页岩气容积法储量计算方法及实例应用

页岩气作为一种重要的非常规天然气资源,近年来受到越来越多的关注,页岩气的成因机理、赋存相态、分布特征等与常规天然气有着明显的区别,其特殊的气体蕴藏方式导致储量计算方法也有别于常规气藏。探讨页岩气藏的特殊性,其主要表现在气体具有双重赋存状态和成藏机理具有混合性等,在此基础上提出了在页岩气藏勘探开发初期计算地质储量的一种有效方法:容积法。页岩气特殊的蕴藏方式有游离气和吸附气两种,游离气储量按照常规天然气的方法来计算,吸附气储量则参考目前已有的相对成熟的煤层气地质储量计算方法。该计算方法在北美页岩气资产地质储量估算中得到成功应用。     

Hydrofluoric Acid‐Free Digestion of Geological Samples for the Quantification of Rare Earth Elements by Inductively Coupled Plasma‐Optical Emission Spectrometry

Rare earth elements (REEs) are very important to technological development as well as to geochemical and environmental studies. In this work, hydrofluoric acid (HF) was replaced by condensed phosphoric acid (CPA) in the digestion of geological samples, and the quantification of REEs was performed by inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Six international reference materials (RMs), named DC86318, CGL 111, CGL 124, CGL 126, OKA‐2 and COQ‐1 and three Brazilian ore samples, named Araxá, Catalão and Pitinga were analysed. Only zircon and xenotime, which are potential REE‐bearing minerals, were not completely dissolved. Nevertheless, no REE associated with zircon was detected. The investigated digestion method presented many advantages: It was relatively fast (3 h), avoided fluoride precipitation, it was less hazardous because handling diluted H₃PO₄ is safer than HF, NH₄F or NH₄HF₂ aqueous solutions, it preserved the quartz fittings of the measurement equipment and the final solution contained lower levels of total dissolved solids than those produced by the fusion method.     

岩体裂隙网络非稳定渗流分析与数值模拟

针对裂隙岩体的非稳定渗流问题,通过将Darcy定理扩展到包含干区的整个裂隙网络区域,并令潜在溢出边界条件为Signorini型互补边界条件,将湿区上的非稳定渗流问题转化为全域上的一个新的初边值问题。为降低试探函数选取的难度,建立与定义在整个裂隙网络区域上的偏微分方程（PDE）提法等价的抛物型变分不等式（PVI）提法,并给出裂隙网络非稳定渗流分析的有限元数值分析格式和迭代算法,与砂槽模型试验数据的对比分析,验证其有效性。最后,将文中发展的计算方法应用到含复杂裂隙网络的边坡非稳定渗流分析,计算结果很好地反映出边坡内部自由面随库水降落的变化规律,并能准确地描述裂隙网络内部渗流运动特征及流量分布的不均匀性。     

海底输液管道内流、轴向力和压强对允许悬空长度的影响

以海底悬跨段输液管道为研究对象,考虑管内流体流动及管道轴向力和压强的作用,对其进行受力分析,导出管道振动微分方程。由于内流流速项的影响,使得导出的管道振动微分方程不能用振型分解法直接求解,故本文将解表示为具有正弦和余弦的对称和反对称的各个空间振型的总和,从而求出悬跨段管道固有频率。为防止管道发生横向涡激振动,用约化速度作为控制条件,求解出管道允许悬空长度。结果表明,管道允许悬空长度随着内流流速、轴向压力和管内压强的增加而减小,随着轴向拉力的加大而增大。     

Monthly changes of glycogen, lipid and free amino acid of oyster

Monthly difference of the chemical composition of oyster cultured along the eastern coast of Shandong Province was analyzed. The components analyzed included glycogen, fatty acid and free amino acid （FAA）. The content of glycogen was high in January and March （2.89 and 2.82 g（100 g） ^-1 on average, respectively） and low in October （2.07g（100g）^- 1 on average）. The low content of neutral lipids in October reflected a relatively poor nutritional value of oyster （1.42 g（ 100 g）^- 1 on average）. The main fatty acids of oyster were palmitic acid （16：0）, oleic acid （18： 1）, eicosapentaenoic acid （EPA, 20： 5（0 3） and docosahexaenoic acid （DHA, 22：6（0 3）. The major FAAs of oyster were Taurine, Glutamicacid, Glycin, Alanine, Arginine and Proline. Taurine was the most abundant FAA with its content ranging from 603 mg（100 g） ^-1 to 1 139 mg（ 100 g） ^-1. The high contents of glycogen, polyunsaturated fatty acid and FAA showed that oyster cultured along the eastern coast of Shandong Province was nutritionally good in January and March.     

断裂带同震温度负异常机制分析

断裂带同震温度响应,可在震后钻孔测温中获得并识别,为发震断层摩擦特性与发震机制等基础研究提供了非常独特的思路和有效手段.集集、汶川及日本东北大地震后,实施了台湾车笼埔断层钻探项目(TCDP)、汶川地震断裂带科学钻探工程(WFSD)和日本海沟快速钻探计划(JFAST).钻孔测温结果表明:滑移面上下5～20m范围内存在温度正异常,这是同震摩擦生热所致,该机制已被广泛认识和接受;同时,距滑移面20～60m范围内也存在明显的温度负异常,但其成因机制几乎还未被真正关注和认识.虽然温度负异常峰值只有正异常峰值的1/4～1/3,但温度负异常分布范围却是正异常分布范围的3～4倍,即正、负温度异常区对应的总能量基本相当.因此,断裂带震后钻孔测温中的负异常及其成因不容忽视.在详细分析几种可能的同震温度负异常机制后(如岩层热物性分布差异、流体运移、表面自由能增大及同震应力释放),发现能在理论、实验及野外观测上都得到支撑的普适性机制只有同震应力释放.这可能是断裂带震后温度负异常的主要原因.     

Thermodynamical analysis of acoustic Schwarzschild black hole

In this paper, we analyze the thermodynamic properties of acoustic Schwarzschild black holes with its parameter. The study is conducted in the extended phase space displaying the phase transition. This phase transition is examined through Gibbs free energy, specific heat, and heat capacity. Later, we discuss the thermal stability of acoustic black holes through Hawking temperature by identifying their stable and unstable regions. We calculate the corrected entropy to examine the thermal fluctuations. Through the corrected entropy we observe that there is no fluctuation in the case of small black holes. We also discuss the energy emission process from acoustic black holes. Moreover, we employ the generalized uncertainty principle to obtain a modified Lagrangian equation. We analyze the tunneling and Hawking temperature of the acoustic Schwarzschild black hole after solving the field equations.     

考虑阻尼海底悬跨段管道的动力特性及允许悬空长度

以海底悬跨段输液管道为研究对象,考虑管道结构阻尼、流体附加阻尼、管内流体流动及管道轴向力和压强的作用,对其进行受力分析,导出管道振动微分方程,进而得到管道动力特性方程。用Hermit插值函数对管道的动力特性方程进行离散得到有限元表达式,采用复模态分析法,求得管道的自振频率。为防止管道发生横向涡激振动,用约化速度作为控制条件,确定管道允许悬空长度。结果表明,管道允许悬空长度随着内流流速、轴向压力和管内压强的增加而减小,随着轴向拉力的增加而加大。