琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律,定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上,分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后,综合各因素的历史演化过程,初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大;水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件;超过600 m水深的海域水合物稳定带厚度大部分超过 100 m,其中西北部稳定带的最大厚度超过300 m,是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果,推测其形成与天然气水合物的分解释放有关。     

非均一相互作用能对超薄膜生长影响的Monte Carlo模拟研究

利用Monte Carlo (MC)模拟技术研究了非均一的吸附原子与基底相互作用能在一定的生长条件下对超薄膜生长过程的影响.非均一相互作用能是由基底表面原子在垂直和水平方向上实际位置与理想晶格原子位置的偏差所造成.本文用高斯分布来表示这种非均一相互作用能.模拟结果表明:非均一相互作用能对超薄膜的生长过程及薄膜的形貌有显著的影响.这种影响同时受到生长条件的限制,在中等温度时相互作用能的非均一性对岛的个数、平均大小的影响最显著;温度的增加在一定程度上可抵御相互作用能的非均一性对薄膜生长的影响.     

Spectroscopic ellipsometric study of the optical properties of Ag2O film prepared by direct-current magnetron reactive sputtering

The Ag₂O film, as-deposited by direct-current magnetron reactive sputtering at a substrate temperature of 150 °C, clearly shows a preferential orientation (111), and is capable of lowering the threshold value of the thermal decomposition temperature to about 200 °C, which is helpful to its application in optical and magneto-optical storage. This paper fits its optical constants in terms of a general oscillator model by using measured ellipsometric parameters. The fitted oscillator energy 2.487 eV is close to the optical direct interband transition energy value of the Ag₂O film determined by Tauc equation; whereas, the fitted oscillator energy 4.249 eV is far from the fitted plasma oscillator energy 4.756 eV by single-oscillator energy. The photoluminescence spectrum centred at about 2.31 eV indicates a direct-energy gap photoluminescence mechanism of the Ag₂O film.     

Thickness distribution and extent of sea ice and snow in Prydz Bay and surrounding waters observed in 2012/2013 austral summer

Three ship-based observational campaigns were conducted to survey sea ice and snow in Prydz Bay and the surrounding waters(64.40°S–69.40°S, 76.11°E–81.29°E) from 28 November 2012 to 3 February 2013. In this paper, we present the sea ice extent and its variation, and the ice and snow thickness distributions and their variations with time in the observed zone. In the pack ice zone, the southern edge of the pack ice changed little, whereas the northern edge retreated significantly during the two earlier observation periods. Compared with the pack ice, the fast ice exhibited a significantly slower variation in extent with its northernmost edge retreating southwards by 6.7 km at a rate of 0.37 km?d-1. Generally, ice showed an increment in thickness with increasing latitude from the end of November to the middle of December. Ice and snow thickness followed an approximate normal distribution during the two earlier observations(79.7±28.9 cm, 79.1±19.1 cm for ice thickness, and 11.6±6.1 cm, 9.6±3.4 cm for snow thickness, respectively), and the distribution tended to be more concentrated in mid-December than in late November. The expected value of ice thickness decreased by 0.6 cm, whereas that of snow thickness decreased by 2 cm from 28 November to 18 December 2012. Ice thickness distribution showed no obvious regularity between 31 January and 3 February, 2013.     

云顶以下臭氧对TOMS反演臭氧总量的影响及反演方法的理论研究

目前紫外后向散射反演臭氧总量的所有算法,都将云考虑成不透明的Lambertian反射体,并假定云顶有效反照率不随波长的变化而变化.然而本文通过模拟计算发现,由于云散射、瑞利散射、臭氧吸收三种作用的综合结果,云顶的有效反照率是与波长相关的,即使光学厚度比较大的云,辐射也可由云顶继续向下传输,因而会受到云顶以下臭氧吸收的影响.用V7方法进行反演,模拟计算结果表明：云的出现使得云顶以下,特别是云内光程增强,导致紫外波段的臭氧吸收衰减增大,所以反演出的臭氧总量值比真实值偏大,本文称这种现象为“云吸收效应”,并讨论了该效应的影响因子.最后,在辐射传输模拟的基础上建立一套反演算法,大大减弱了“云吸收效应”的影响.     

