Analysis of the spatial variation of heavy metals in the Guadiana Estuary sediments (SW Iberian Peninsula) based on GIS-mapping techniques

This work reveals the usefulness of the GIS (Geographic Information Systems) mapping techniques to show the distribution of pollutants along an estuarine environment, as the final stage of a thorough study. In the case of study, the environmental quality of the sediments in the Guadiana river estuary was determined by means of a complete geochemical characterization consisting on the calculation of enrichment factors for the most important metals and metalloids (compared with the local background of non-contaminated sediments). The obtained results were depicted in “enrichment distribution maps” which evidenced a distribution of the elements in two groups: Group-I, elements with natural origin (Al, Fe, Mn, Co, and Cr) distributed homogeneously along the basin, and Group-II, elements associated to anthropic origin (As, Cd, Cu, Pb, Ni and Zn) with clear punctual sources besides a high concentration all over the estuary. The enrichment factors for the elements of Group-II are indicative of the existence of a noticeable diffuse historical mining pollution associated with the acid mine drainage generated in the internal zones of the basin, which could overlap minor pollution inputs from other human activities. The obtained results lead us to a reconsideration of the traditionally thought “unpolluted” environment when it was compared to nearby estuaries.     

徐闻南山镇红树林沉积物及红树植物中重金属的累积特征与迁移规律

为探究重金属在红树林沉积物及红树植物中的分布累积及迁移规律,选取了徐闻南山镇红树林为研究对象,通过测定红树林沉积物及红树植物不同部位（根、茎、叶）的重金属质量分数,运用富集因子、生物富集系数、转移系数及相关性分析等方法进行分析。结果表明：1）红树林沉积物重金属质量分数表现为铬（Cr）＞锌（Zn）＞镍（Ni）＞铜（Cu）＞铅（Pb）＞砷（As）＞汞（Hg）＞镉（Cd）,为中等变异程度;除了镍（Ni）元素外,其余7种重金属未超过国家一级标准,除了铅（Pb）元素外,其余7种重金属均超过广东省土壤环境背景值,说明研究区沉积物中重金属具有一定的积累效应。2）沉积物中砷（As）、铜（Cu）、锌（Zn）、汞（Hg）、镍（Ni）、铬（Cr）富集因子值均＞1.5,说明受到轻微人为活动影响;各站位镍（Ni）富集因子值均＞5,结合研究区背景,反映了镍（Ni）受到自然和人为输入的共同影响。3）白骨壤体内重金属主要集中在根部,而红海榄体内重金属在根茎叶中分布相对均匀。白骨壤根茎叶部位的大多数重金属质量分数远高于红海榄,说明白骨壤对重金属的吸附能力比红海榄强。汞（Hg）集中分布在植物的叶片部位,且与其他重金属之间相关性不明显;推测汞（Hg）主要通过叶片吸收进入植物体内,与交通运输污染有关。4）不同红树植物对不同重金属富集能力各异,白骨壤对重金属的富集能力表现为：镉（Cd）＞砷（As）＞铜（Cu）＞锌（Zn）＞汞（Hg）＞铅（Pb）＞镍（Ni）＞铬（Cr）,红海榄表现为：镉（Cd）＞铜（Cu）＞汞（Hg）＞锌（Zn）＞铅（Pb）＞砷（As）＞镍（Ni）＞铬（Cr）。白骨壤和红海榄对汞（Hg）的运移能力都较强;红海榄对镉（Cd）的富集能力和转运能力都较强,而白骨壤对镉（Cd）富集能力较强,转运能力却较弱,这说明红树植物对重金属元素的富集能力与转运能力不存在正比关系。     

广西河池五圩矿田箭猪坡矿区主要成矿元素富集规律

箭猪坡矿床位于羌塘-扬子克拉通滇黔桂被动陆缘南盘江—右江裂谷盆地南丹坳陷带的东南缘,属湘中—桂中北(坳陷)成矿带桂中北成矿亚带芒场-大厂成矿带.主要含矿地层为下泥盆统塘丁组灰黑色条带状及薄层状绢云母泥岩,矿区内NNW向的张扭性断裂,是矿床的主要控矿构造,矿脉的产状及形态,严格受其控制.在总结前人认识基础上,通过野外地质...     

