Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.     

Sea‐level rise impact on fresh groundwater lenses in two‐layer small islands

The fresh groundwater lenses (FGLs) of small islands can be highly vulnerable to climate change impacts, including sea‐level rise (SLR). Many real cases of atoll or sandy islands involve two‐layer hydrogeological conceptualizations. In this paper, the influential factors that affect FGLs in two‐layer small islands subject to SLR are investigated. An analytical solution describing FGLs in circular islands, composed of two geological layers, is developed for the simplified case of steady‐state and sharp‐interface conditions. An application of the developed model is demonstrated to estimate the FGL thickness of some real‐world islands by comparison with existing FGL thickness data. Furthermore, numerical modelling is applied to extend the analysis to consider dispersion effects and to confirm comparable results for both cases. Sensitivity analyses are used to assess the importance of land‐surface inundation caused by SLR, relative to other parameters (i.e. thickness of aquifer layers, hydraulic conductivity, recharge rate and land‐surface slope) that influence the FGL. Dimensionless parameters are used to generalize the findings. The results demonstrate that land‐surface inundation has a considerable impact on a FGL influenced by SLR, as expected, although the FGL volume is more sensitive to recharge, aquifer thickness and hydraulic conductivity than SLR impacts, considering typical parameter ranges. The methodology presented in this study provides water resource managers with a rapid‐assessment tool for evaluating the likely impacts of SLR and accompanying LSI on FGLs.     

航空电磁法在黄河口地区寻找浅层淡水的地质效果

对利用航空电磁法寻找浅层淡水的方法技术进行了探索,根据找水需要编制了保留区域场的三频标差异常图,对本区的海侵界线及海侵程度进行了研究,并在咸水区内圈定浅层淡水远景区29处,对各淡水远景区进行了分析与评价.     

长江河口青草沙水库最长连续不宜取水天数

为解决上海日益增长的用水需求, 保障淡水资源安全, 需要建设长江河口避咸蓄淡特大型水库。本文应用改进的三维长江河口盐水入侵数值模式, 采用2007和2008年10个水文站盐度资料对模式进行验证, 计算青草沙水库最长不宜取水天数。本文以径流量特枯的1978—1979年作为水文计算年, 考虑三峡工程、南水北调东线工程和沿江引排水对大通实测逐日径流量的修正, 考虑潮汐、风应力和混合等作用。根据2003年地形计算得出青草沙水库的最长连续不宜取水天数为68天, 这个水库设计的重要参数已在水库建设中采用。根据2008年地形计算得出青草沙水库的最长连续不宜取水天数为54天, 已被水库调度采用。2003年至2008年北支上段河势发生了明显变化, 导致北支盐水倒灌减弱, 因此这期间的最长不宜取水天数减少。     

美洲鲥仔稚鱼淡、海水培育试验

在室内水泥池用淡水和海水培育美洲鲥(Alosa sapidissima)仔鱼,研究两种培育模式下美洲鲥的生长。结果表明,美洲鲥仔稚鱼可较好地适应海水培育环境,经33 d的培育,淡、海水培育模式下美洲鲥平均全长日增长分别为0.965 7 mm和0.922 0 mm,前者略高于后者;成活率分别为70.3%和74.7%,海水培育模式成活率略高于淡水培育模式;仔稚鱼培育期间的生长模型方程分别为Y=9.614 3+0.500 7 X+1.326 6 X2和Y=9.478 3+0.558 4 X+1.038 0 X2(Y为全长,X为日龄)。可见,两种培育模式生长差异不显著,只要生产条件许可,均可采用淡水或海水培育美洲鲥苗种。     

珠江河口咸潮问题之我见

咸潮只是河口偏于向陆一侧盐度较低（0.5~10）的那一部分盐淡混合或冲淡水体,不宜将河口“咸水”和海洋“盐水”等同或混为一谈;视“咸潮上溯”为“盐水入侵”欠当。咸潮上溯为河口自身物质的随潮运动,基本上是一种被动的行为。咸潮上溯之动力机理,与河口水、盐物质于一年、一月和一天中随潮在河口的进出、“排”“蓄”循环运动过程有关。小潮向中潮变化时期（一月中）及其初落时段（一天中）,河口正处于由“蓄”（进）转“排”（出）阶段,其时表“排”（淡水）、底“蓄”（咸水）,水体高度呈层,受异重流的影响,底部咸潮进一步上溯“冲刺”达盐度最大值。大潮向中潮变化时的压咸效果最佳。     