Crustal complexity in the Lachlan Orogen revealed from teleseismic receiver functions

There is an ongoing debate about the tectonic evolution of southeast Australia, particularly about the causes and nature of its accretion to a much older Precambrian core to the west. Seismic imaging of the crust can provide useful clues to address this issue. Seismic tomography imaging is a powerful tool often employed to map elastic properties of the Earth's lithosphere, but in most cases does not constrain well the depth of discontinuities such as the Mohorovi?i? (Moho). In this study, an alternative imaging technique known as receiver function (RF) has been employed for seismic stations near Canberra in the Lachlan Orogen to investigate: (i) the shear-wave-velocity profile in the crust and uppermost mantle, (ii) variations in the Moho depth beneath the Lachlan Orogen, and (iii) the nature of the transition between the crust and mantle. A number of styles of RF analyses were conducted: H-K stacking to obtain the best compressional–shear velocity (V _P /V _S) ratio and crustal thickness; nonlinear inversion for the shear-wave-velocity structure and inversion of the observed variations in RFs with back-azimuth to investigate potential dipping of the crustal layers and anisotropy. The thick crust (up to 48 km) and the mostly intermediate nature of the crust?mantle transition in the Lachlan Orogen could be due to the presence of underplating at the base of the crust, and possibly to the existing thick piles of Ordovician mafic rocks present in the mid and lower crust. Results from numerical modelling of RFs at three seismic stations (CAN, CNB and YNG) suggest that the observed variations with back-azimuth could be related to a complex structure beneath these stations with the likelihood of both a dipping Moho and crustal anisotropy. Our analysis reveals crustal thickening to the west beneath CAN station which could be due to slab convergence. The crustal thickening may also be related to the broad Macquarie volcanic arc, which is rooted to the Moho. The crustal anisotropy may arise from a strong N–S structural trend in the eastern Lachlan Orogen and to the preferred crystallographic orientation of seismically anisotropic minerals in the lower and middle crust related to the paleo-Pacific plate convergence.     

Modelling of groundwater flow in heterogeneous porous media by finite element method

The HySuf‐FEM code (Hydrodynamic of Subsurface Flow by Finite Element Method) is proposed in this article in order to estimate the spatial variability of the transmissivity values of the Berrechid aquifer (Morocco). The calibration of the model is based on the hydraulic head, hydraulic conductivity and recharge. Three numerical tests are used to validate the model and verify its convergence. The first test case consists in using the steady analytical solution of the Poisson equation. In the second, the model has been compared with the hydrogeological system which is characterized by an unconfined monolayer (isotropic layer) and computed by using PMWIN‐MODFLOW software. The third test case is based on the comparison between the results of HySuf‐FEM and the multiple cell balance method in the aquifer system with natural boundaries case. Good agreement between the Hydrodynamic of Subsurface Flow, the numerical tests and the spatial distribution of the thickening of the hydrogeological system is deduced from the analysis and the interpretations of hydrogeological wells. Copyright © 2011 John Wiley & Sons, Ltd.     

Influence of the surface microlayer on the flux of nonconservative trace gases (CO,H2, CH4, N2O) across the ocean-atmosphere interface

Gas exchange experiments were conducted in the tropical Atlantic Ocean during a ship expedition with FS Meteor using a small rubber raft. The temporal change of the mixing ratios of CO, H₂, CH₄ and N₂O in the headspace of a floating glass box and the concentrations of these gases in the water phase were measured to determine their transfer velocities across the ocean-atmosphere interface. The ocean acted as a sink for these gases when the water was undersaturated with respect to the mixing ratio in the headspace. The transfer velocities were different for the individual gases and showed still large differences even when normalized for diffusivity. Applying the laminar film model, film thicknesses of 20 to 70 m were calculated for the observed flux rates of the different gas species. When the water was supersaturated with respect to atmospheric CO, H₂, CH₄ and N₂O, the transfer velocities of the emission process were smaller than those determined for the deposition process. In case of H₂ and CH₄, emission was even not calculable although, based on the observed gradient, the laminar film model predicted significant fluxes at the air-sea interface. The results are interpreted by destruction processes active within the surface microlayer.     

砂岩风化晕厚度在广东晚更新世测年中的应用

广东地区河流阶地和冲积扇沉积物中砂岩砾石风化晕随时间增厚。风化晕生长速度呈指数衰减,并拟合于下列公式:T 1485D4.13这里T=时间,以年表示,D=沉积物表部约50块砾石风化晕厚度的加权平均值,以毫米表示。利用风化晕厚度确定出广东地区河流第一和第二级阶地分别为1000—13300年和8600—26500年,肇庆盆地北部山前地带第Ⅰ和第Ⅱ级冲积扇分别为51500年和24400年。同时,在构造地貌变形分析的基础上,估算出本区三条主要北东向断裂带在晚更新世—中全新世的垂直断层作用速度为0.6—1.6毫米/年,中全新世甚或晚更新世晚期以来的活动速度极小