红石泉铀矿床黑云母与晶质铀矿同步富集作用探讨

红石泉铀矿床是以岩浆气成热液成矿作用占主导地位的复成因型铀矿床。研究结果表明,黑云母的结晶时间明显晚于伟晶状白岗岩中的长石、石英等主要造岩矿物,这是由白岗质 岩浆本身的物质成分和物理化学条件所决定的。岩体边缘的黑云母与晶质铀矿同步富集作用是以元素地球化学和矿物热力学作用为主导的地质作用。黑云母与晶质铀矿结晶时间相近,具有一定的成因联系,并且,其组份具有明显的亲缘性是二者密切共生的原因。     

粮食中痕量氟的离子选择电极法测定

本文采用0.1mol/L HClO_4 80℃恒温水浴浸取粮食中的氟,并用氟离子选择电极于pH=1.0下直接测定其电位值。该方法浸取率高,检测限为0.016μg/ml。在0.14—1.0μg/ml之间有较好地能斯特响应。并对氟含量小于0.14μg/ml的样品提出了空白浓度校正的数字处理方法,经过空白校正能斯特响应线性范围变为0.01—1.00μg/ml。该方法适于固态生物样品中氟的测定。变异系数小于5％。     

秦巴地区砂金矿的分布及富集规律

本文通过对秦巴陕、甘、川、豫、鄂五省已知砂金矿床资料的整理和综合,简要的总结了区内砂金矿床的成因,形态类型,不同类型砂金矿床的地质特征及砂金矿的富集规律。对砂金矿的普查找矿工作有一定的指导意义。     

A CASE STUDY ON SANDSTORM

The favourable synoptic situation and climate background for a sandstorm process,which occurred in theperiod 9—16 April 1988,have been studied through analyzing weather maps,meteorological elements,satellitecloud pictures and sandstorm trajectories.The sand dust origin area,the directions and the paths of sanddust transport,and the extent the sand dust reached are also investigated.The results of measurments andanalysis indicate that the concentration of sand dust particles is 10 times greater than the normal.It is also shownthat the elements in the sand dust are lithophylic and come from natural source through the chemical composi-tion analysis of the sand dust,so that the sand dust has not been polluted by human activities.     

Geochemistry of the Baishitouquan Amazonite—and Topaz—bearing Granite in the Mid—Tianshan Belt,Xinjiang,China

The Baishitouquan amazonite and topaz-bearing granite is one of the typical high-rubidium and high-fluorine granites in the eastern part of the Mid-Tianshan belt. This intrusion is in sharp contact with Mid-Proterozoic schists, gneisses and marbles, and is composed of four zones transitional from the bottom upwards: leucogranite, amazonite granite, topaz-bearing amazonite granite and topaz quartz albitite. The Baishitouquan granite contains highly ordered K-feldspar, Li-rich mica, Mn-rich garnet, α-quartz and low temperature zircon and is chemically high in Si, K, Na, Al, Li, Rb, Cs and F, and low in Ti, Fe, Ca, Mg, P, Co, Ni, Cr, V, Sr and Ba, with Na₂O<K₂O. Amazonite from the amazonite granite zone contains 1867 ppm Rb. The F contents of bulk rocks are 3040 and 4597 for the amazonite granite and topaz-bearing amazonite granite zones, respectively. These two zones have δ¹⁸O values of 8.97–9.85‰ (SMOW) and show flat REE distribution patterns with strong Eu depletion. K-Ar and Rb-Sr ages of this intrusion are 226. 6 Ma and 209. 6 Ma respectively, with an initial⁸⁷Sr/⁸⁶Sr ratio of 0.987±0.213. The Baishitouquan granite is the product of crystallization of a low temperature, and water, rubidium and fluorine-rich magma, which may have been derived from partial melting of muscovite-rich crustal rocks. Consolidation of this granite involved two contrasting and successive stages: melt crystallization and hydrothermal metasomatism and precipitation. Various geological features of this granite were formed during the transition from the magmatic to the hydrothermal stage.     

成矿组分沉积同生富集的一种新机制:动态海水团的混合过程

海洋可以被分成若干特征各异的、运动着的海水团，各种海洋现象就源于海水团的运动和相互作用。分隔不同海水团的前锋面上的混合作用是促使成矿组分发生沉淀富集的地球化学障。在海水团前锋混合带上，成矿组分在沉积物中产生同生富集，结果生成沉积矿床或矿源层。这是一种在时间上广泛发生但又尚未被人们所认识的崭新机制。     

浙江杭嘉湖平原区土壤中营养元素丰缺状况的评价

根据杭嘉湖平原区区域地球化学调查的结果,对本区土壤中农作物营养元素含量及有效量特征进行了评价研究。研究结果表明,本区土壤中营养元素除Mo、S含量表现缺乏外,其它元素为足量和丰富水平。不同土壤中营养元素有效量水平存在明显差异。在区域分布规律上,营养元素的含量及有效量随成土母质、成土过程和人类耕作等因素的不同而显示其差异特征。评价研究结果为本区农业生产中的合理区划、科学施肥、合理种植、土壤改良等提供了重要的地球化学依据。