围海造陆工程泄水口悬浮物扩散规律分析

掌握围海造陆工程泄水口悬浮物扩散规律,对保护海洋水环境质量具有重要意义。选取围海造陆工程泄水口为研究对象,基于泥沙对流扩散方程,推求出泄水口悬浮物扩散平面二维分析解表达式。开展现场观测,确定泄水口源强取值,并对泄水口悬浮物扩散进行理论计算和分析。研究结果显示,围海造陆工程施工后期,泄水口悬浮物流失非常严重。泄水口附近水域出现的最大悬浮物浓度主要由源强的大小来决定,悬浮物扩散范围主要由流速的大小来控制。     

黄河沉积物向渤海湾扩散的沉积地球化学示踪

使用ICP-AES和ICP-MS对渤海中部118°54′E左右南北向断面的表层沉积物中53种常、微量及稀土元素进行了测试,研究了其含量变化和分布特征,并进行了物质组成分析。研究表明:该区沉积物以B94站为界,南北差异明显,南部区域沉积物以黏土质粉砂为主,富集Al2O3,CaO,Fe2O3,MgO,MnO,P2O5和TiO等常量元素以及绝大多数的微量元素和稀土元素等与细颗粒黏土矿物相关的元素;北部区域沉积物以粉砂-砂为主,富集SiO2,K2O和Na2O等常量元素以及Zr,Ba,Sr,Sb和Hf等微量元素,稀土元素相对亏损。物源对比表明南部沉积物具有黄河来源沉积物特点,北部沉积物具有滦河来源特点,两者的分界大致在38°42′N附近。河口动力过程、渤海环流是影响该区沉积物扩散的主要因素。     

数字滤波技术在潮汐观测中的应用研究

潮汐是重要的海洋物理要素。瞬时变化的海面高度信息除了包含潮汐信息外,还包括波浪等高频干扰信息,因此需要对干扰信息进行滤除。如何从获取到的海面瞬时高度变化中提取出潮汐信息就成为一个关键问题。海洋学中通常是通过低通滤波来获取低频的潮汐信息。通过分析常用的3种低通数字滤波的方法,即滑动平均法、快速傅里叶变换法和小波变换法,对3种低通滤波方法应用于潮汐数据处理的效果进行了比较分析,得出滑动平均法在潮汐信息提取中具有较高应用价值的结论。     

Ronge-Kutta法在计算复杂构造区域地震波旅行时中的应用

采用Ronge-Kutta射线追踪法对地震勘探中几个典型地质模型的地震波射线路径和旅行时计算的实例和效果进行分析。将Ronge-Kutta射线追踪模拟的结果与程函方程计算的时距曲线结果进行对比,验证了Ronge-Kutta射线追踪法的易实现性和程函方程有限差分旅行时算法的强稳定性,表明Ronge-Kutta射线追踪法在复杂构造区域进行地震射线路径和旅行时计算时能得到较好的模拟效果。     

基于Landsat TM影像不同地表温度反演算法的比较

地表温度是反映地表环境的一个重要参数,精确获取地表温度的方法对研究城市热岛效应、进行生态环境监测评价是必不可少的。利用遥感手段进行地表温度的反演是一种较新颖的方法,相对成熟的反演算法主要有单通道算法、辐射传输方程法及单窗算法。本文以山东省威海市Landsat TM数据为例,分别利用辐射传输方程法和单窗算法进行地表温度反演,通过遥感目视解译的方法提取研究区各类典型地物对应的地表温度,进行统计分析,结果表明,两者反演得到的地表温度具有一致的变化趋势,其中单窗算法中不同典型地物的地表温度整体标准差较小,如建设用地为0.530,起伏波动小,算法精度略优于辐射传输方程法。     

热带风压场平衡特征及其对GRAPES系统中同化预报的影响研究I:平衡特征分析

本文基于GRAPES全球模式的短期预报误差样本,利用赤道波动正规模态研究了热带风、压场平衡特征,并根据这些特征分析了线性平衡方程(LBE)在该区域应用时存在的问题。结果表明:(1)赤道波动能成功解释热带短期预报误差样本的大部分分量,对流层中层为60%~80%,对流层顶和平流层低层为80%以上。(2)在可解释的误差方差中,赤道罗斯贝波(ER)占比仅为30%~55%,其他赤道波动的作用不可忽视。(3)在ER模态基础上引入其他赤道波动会大幅削弱原有风、压场平衡约束,重力惯性波与Kelvin波的作用最为显著。此时,对流层中层位势高度h与u风、v风间的约束接近于零,而平流层低层h-u的平衡特征由Kelvin波主导。(4)LBE主要表达了ER模态下的风、压场平衡特征,与实际情形相比高估了热带风、压场的耦合程度,进一步的改进中需削弱这一虚假平衡,使得热带风、压场分析变得更加独立。     

