富镉锌矿成矿流体地球化学研究:以贵州都匀牛角塘富镉锌矿为例

通过对贵州都匀牛角塘富镉锌矿包裹体的研究,发现有一定数量的有机包裹体。该矿床与密西西比河谷型（ＭＶＴ）矿床相似,均属于Ｎａ＾＋－Ｃａ＾２＋－Ｋ＾＋－Ｍｇ＾２＋－Ｃｌ＾－体系,同时,两者在成矿流体温度、盐度和密度方面也有一定差别。该矿床成矿流体组分与油田卤水相似,仅Ｃａ＾２＋和Ｍｇ＾２＋含量偏高,这可能与晚阶段的碳酸盐有关。笔者认为,成矿流体可能与麻江古油藏的油田卤水有关,正是由于油田卤水携带了Ｃｄ     

热水沉积研究及相关科学问题

本评述了现代大洋底、大陆边缘及大陆热区流体活动和热水沉积的观察研究及其重大理论意义;分析了古代热水沉积岩的普遍性、多样性、规律性及在确立VMS型和Sedex型成矿认识中的作用;提出了三个与热水沉积相关科学问题：盆地动力学演化的热水沉积响应,盆地古流体场及其演化的热水沉积记录．盆地演化-盆地流体-流体成矿三动态耦合。利用盆地中热水沉积序列对盆地发生发展及盆地异常热史和盆地流体演化的详细记载,配合盆地流体数值模拟,是认识盆地流体及其成矿效应等科学问题的全新思路和有效途径。南秦蛉热水沉积海盆具备开展此方面研究的优越条件。     

Hydrothermal Fluid Evolution Associated with Gold Mineralization at the Wenyu Mine, Xiaoqinling District, China

Abstract: The Wenyu mesothermal gold deposit is located in the Xiaoqinling district about 1000 km southwest of Beijing in central China. It occurs in the Late Archean to Early Proterozoic metamorphosed volcanic and sedimentary rocks. Three distinct stages of veins have been identified: (I) gold‐poor quartz–pyrite veins, (II) gold‐rich sulfide–quartz veins, and (III) gold‐poor carbonate–quartz veins. Stage II can be subdivided into IIa and IIb. Gold typically occurs as fracture‐fillings associated with chalcopyrite and galena. Fluid inclusions were examined in quartz samples from veins of both stage I and II. Three types of fluid inclusions are identified: CO₂–H₂O, CO₂–rich, and aqueous inclusions. The first two types are of primary in origin. The last type occurs in two ways: coexisting with CO₂–H₂O and CO₂–rich inclusions and thus primary in origin; and occurring along late healed fractures and hence secondary in origin. CO₂–H₂O inclusions display progressively decreasing Th and increasing Thco₂, from the highest Th (311–408C) and lowest Thco₂ (average 18C) in stage I quartz through middle Th (284–358C) and ThCO₂(average 25C) in stage IIa quartz to the lowest Th (275–314C) and highest ThCO₂ (average 28C) in stage IIb quartz, indicating an evolving H₂O–CO₂–NaCl fluid system. CO₂–rich and primary aqueous inclusions show consistent ThCO₂ or Th with their coexistent CO₂–H₂O inclusions. Whereas the secondary aqueous inclusions in stage I and IIa quartz have almost the same Th and salinity as the primary aqueous inclusions in stage IIb quartz. Comparing with CO₂–H₂O inclusions, these non–CO₂, low salinity aqueous inclusions may come from different origin, most probably meteoric water. Unlike in both stage I and IIa quartz, fluid inclusions in stage IIb do not show evidence of fluid immiscibility. The fact that most of gold is associated with stage IIa and IIb veins and not with veins of stage I which is the main stage of vein formation suggests that gold deposition occurs at the later stage of fluid immiscibility. The continuing phase separation led to the deposition of large amounts of gold at the Wenyu mine.     

超临界萃取／气相色谱—质谱测定油页岩中的生物标志物

采用超临界萃取 /气相色谱 -质谱技术测定了广东茂名油页岩中环己烷的链取代烃、甾烷、甾烯和藿烷等生物标志物 ,其分析结果与经典索式抽提和文献结果基本相符。该方法与索式抽提法相比简单、快速、无污染和危险 ,可用于油页岩等固体样品中生物标志物的分析     

煤层气泡沫水泥浆固井工艺技术及现场应用

针对沁水盆地南部煤层气井储层压力低、易漏失、易坍塌的特点,开发了超低密度泡沫水泥浆体系及暂堵型前置液体系,并形成了泡沫水泥浆固井技术。泡沫水泥浆体系密度为1.10~1.20 g/cm³,具有良好的流动性能、无游离液、沉降稳定性好、API失水量小于50 mL/30 min、稠化时间合理、水泥石强度高等优点;暂堵型前置液体系具有良好的流变性能,对3号煤层具有良好的堵漏能力。根据钻井过程中出现的漏失情况、完钻后的钻井液返出情况及井壁稳定情况,从固井浆体的用量、顶替液的顶替排量等方面总结了泡沫水泥浆固井的配套工艺措施。在沁水盆地南部现场试验了4口井,取得了较好的效果。     

Dolomitization of the Waulsortian Limestone (Lower Carboniferous) in the Irish Midlands

