ra and ²²⁴Ra measurements using a Radium Delayed Coincidence Counter are determined on a detailed error propagation basis with a confidence interval of 1σ. From the data analyses of several groups of coastal water samples, the calculated relative uncertainties averaged 12% for the ²²³Ra and 7% for the ²²⁴Ra. These uncertainties can decrease for radium-enriched groundwater samples although asymptotic limits have been found at 7% relative uncertainty for ²²³Ra and 4% for ²²⁴Ra. In this paper, the influence of sampling and measurement parameters on the final radium uncertainties is evaluated in order to provide guidance to optimize these factors and obtain more reliable results.     

河流静水滩区潜流带水交换空间分布模式研究（英文）

Hyporheic zone(HZ) influences hydraulic and biogeochemical processes in and alongside streams, therefore, investigating the controlling geographic factors is beneficial for understanding the hydrological processes in HZ. Slack water pool (SWP) is an essential micro-topographic structure that has an impact on surface water and groundwater interactions in the HZ during and after high flows. However, only a few studies investigate HZ surface water and groundwater exchange in the SWP. This study used the thermal method to estimate the HZ water exchange in the SWP in a segment of the Weihe River in China during the winter season. The findings show that on the flow-direction parallel to the stream, river recharge dominates the HZ water exchange, while on the opposing flow-direction bank groundwater discharge dominates the water exchange. The water exchange in the opposing flow-direction bank is about 1.6 times of that in the flow-direction bank. The HZ water exchange is not only controlled by flow velocity but also the location and shape of the SWP. Great water exchange amount corresponds to the shape with more deformation. The maximum water exchange within the SWP is close to the river bank where the edge is relatively high. This study provides some guidelines for water resources management during flooding events.     

Spatial analysis of water quality and its suitability in farming giant freshwater prawn (Macrobrachium rosenbergii) in Negeri Sembilan region,Peninsular Malaysia

Finding potential sites for resilient prawn production in the tropical environment that also prevents wastage of natural resources is not an easy task. The purpose of this study is to evaluate water quality suitability for prawn farming in Negeri Sembilan of Peninsular Malaysia based on Geographic Information System (GIS). To achieve this goal, numerous criteria including sources of water, water temperature, water pH, sources of pollution, salinity, soil texture and availability of phytoplankton criteria were considered for the modelling process. Analytic Hierarchy Process (AHP) technique was performed to standardize the criteria and the weighting process. The weighted overlay of indicators and results were accomplished by applying the Multi‐Criteria Decision Analysis (MCDA) method in GIS. It was indicated that the Negeri Sembilan area has potential for prawn farming. The results showed that about 25 per cent (163 056.93 ha) of the area was most suitable for prawn farming, about 58 per cent (384 656.88 ha) was considered moderately suitable, while 18 per cent (117 633.49 ha) was regarded as least suitable. The study concluded that the multi‐criteria decision analysis of water quality for prawn farming is vital for regional economic planning in the Negeri Sembilan area and also significant when establishing a model for aquaculture development.