Geochemical constraints on the contribution of Louisville seamount materials to magmagenesis in the Lau back-arc basin,SW Pacific

Seamounts are an integral part of element recycling in global subduction zones. The published trace element and Pb-Sr-Nd isotope data for basaltic lavas from three key segments (Central Lau Spreading Ridge (CLSR), Eastern Lau Spreading Ridge (ELSR), and Valu Fa Ridge (VFR)) of the Lau back-arc basin were compiled to evaluate the contribution of Louisville seamount materials to their magma genesis. Two geochemical transitions, separating three provinces with distinct geochemical characteristics independent of ridge segmentation, were identified based on abrupt geochemical shifts. The origin of the geochemical transitions was determined to be the result of drastic compositional changes of subduction components added into the mantle source, rather than the transition from Indian to Pacific mid-ocean ridge basalt (MORB) mantle, or due to variable mantle fertilities. The most likely explanation for the drastic shifts in subduction input is the superimposition of Louisville materials on ‘normal’ subduction components consisting predominantly of aqueous fluids liberated from the down-going altered oceanic crust and minor pelagic sediment melts. Quantitative estimation reveals that Louisville materials contributed 0–74% and 21–83% of the Th budget, respectively, to CLSR and VFR lavas, but had no definite contribution to the lavas from the ELSR, which lies farthest away from the subducted Louisville seamount chain (LSC). The spatial association of the subducted LSC with the Louisville-affected segments suggests that the Louisville signature is regionally but not locally available in the Tonga subduction zone. Besides, the preferential melting of subducted old Cretaceous LSC crust instead of the old normal Pacific oceanic crust at similar depths implies that elevated temperature across the subduction interface or seamount erosion and rupture were required to trigger melting. A wider implication of this study, thus, is that seamount subduction may promote efficiency of element recycling in subduction zones.     

THE FREE-WILSON PARADIGM REDUX:SIGNIFICANCE OF THE FREE-WILSON COEFFICIENTS,INSIGNIFICANCE OF COEFFICIENT ‘UNCERTAINTIES’ AND STATISTICAL SINS

The Free-Wilson paradigm is an established and powerful tool for quantitatively relating activity withchemical structure.Current implementations of the paradigm,however,are flawed both conceptually andin execution.As part of an attempt to more fully realize the promise of the paradigm,it was necessaryto examine these limitations in detail.This report introduces a robust,theory-founded Free-Wilson implementation:stepwise principalcomponents regression analysis(SPCRA).SPCRA is computationally superior to previousimplementations but does not in itself correct their conceptual flaws.The development of SPCRA did,however,facilitate derivation of a simple and chemically significantinterpretation of the Free-Wilson structure-activity model.A number of statistical aspects of this modelcommonly misused in previous applications are discussed at length.These discussions provide criticalbackground for the development of an alternative implementation of the Free-Wilson paradigm.     

Detecting subtle hydrochemical anomalies with multivariate statistics: an example from ‘homogeneous’ groundwaters in the Great Artesian Basin,Australia

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO₂ input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright © 2006 John Wiley & Sons, Ltd.     

PRINCIPAL COMPONENTS REGRESSION FOR ROUTINE MULTICOMPONENT UV DETERMINATIONS: A VALIDATION PROTOCOL

A validation protocol for multicomponent spectroscopic assays based on principal componentsregression is described. Factorial design and hypothesis tests are used to establish the linearity andabsence of interaction between components in the regression model. Testing considers multiple responsevariables simultaneously so that correlation between residuals is properly treated. Assay reproducibilityand sensitivity to related substances are evaluated.     

MULTIVARIATE RESPONSE SURFACE MODELLING BY PRINCIPAL COMPONENTS ANALYSIS

Analysis of multivariate response data by modelling the principal components of the response has beenapplied to two sets of data. In both cases principal components analysis revealed the relationships amongthe response variables and exploited them to simplify the problem of modelling and optimizing themultivariate response. The models and optima obtained from the principal components comparedfavourably with the individual models and simultaneous optima.     

地理信息系统发展趋势

本文根据国内外在地理信息系统方面的进展，就地理信息系统的科学概念、基本构成和它的以下一些发展趋势作了讨论：（1）地理信息系统是构成地理学日臻完善的技术体系的重要部分；（2）空间分析功能是系统研究和应用的主要目标；（3）系统最重要的技术问题是管理和存储大量空间数据的数据结构；（4）综合性的发展特色日益明显；（5）标准化和智能型的发展方向已引起关注。     

攀枝花市大气污染物降水清除机制的研究

本文采用了主成份分析及因子分析的方法,研究了影响降水pH值的主要源及其贡献和这些源被降水清除的机制。分析结果表明:大气中一次污染物是影响降水pH及各种成分浓度的主要因素。人为污染源包括高排放源、低排放源和汽车源,它们的排放物以碱性物质为主;自然污染源包括输送物、腐烂物、自然NOx等,它们的排放物主要是酸性物质;在一般情况下,降水的pH值取决于高、低排放源排放的碱性物质的多寡;降水量越大,清除的污染物越多,在雨季各测点降水平均pH值为6.31～7.10。在高排放源影响小的地方,对持续时间长的大雨,降水后期的pH能反映自然源的影响,其值小于5.60。可见,攀枝花市酸雨几率极低甚至降水呈碱性,     

Numeric examination of multivariate soil samples

Numerical methods for the examination of multivariate soil samples are presented in geometric terms. Techniques of coordinate representation by principal components, by nonmetric scaling, and by a new method are discussed, as are techniques for agglomerative hierarchic cluster analysis. These are illustrated by two sets of previously published data.     

Helmert方差分量估计严密公式与简化公式等价性的证明

在分析了Helmert方差分量估计严密公式与简化公式迭代收敛结果一些统计性质的基础上,导出了关于收敛结果共同的求解方程,从理论上证明了两种结果的等价性,为使用简化公式提供了依据。