The Waulsortian Limestone (Lower Carboniferous) of the southern Irish Midlands is dolomitized pervasively over a much larger region than previous studies have documented. This study indicates a complex, multistage, multiple fluid history for regional dolomitization. Partially and completely dolomitized sections of Waulsortian Limestones are characterized by finely crystalline (0·01–0·3 mm) planar dolomite. Planar replacive dolomite is commonly followed by coarse (≥0·5 mm) nonplanar replacive dolomite, and pervasive void‐filling saddle dolomite cement is frequently associated with Zn–Pb mineralization. Planar dolomite has average δ¹⁸O and δ¹³C values (‰ PDB) of –4·8 and 3·9 respectively. These are lower oxygen and slightly higher carbon isotope values than averages for marine limestones in the Waulsortian (δ¹⁸O=–2·2, δ¹³C=3·7). Mean C and O isotope values of planar replacive dolomite are also distinct from those of nonplanar and saddle dolomite cement (–7·0 and 3·3; –7·4 and 2·4 respectively). Fluid inclusions indicate a complex history involving at least three chemically and thermally distinct fluids during dolomite cementation. The petrography and geochemistry of planar dolomites are consistent with an early diagenetic origin, possibly in equilibrium with modified Carboniferous sea water. Where the Waulsortian was exposed to hydrothermal fluids (70–280 °C), planar dolomite underwent a neomorphic recrystallization to a coarser crystalline, planar and nonplanar dolomite characterized by lower δ¹⁸O values. Void‐filling dolomite cement is isotopically similar to nonplanar, replacive dolomite and reflects a similar origin from hydrothermal fluids. This history of multiple stages of dolomitization is significantly more complex than earlier models proposed for the Irish Midlands and provides a framework upon which to test competing models of regional vs. localized fluid flow.     

Petrogenetic and Metallogenetic Background of the Dajing Cu–Sn–Ag–Pb–Zn Ore Deposit, Inner Mongolia, and Characteristics of the Mineralizing Fluid

Abstract: The Dajing Cu–Sn–Ag–Pb–Zn ore deposit, Inner Mongolia of China, is a fissure‐filling hydrothermal ore deposit that occurs within the Upper Permian Linxi group. No magmatic pluton and volcanic rocks outcrop on the surface of the deposit. Most of ore veins show clear‐cut boundary with country rocks. Wallrock alterations that include silicification, carbonation, chlori–tization, and sericitization are generally weak and occur in the close vicinity of ore veins. Mineralization is divided into three stages: (1) cassiterite–arsenopyrite–quartz stage, (2) sulfide stage, and (3) Pb–Zn–Ag–carbonate stage. These mineralization stages have distinct ranges of homogenization temperatures, 290–350C for Stage 1, 260–320C for Stage 2, and 150–250C for Stage 3. However, salinities for Stages 1, 2, and 3 overlap and range between 2.2 and 10.4 wt % NaCl equivalent. The dD values relative to V‐SMOW of inclusion water from quartz are lower than –88% and centered at –100 to –130%. The δ³⁴S values relative to CDT of sulfide ore minerals and δ¹³C values relative to PDB of carbonate gangue minerals, vary from –0.3 to +2.6%, and from –7.0 to –2.9%, respectively. Integrated isotopic data point to two major contributions to the mineralizing fluid that include a dominant meteoric‐derived water and the other from hypogene magma for sulfur and carbon species. Analyses of inclusion gas and liquid compositions are performed. The H₂O and CO₂ are the two most abundant gaseous components, whereas SO₄^2‐ and Cl^‐, and Na⁺, Ca²⁺, and K⁺ are the major anions and cations, respectively. A linear trend is shown on the gaseous H₂O versus CO₂ plot. Phase separation is excluded as cause for the trend on the basis of isotope data and fluid inclusion microthermometry. In addition, a weak wallrock alteration does not support fluid‐rock interaction as an efficient mechanism. Hence, the linear H₂O–CO₂ trend is interpreted in terms of absorption or dilution of CO₂–dominant magmatic vapor by meteoric‐derived water. Cooling effects resulting from dilution may have caused precipitation of ore minerals. Major and trace element compositions of regional granites show a high‐K calc–alkaline characteristics and an arc–affinity. Lead isotopic compositions of galena samples from the Dajing deposit exhibit elevated U/Pb and Th/Pb ratios. These characteristics indicate a common source of supra subduction zone mantle wedge for regional granites and metals from the Dajing deposit.     

松辽盆地大陆科钻二开段大井眼钻井液技术

CCSD-SK2井是一口钻穿松辽盆地白垩纪陆相沉积地层的中国大陆科学钻探井。二开段先以216mm口径钻至2806.20m,然后进行444.5mm口径扩孔。泥页岩地层大井眼钻进过程中粘土矿物含量高且易造浆,砂砾岩层渗透性强易粘卡,井壁稳定控制与钻屑携带难度大。选用了钾铵聚合物钻井液体系和聚磺钻井液体系,通过正交实验确定了钻井液配方。将钻井液控制在合适的密度、较低的失水量以及较强的封堵性,有效实现了井壁稳定;保持适当的环空返速、较高的动塑比以及定期打稠塞举砂等措施,有效实现了井眼净化。1086.45m~1147.56m与1182.74m~1256.01m井段累计收获岩心130.90m,取心率达到97.41%,平均机械钻速为0.84m/h;最终顺利钻至2806.20m。     

断层参数对承压水体上采煤的影响分析

根据流固耦合理论,采用有限元数值模拟的方法,针对承压水体上采煤过程中断层参数(断距、倾角)对煤层、围岩的应力、变形和水压力变化的影响进行了模拟分析,探讨了存在断层时突水的机理和可能的突水点位置,并定量分析了防水煤柱的预留距离。得出以下结论:(1)当存在正断层时,多发生断层破坏型突水,而底板破坏型突水发生的几率较小;(2)突水性质和突水发生位置受断层断距和倾角的影响不大,煤层和采煤工作面附近的底板围岩都可能成为突水涌出点;(3)随着断层断距和倾角的增加,防水煤柱的合理留设距离应随之增大。以上结果可为实际矿井采煤防突水设计提供参考。 更多还原