Computing Lippmann Diagrams from Direct Calculation of Mixing Properties of Solid Solutions: Application to the Barite-Celestite System

The Lippmann diagram for the system(Ba, Sr)SO₄-H₂O was computed at 25 °Cby determining the solid-phase activity coefficientsfrom first principles calculations. Directcalculations of the mixing properties of thebarite-celestite series indicate this solid solutionbehaves as non-ideal and non-regular. At 25 °C,the enthalpy of mixing shows a minimum around 50 mole% SrSO₄ due to an ordering tendency. Thefree energy of mixing shows two minima that delimit awide and symmetric miscibility gap (from 2.1 to 97.9 mole% SrSO₄) at this temperature. The excessfree energy of mixing requires a Guggenheim expansionseries of 5 terms to be described, where the termswith odd exponents are null as a consequence of thesymmetric distribution of the mixing properties withcomposition. The Lippmann diagram shows a peritecticpoint that corresponds to the composition of an aqueoussolution which is simultaneously at equilibrium withthe two extremes of the miscibility gap. The largedifference between the solubility products of theendmembers involves a strong preferential partitioningof the less soluble endmember towards the solid phase,which explains the extremely Ba-poor composition ofthe aqueous solution (aqueous activity fraction forBa²⁺ = 0.000446 ) at the peritectic point.     

沉积盆地有机质自由基热演化特征及其作为古温标的探索

恢复沉积盆地热历史的方法主要有古地温指标法和动力学模拟法两类.古温标法中最常用的为有机质成熟度和矿物裂变径迹,动力学模拟法中最常用的是盆地的拉张模型和挤压模型.本文针对Ⅰ型有机质自由基浓度作为沉积盆地古温标进行了探索研究.分析了自然演化系列Ⅰ型有机质的自由基的热演化特征;根据自然演化系列的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)数据,对热模拟实验下的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)值进行校正,由校正后的数据初步建立了Ⅰ型有机质的自由基浓度(Ng)与时间-温度指数(TTI)的定量模型.     

地震波有限差分数值模拟框架下的起伏地表处理方法综述

本文查阅了近30年来国内外关于有限差分方法模拟近地表复杂介质方面的文献,分析了在有限差分法框架下复杂地表地形起伏问题的处理及实现方法.总结了地震波有限差分数值模拟方面的成果.复杂地表类型很多,对地震资料的影响程度也不尽相同,要想完全描述近地表影响因素是不可能的,而关键的问题就是自由边界条件方程的处理.所有处理及实现方法中不外两种:直接法(局部)和间接(全局)法.文中列出的方法,各有特点.我们的目的是寻找合适的方法解决适合的问题.     

Foreword

Destructive earthquakes have caused great damage in China and the United States and collapsing buildings havecaused many deaths and injuries. The field of earthquake engineering studies earthquake hazards, the occurrence ofearthquakes of various magnitudes, the nature of the ground shaking during an earthquake, the vibration of structuresduring earthquakes, the strengthening of existing structures and the design of new structures to be earthquake resistant,and finally, how to cope with earthquake damage and restore a city to normal functioning. Such efforts are in progressin both countries, but unfortunately, the language barrier interferes with the free flow of information between China andthe Untied States. It would be mutually beneficial if some means could be developed to promote the exchangeof information across the Pacific Ocean. This new journal has been established for this purpose and its success willbe an important step in promoting earthquake engineering in China and the United States.     

盐酸羟胺-盐酸体系提取黄土中游离氧化铁

黄土中游离氧化铁是指示夏季风的替代性气候指标之一。使用经典的CBD法提取游离氧化铁实验过程烦琐,而且实验条件不同对浸提结果影响很大。本实验采用盐酸羟胺-盐酸体系在不同的温度下浸提黄土中的游离氧化铁。实验结果表明:温度对实验结果影响最大,盐酸浓度次之。与经典的CBD法进行对比,在一定的条件下可以代替CBD法,从而简化试验。     

用线性自由能关系预测金属络合物的热力学性质

Sverjensky与Molling提出的线性自由能关系是根据金属阳离子的热力学性质来预测等结构系列中固体相的标准生成自由能。本文研究结果证实,水溶液中金属络合物与简单金属阳离子之间也存在类似的相关关系,预测值与实验值的差异通常小于1．5kcal／mol或小于一个log单位,这一线性自由能关系对于预测自然环境中重金属的水溶物种的配分、迁移和毒性具有非常重要的应用价值。     

