浙江杭嘉湖平原区土壤中营养元素丰缺状况的评价

根据杭嘉湖平原区区域地球化学调查的结果,对本区土壤中农作物营养元素含量及有效量特征进行了评价研究。研究结果表明,本区土壤中营养元素除Mo、S含量表现缺乏外,其它元素为足量和丰富水平。不同土壤中营养元素有效量水平存在明显差异。在区域分布规律上,营养元素的含量及有效量随成土母质、成土过程和人类耕作等因素的不同而显示其差异特征。评价研究结果为本区农业生产中的合理区划、科学施肥、合理种植、土壤改良等提供了重要的地球化学依据。     

Characterization of Geochemical Distributions Using Multifractal Models

The use of multifractals in the applied sciences has proven useful in the characterization and modeling of complex phenomena. Multifractal theory has also been recently applied to the study and characterization of geochemical distributions, and its relation to spatial statistics clearly stated. The present paper proposes a two-dimensional multifractal model based on a trinomial multiplicative cascade as a proxy to some geochemical distribution. The equations for the generalized dimensions, mass exponent, coarse Lipschitz–Hölder exponent, and multifractal spectrum are derived. This model was tested with an example data set used for geochemical exploration of gold deposits in Northwest Portugal. The element used was arsenic because a large number of sample assays were below detection limit for gold. Arsenic, however, has a positive correlation with gold, and the two generations of arsenopyrite identified in the gold quartz veins are consistent with different mineralizing events, which gave rise to different gold grades. Performing the multifractal analysis has shown problems arising in the subdivision of the area with boxes of constant side length and in the uncertainty the edge effects produce in the experimental estimation of the mass exponent. However, it was possible to closely fit a multifractal spectrum to the data with enrichment factors in the range 2.4–2.6 and constant K₁ = 1.3. Such parameters may give some information on the magnitude of the concentration efficiency and heterogeneity of the distribution of arsenic in the mineralized structures. In a simple test with estimated points using ordinary lognormal kriging, the fitted multifractal model showed the magnitude of smoothing in estimated data. Therefore, it is concluded that multifractal models may be useful in the stochastic simulation of geochemical distributions.     

江苏丰、沛、铜地区高氟地下水成因探讨

通过该区太古界一新生界氟的地层地球化学剖面及岩浆岩和土壤中氟的丰度的研究,论证了该区为一高氟的地球化学区。根据重矿物对比研究和地貌分析,阐明了泰沂隆起区太古界和元古界的高氟古老岩系为该区土壤沉积物源,黄河多次泛滥堆积（粘土矿物对氟的吸附）对土壤氟起了叠加富集的作用。研究揭示该区土壤水溶氟较高,经降水淋滤和浸取作用氟转入地下水,并在凹陷区或河间洼地中聚集,水体停泄、蒸发浓缩形成高氟地下水区。     

●●以下文章网络预出版（在线出版）于2022年12月20日，预计刊于《地质论评》2023年第69卷第1期(2023年1月15日发行纸质版）或2023年第69卷第2期（2023年3月15日发行纸质版）

元素富集机制的研究是重现成矿过程和查明成矿机制的基础,有助于深化对矿床的认识,为找矿提供理论依据。本文总结了近年来关于铅锌元素的迁移与沉淀机制的研究及其应用,包括3种铅锌迁移沉淀模式,4种含铅锌流体驱动模式,铅锌的迁移形式及其沉淀机制;同时简述了我国高温高压实验的发展历程以及4种高温高压模拟实验方法。重点介绍了4种高温高压实验模拟方法及其研究现状：① 高压釜实验;② 热液金刚石压腔—激光拉曼实验;③ 熔融毛细硅管—激光拉曼实验;④ 计算机模拟实验。从封闭—平衡—静止到（半）开放—非平衡—流动、淬火分析到原位观察,应是今后高温高压实验的发展方向。以地质特征为基础,采用高温高压成岩成矿模拟实验结合计算机模拟,精细刻画成矿过程并揭示元素富集机制不仅是解决实际地质问题的有效手段,更是很长一段时间内要为之努力的方向。     