Chemical characteristics and environmental significance of fresh snow deposition on Urumqi Glacier No. 1 of Tianshan Mountains, China

Ice and snow chemistry of alpine glaciers is crucial for the research of regional atmospheric environment change. Fresh snow samples were weekly collected from Urumqi Glacier No.1 in the Tianshan Mountains, Xin- jiang, China, and the chemical characteristics and seasonal variations of major ions, mineral dust, δ18O and trace metals were measured. Results show that the concentrations of major ions in the snow are Ca2+ SO42- NH4+ NO3- Cl- Na+ Mg2+ K+, in which Ca2+ is the dominant cation, and SO42-is the dominant anion. All major ions have close positive correlations with each other except NO3-. δ18O shows positive correlation with air temperature change during the study period. Mineral dust particle and major ionic concentrations in fresh snow have obvious seasonal change, with high concentration in spring but low concentration in summer and autumn, which indicates that the chemical mass input from Asian dust activity to snow is very significant. Temporal changes of trace metals in fresh snow, e.g., Cd, Pb, Zn, Al, Fe, have shown that human-induced pollution of central Asian region also has large contribution to the snow chemistry on alpine glaciers of the Tianshan Mountains.     

淡水中丝状绿藻对重金属Pb2+的吸附

通过淡水中绿藻门的一些丝状种类,如毛枝藻(Stigeoclonium)、刚毛藻(Cladophora)、水绵(Spirogyra)对铅的吸附实验,研究淡水藻类与铅的吸附关系及影响因素。结果表明,淡水中丝状绿藻对铅有较强的吸附能力, 当pH值和温度以及包埋藻类的量控制在一定条件下,即pH值约为4,温度为28℃左右,按照2 g藻类处理20 mL 质量浓度为100 mg/L Pb²⁺溶液原则包埋藻类,就可以使单位藻类吸附效率达到40％。     

Fresh snow chemistry from high mountain regions in central himalayas

Investigations of atmospheric composition in the Himalayas has been limited in both temporal and spatial scales, mainly due to difficult logistics. Ideal sites for monitoring atmospheric composition and its evolution should be free from local pollution and representative of the remote troposphere (HUEBERT et al., 1980). As the Himalayas are far removed from highly industrialized regions they provide suitable locations to monitor the chemistry of the remote troposphere and to study the evolu…     

不同鲜重秋茄胚轴形态及其对幼苗生长的影响

为了探讨不同鲜重秋茄胚轴的表型性状和营养成分含量差异,及其对幼苗生长的影响,确定浙江省秋茄胚轴质量标准,提高造林质量,本研究采集4.0～5.0g、5.0～6.0g、6.0～7.0g、7.0～8.0g、8.0～9.0g、9.0～10.0g共6组不同鲜重的秋茄胚轴,测定其表型性状、营养成分含量和幼苗生长性状。结果表明,胚轴长度、横径、顶径随着胚轴鲜重的增加而显著增加。不同鲜重等级胚轴间的氮(N)、磷(P)、钾(K)和有机碳百分含量差异不显著,但随着秋茄胚轴鲜重增加,淀粉百分含量显著减小。单根胚轴的营养成分总含量随胚轴鲜重的增加而显著增加。胚轴的C:N、N:P和C:P值在鲜重7.0～8.0g等级时均显著高于其他鲜重等级。幼苗生长高、基径、叶片数及生物量随胚轴鲜重的增加而显著增加,但在5.0～6.0g、6.0～7.0g和7.0～8.0g等级间幼苗茎干重、叶干重、净生物量和总生物量差异不显著。胚轴表型性状与幼苗生长指标之间的相关性均呈显著水平(P<0.05),除胚轴P总含量与生长高之间的相关性不显著外, N、K、Na、有机碳、淀粉总含量与幼苗生长指标之间均呈显著正相关关系(P<0.0...