Composition and assemblage characteristics of magnetic minerals in layer S<Subscript>5-1</Subscript> of Xifeng and Duanjiapo sections

Relatively strongly magnetic fine components (< 30μm, XS-4J and DS-4J) which are most environmentally sensitive were separated from layer S_5-1 in the Xifeng and Duanjiapo loess sections and analyzed by MPV-3 for their morphometric characteristics and reflectance, SEM-ESD for their element contents and XRD for their mineral phases, respectively. The results showed that minerals in both samples are dominated by detrial Fe-Ti oxides of aeolian origin. In sample XS-4J the reflectance and iron contents of magnetic minerals are usually high. In addition to magnetite (Fe₃O₄), maghemite (γFe₂O₃) and hematite (Fe₂O₃), some Fe-high oxide (72.25 wt%–86.67 wt%), ilmenite (FeTiO₃), and magnetite-ulvöspinel [Fe(FeCr)O₄, Fe (FeNi)O₄] were also detected. In sample DS-4J obvious negative linear correlations were found between Ti and Fe, and the contents of Mn, Si, Al and Ca are usually high and the minerals are dominated by magnetite (maghemite), goethite (FeOOH) and limonite (containing Si and OH). In addition, the signs of corrosion of magnetic minerals and newly crystallized magnetite (maghemite) were recognized. Differences in the composition and assemblage characteristics of magnetite minerals between XS and DS reflect significant differences in source rocks and preserving conditions.     

用线性自由能关系预测金属络合物的热力学性质

Sverjensky与Molling提出的线性自由能关系是根据金属阳离子的热力学性质来预测等结构系列中固体相的标准生成自由能。本文研究结果证实,水溶液中金属络合物与简单金属阳离子之间也存在类似的相关关系,预测值与实验值的差异通常小于1．5kcal／mol或小于一个log单位,这一线性自由能关系对于预测自然环境中重金属的水溶物种的配分、迁移和毒性具有非常重要的应用价值。     

青龙县某铁矿矿区水文地质特征分析及矿坑涌水量预测

从区域水文地质、矿区水文地质两方面分析了矿区的水文地质特征,确定该矿区水文地质条件为简单,主要含水层(带)为第四系含水层、基岩风化裂隙含水带、构造破碎裂隙含水带。通过对矿床充水因素和矿坑边界条件的分析,提出利用承压水完整井结合大井法的计算方法,预测矿坑涌水量为9 283.6 m3/d,为后续矿山露采转地下开采提供依据。     

Iron(II) oxide determination in rocks and minerals

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.     

吉林东部铁矿成因类型、地质特征及找矿方向探讨

在成矿地质背景分析的基础上,划分了吉林省东部铁矿成因类型,总结了各种成因类型矿床的地质特征.结合近几年地质找矿工作的新进展,认为吉林省东部具备铁矿成矿的地质条件,铁矿的资源潜力较大,实现铁矿找矿突破是完全可能的.     

Influence of ferric iron on phase equilibria in greenschist facies assemblages: the hematite‐rich metasedimentary rocks from the Monti Pisani (Northern Apennines)

We have investigated the effects of different Fe₂O₃ bulk contents on the calculated phase equilibria of low‐T/intermediate‐P metasedimentary rocks. Thermodynamic modelling within the MnO–Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNKFMASHTO) chemical system of chloritoid‐bearing hematite‐rich metasedimentary rocks from the Variscan basement of the Pisani Mountains (Northern Apennines, Italy) fails to reproduce the observed mineral compositions when the bulk Fe₂O₃ is determined through titration. The mismatch between observed and computed mineral compositions and assemblage is resolved by tuning the effective ferric iron content by P–XFe₂O₃ diagrams, obtaining equilibration conditions of 475 °C and 9–10 kbar related to a post‐compressional phase of the Alpine collision. The introduction of ferric iron affects the stability of the main rock‐forming silicates that often yield important thermobaric information. In Fe₂O₃‐rich compositions, garnet‐ and carpholite‐in curves shift towards higher temperatures with respect to the Fe₂O₃‐free systems. The presence of a ferric‐iron oxide (hematite) prevents the formation of biotite in the mineral assemblage even at temperatures approaching 550 °C. The use of P–T–XFe₂O₃ phase diagrams may also provide P–T information in common greenschist facies metasedimentary rocks.     

Types and genesis of manganese oxide ores in Guangxi, Southwest China

Systematic studies are diven to the genesis and spatial distribution of manganese oxide deposits in Guangxi,Southwest China.The deposits are classified as 3 types and 7 subtypes among which the karst depression type is regionally characteristic an of reat potential.A genetic model is presented for the mineralization on the basis of proto-rock,tectonic background,topographic features and climatic and hydrogeological conditions.     

西石门铁矿环境水文地质分析与评价

通过分析西石门铁矿环境水文地质特征,依据水环境污染综合评价指数方法对矿区地下水环境质量的现状进行了评价.简要阐述了矿区生产和老窿水的存在对地下水资源造成的影响,矿区井巷工程在地下水位以下施工后地下水环境的一些变化趋势及初步预防措施,为将来矿区深部生产过程中提供了参考资料.     

露天铁矿禀赋优势等级划分和合理矿业税费的研究

利用自组织神经网络，对我国主要露天铁矿进行了禀赋优势等级划分。权利金大小的确定，应以铁矿资源的资产评估为基础，资产评估时合理成本的取值应是评估矿山所在同一等级矿山的平均成本。矿产资源的原有价值是权利金征收的对象。最后以歪头山为实例，计算了铁矿资源的原有价值和权利金。结果表明，目前对歪头山铁矿征收的税费仍然偏高。     

铁硫化物球粒

铁硫化物的合成,通常是通过固－气反应来实现,本文利用电弧放电的方法,使黄铁矿（ＦｅＳ２）还原成磁黄铁矿（Ｆｅ１－ｘＳ）、陨硫铁（ＦｅＳ）和金属铁（Ｆｅ）,利用反光显微镜（ＲＬＭ）,Ｘ射线衍射（ＸＲＤ）,扫描电镜（ＳＥＭ）,透射电镜（ＴＥＭ）和能谱（ＥＤＳ）综合研究合成物的特征及各物相的相互关系。初步研究了合成物的电学和磁学性能。讨论在电弧作用的还原环境里,ＦｅＳ２向ＦｅＳ、Ｆｅ１－ｘ和Ｆｅ转变的特