贵州盘州米妥勘查区煤层顶底板Ga矿富集特征及成因

为查清贵州盘州米妥勘查区煤层顶底板及煤中Ga的赋存状况,开展钻孔勘探工作,采集煤层顶底板泥化样品39件,煤样品25件,使用电感耦合等离子体发射光谱法测定Ga含量,根据样品中Ga含量的实测结果,结合勘查区聚煤时期的古地理环境及煤层顶底板沉积物源等特征,分析上二叠统煤层顶底板中Ga矿的富集特征及成因。结果表明：米妥勘查区煤中Ga富集程度低,25件煤样品中Ga的平均含量为7.90 μg/g,远低于边界品位;煤层顶底板中Ga富集程度高,21件顶板样品中Ga含量为31.8～46.2 μg/g,平均值为39.6 μg/g,18件底板样品中Ga含量为31.1～51.4 μg/g,平均值为41.3 μg/g,底板中Ga含量均值略高于顶板。顶底板中Ga的含量达到我国煤中伴生矿的工业指标,该区域煤层顶底板及围岩具有稀散金属矿找矿前景。分析沉积的古地理环境特征及沉积物源,认为聚煤时期古地理环境多为陆相及海陆交互相,导致煤层顶底板多为泥岩及泥质砂岩,陆源碎屑物为Ga沉积提供了很好的来源,流水、风力等搬运作用为Ga提供了很好的富集方式。     

鄂尔多斯盆地下寺湾地区三叠系延长组油气富集规律

通过对下寺湾地区延长组沉积特征及演化、油气的生成条件、储层特征、油气的运移、圈闭条件及圈闭类型的综合研究,系统地分析了下寺湾地区延长组油气的富集因素和分布规律。     

渔塘坝硒矿床多元素富集与沉积环境

对采自湖北西部渔塘坝二叠系独立硒矿区的硅质岩和页岩样品进行了元素测试（微量元素、总铁、总有机碳、总硫）,分析了该区域的多元素富集及沉积环境。该区域V、Cu、As、Cd、Tl、Se、Mo、V、 Sb、 U、Ag、 Cr、Ni相对富集, Ba、Hf、Ta、W、Pb、Th相对贫化或亏损。全硫—全铁（TS—TFe）的关系表明页岩及部分硅质岩的S/Fe比值均大于1.15,说明有过量的硫存在,可能为有机硫或为其他亲硫元素沉淀提供条件。TOC—TS—TFe三角图及V/(V + Ni)表明该区域的岩石形成于缺氧或静海相环境。U/Th、Zr—Cr、P—Y等微量元素地球化学参数表明该区域有热水沉积的存在。通过对微量元素可能的来源研究分析,该区域的微量元素可能存在多种来源:热水来源、海水沉积、峨眉山玄武岩。     

Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.     

粮食中痕量氟的离子选择电极法测定

本文采用0.1mol/L HClO_4 80℃恒温水浴浸取粮食中的氟,并用氟离子选择电极于pH=1.0下直接测定其电位值。该方法浸取率高,检测限为0.016μg/ml。在0.14—1.0μg/ml之间有较好地能斯特响应。并对氟含量小于0.14μg/ml的样品提出了空白浓度校正的数字处理方法,经过空白校正能斯特响应线性范围变为0.01—1.00μg/ml。该方法适于固态生物样品中氟的测定。变异系数小于5％。     

Brick tea and its health impact

Tea bush is one of the plants cultivated in acidic soil, and is a typical hyper-accumulator of F and Al. Brick tea is a kind of brick-formed tea compressed using the older and coarse leaves and branches of tea trees. Brick tea mixed with milk is drunk as a daily indispensable beverage for Mongols, Ewenki, and other minority nationalities in the pastoral and semi-pastoral areas of Northwest China. It is reported that drinking brick tea can result in dental and skeletal fluorosis due to the high F content in it. Because Alzheimer＇s disease （AD） is related with Al in human brain, and Al has potential toxicities for skeletal and neural systems,