From an initial transient-state to a steady-state in metamorphic reactions: An experimental approach in the system dolomite-quartz-H2O

Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H₂O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /L_CaOCaO and b = /L_MgOMgO) but also on the relative rate P = (−2ξ₁ − ξ₂)/(–ξ₁ − 2ξ₂) of competing reactions: Dol + 2Qtz = Di + 2CO₂ (ξ₁) and 2Dol + Qtz = Fo + 2Cal + 2CO₂ (ξ₂). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.     

Angstrom公式参数对ET0的影响及FAO建议值适用性评价

作为计算太阳总辐射(R_s)的主要公式,Angstrom公式参数(a、b)的合理取值是计算参照腾发量(ET₀)的重要前提。针对FAO所提出的a、b建议值(a=0.25、b=0.5)在中国无辐射观测资料地区被大量使用,而其合理性尚未得到系统评价的情况,基于中国104个地面站的观测数据,在逐月时间尺度上,讨论了a、b变化对ET₀的影响,分析了a、b的地区分布规律,评价了FAO建议值所导致的ET₀计算误差,进而阐明了该建议值在中国7个区域的适用性。提出了无辐射资料情况下a、b的地区综合取值方法。主要研究结论是:①参数a、b偏差对ET₀的计算有重要影响,在中国无资料地区采用FAO建议值将导致较大的太阳总辐射(R_s)和ET₀计算误差。②大多数站点,a的率定值较FAO建议值明显偏小,而b的率定值明显偏大。新疆地区和华南地区a、b率定值分布比较集中,而在其它区域比较分散。③FAO建议参数值在东北、西北和新疆3个区域计算ET₀的适用性较好,而在西南和华南两个区域的适用性很差,计算的ET₀偏高较大。④提出的地区综合取值方法,能使R_s和ET₀的计算精度较FAO建议值显著提高。     

Numerical estimation of effective diffusion coefficients for charged porous materials based on micro-scale analyses

In order to describe diffusive transport of solutes through a porous material, estimation of effective diffusion coefficients is required. It has been shown theoretically that in the case of uncharged porous materials the effective diffusion coefficient of solutes is a function of the pore morphology of the material and can be described by the tortuosity (tensor) (Bear, 1988 [1]). Given detailed information of the pore geometry at the micro-scale the tortuosity of different materials can be accurately estimated using homogenization procedures. However, many engineering materials (e.g., clays and shales) are characterized by electrical surface charges on particles of the porous material which strongly affect the (diffusive) transport properties of ions. For these type of materials, estimation of effective diffusion coefficients have been mostly based on phenomenological equations with no link to underlying micro-scale properties of these charged materials although a few recent studies have used alternative methods to obtain the diffusion parameters (Jougnot et al., 2009; Pivonka et al., 2009; Revil and Linde, 2006 2, 3 and 4). In this paper we employ a recently proposed up-scaled Poisson–Nernst–Planck type of equation (PNP) and its micro-scale counterpart to estimate effective ion diffusion coefficients in thin charged membranes. We investigate a variety of different pore geometries together with different surface charges on particles. Here, we show that independent of the charges on particles, a (generalized) tortuosity factor can be identified as function of the pore morphology only using the new PNP model. On the other hand, all electro-static interactions of ions and charges on particles can consistently be captured by the ratio of average concentration to effective intrinsic concentration in the macroscopic PNP equations. Using this formulation allows to consistently take into account electrochemical interactions of ions and charges on particles and so excludes any ambiguity generally encountered in phenomenological equations.     

扩散法——EA-IRMS测定天然水体铵态氮同位素实验条件研究

稳定氮同位素是研究氮循环和氮污染源示踪的一个有效手段。然而目前国内对水体中铵态氮同位素测定方法研究较少,限制了水体氮循环和污染机理的深入探讨。本文采用改进的扩散法(EA-IRMS)测定水中铵态氮同位素,探讨了样品制备过程中扩散溶液的体积、浓度和扩散时间对回收率及氮同位素测定值的影响。实验得出最佳扩散条件为:1.50 mg/L氯化铵溶液400 mL扩散14天,回收率大于95%,且不会产生氮同位素分馏。本研究为高精度测定天然水体中铵态氮同位素提供了更可靠的实验条件。