河北省极值气温变化特征

利用河北省60个气象观测站资料,对全省近50年极值气温变化特征进行了分析,结果表明:极端最高气温线性变化趋势不明显,但年代际变化特征突出,而极端最低气温线性升高趋势明显。低于-30℃的极端寒冷日呈线性减少趋势,而高于40℃的极端炎热日线性变化趋势不明显,但年代际变化特征突出,20世纪90年代后期以来呈多发的特点。最低气温出现偏冷段(-10℃)的天数呈线性减少趋势,出现在偏暖段(20～30℃)的天数呈线性增加趋势,在其他界限气温的天数变化趋势不明显。最高气温出现在偏冷段(-30～0℃)的天数呈明显减少趋势,在其他界限气温的天数变化趋势不明显。河北省无霜期、无冰冻期均呈明显延长趋势,平均每10年分别延长4.5天、4.6天。年平均最高气温、最低气温和平均气温都呈显著的线性升高趋势,平均每10年分别升高0.21℃、0.45℃、0.30℃,低温升温速率明显大于高温升温速率。日较差呈逐年减小趋势,平均每10年减小0.25℃。空间上最低气温表现为全省明显升高,而最高气温升温主要集中在中北部和东部沿海地区,南部升温不明显,日较差大部分地区为逐渐减小趋势。     

Study on the Free Radical Scavenging Activity of Sea Cucumber(Paracaudina chinens var.) Gelatin Hydrolysate

Gelatin from the sea cucumber(Paracaudina chinens var.) was hydrolyzed by bromelain and the hydrolysate was found to have a high free radical scavenging activity. The hydrolysate was fractionated through an ultrafiltration membrane with 5 kDa molecular weight cutoff(MWCO). The portion(less than 5 kDa) was further separated by Sephadex G-25. The active peak was col-lected and assayed for free radical scavenging activity. The scavenging rates for superoxide anion radicals(O2·-) and hydroxyl radi-cals(·OH) of the fraction with the highest activity were 29.02% and 75.41%,respectively. A rabbit liver mitochondrial free radical damage model was adopted to study the free radical scavenging activity of the fraction. The results showed that the sea cucumber gelatin hydrolysate can prevent the damage of rabbit liver and mitochondria.     

Expression of the Phycoerythrin Gene of Gracilaria lemaneiformis (Rhodophyta) in E. coli and Evaluation of the Bioactivity of Recombinant PE

Phycoerythrin (PE) is one of the most important proteins involved in light capturing during photosynthesis in red algae. Its potential biological activities had gained wide concerns. In the present study, tumor cytotoxic and hydroxyl radical assay were preformed to detect the bioactivity of recombinant PE. Recombinant plasmids pGEX-PE and pBGL were transformed into E.coli BL21 to make two recombinant strains BEX (pGEX-PE) and BGL (pBGL). PE expressing in BEX (pGEX-PE) was validated by SDS-PAGE and Western blotting analysis. SDS-PAGE analysis indicated that the PE-GST fusion protein was mostly inclusion bod- ies. Specific expression of PE was confirmed by Western blotting analysis. The recombinant E. coli BEX (pGEX-PE) cells were col- lected and sonicated. The supernatants were reserved for the tumor cytotoxic experiments. The result of tumor cytotoxic assay indi- cated that the supernatants containing PE had the activity of inhibiting the growth of Hela cells and with the increase of protein con- centration, the inhibiting rate increased from 37.31% to 63.26%, which showed significant difference from the control. Hydroxyl radical scavenging effect was tested with supernatants of BEX (pGEX-PE) and BGL (pBGL) cell lysates treated with sonication and heating. For the sonication samples, the scavenging rates of the supernatants of BEX (pGEX-PE) and BGL (pBGL) cell lysates were significantly higher than the negative control BL21(pGEX-4T) (P<0.02), and the scavenging rates increased slowly following the increase of the protein content. For the heating samples, except for the 0.2 mg mL-1 BGL (pBGL) products, the scavenging effects of the supernatants of BEX (pGEX-PE) and BGL (pBGL) cell lysates were stronger than that of negative control BL21(pGEX-4T). However, the effect intensity was not positively correlated with the increase of the protein concentration. Though a partially de- creased hydroxyl radical scavenging activity was led by heating, the biological activity was still retained and conspicuous. This re- search showed that phycoerythrin protein expressing in E. coli has the potential medical and sanitarian value.     

RTK在大比例尺地形图航测数字化测图中的应用

结合某开发区1：2000地形图航测数字化测图工程，探讨了采用GPSRTK的自由基站二步法拟合方式测量航外像控点（平高点），实施大比例尺地形图野外检测的可行性。对比测量实验表明，该方式在像控点要求的特定位置不仅能保证平面精度，也可以保证高程精度；与常规的RTK相比，该方式具有基站设置位置灵活、不需单独提前解算基准转换参数，以及显著提高工效等优点。