微机电化学仪器的误差处理软件设计

根据WJH多功能电位分析仪,讨论在电化学分析仪器中误差分析与处理方法,利用计算机软件进行误差处理,该系统设计了10种误差处理方法.     

Fluid regime of the amphibolite-facies metamorphism in the Dzhugdzhur-Stanovoy fold area (Far East)

Chromatographic and electrochemical measurements, combined with computer simulation of the natural mineral parageneses and estimation of the stability field of muscovite-bearing assemblages, yielded a consistent model of the fluid regime for the amphibolite-facies metamorphism of the Dzhugdzhur-Stanovoy fold area (DSFA). The model allows the fluid differentiation into “internal” and “external” fluids. The “internal” fluid is formed by the volatiles of the rock, while the “external” fluid arrived from an outer source: the mantle or other reservoir. It is established that the chromatographic and electrochemical measurements refer to the “external” fluid, whereas the redox state estimated from the mineral equilibria is related to the “internal” fluid, whose composition is buffered by the equilibrium mineral assemblage. The “external” fluid trapped by rocks preserves its own redox state only at the regtrograde stage, when the solid-phase reactions slacken and the buffer role of the mineral assemblages is minimized. This aspect explains the contradiction between the wide variations in the oxidation state of the mineral equilibria (log fO₂ from ?15 to ?20), on the one hand, and the persistent oxidation state of the external fluid established by the chromatographic and electrochemical methods, on the other hand. The main reason for the wide development of hornblende-bearing assemblages in the amphibolite-facies metamorphic rocks of the Dzhugdzhur-Stanovoy fold system is the high H₂O pressure in the “external” fluid. According to the obtained data, the composition of the “external” fluid is determined by the conditions $ P_{H_2 O} Chromatographic and electrochemical measurements, combined with computer simulation of the natural mineral parageneses and estimation of the stability field of muscovite-bearing assemblages, yielded a consistent model of the fluid regime for the amphibolite-facies metamorphism of the Dzhugdzhur-Stanovoy fold area (DSFA). The model allows the fluid differentiation into “internal” and “external” fluids. The “internal” fluid is formed by the volatiles of the rock, while the “external” fluid arrived from an outer source: the mantle or other reservoir. It is established that the chromatographic and electrochemical measurements refer to the “external” fluid, whereas the redox state estimated from the mineral equilibria is related to the “internal” fluid, whose composition is buffered by the equilibrium mineral assemblage. The “external” fluid trapped by rocks preserves its own redox state only at the regtrograde stage, when the solid-phase reactions slacken and the buffer role of the mineral assemblages is minimized. This aspect explains the contradiction between the wide variations in the oxidation state of the mineral equilibria (log fO₂ from −15 to −20), on the one hand, and the persistent oxidation state of the external fluid established by the chromatographic and electrochemical methods, on the other hand. The main reason for the wide development of hornblende-bearing assemblages in the amphibolite-facies metamorphic rocks of the Dzhugdzhur-Stanovoy fold system is the high H₂O pressure in the “external” fluid. According to the obtained data, the composition of the “external” fluid is determined by the conditions ≥ 0.7 P_S and = 0.01–0.3. The oxidation potential of the “external” fluid is close to that of the H₂O-C system under carbon-saturated vapor conditions. Original Russian Text ? O.V. Avchenko, I.A. Aleksandrov, V.O. Khudolozhkin, M.A. Mishkin, 2009, published in Tikhookeanskaya Geologiya, 2009, Vol. 28, No. 4, pp. 3–15.     

电化学导流法提高原油采收率试验研究

电化学导流提高原油采收率技术,在油田各个开发阶段都可达到增油降水的效果.目前多数主力油层内部剩余油分布零散,注水效果差,新增储量的油层大多数是渗透率低、物性差的薄油层.现场试验证明,应用电动法这一新技术,已初步实现了增加原油渗流速度、提高油水流动的相对渗透率和解除油层堵塞等的效果,工艺上是可行的.且用导线传输直流电场与其它传输方式相比,对井口及地面通电设备的安全性也较好.     

自制电化学净水器净化饮用水中氟化物

根据法拉第电解定律，利用电化学原理自制了净水器，并进行了工作参数的选择，净水器的电生铝离子用来沉淀和分离水中超标的氟离子，以此除去高氟水中的氟化物，得到符合卫生标准的生活饮用水。应用该装置对9．0mg／L的高氟水进行处理，可以达到1．0mg／L的饮用水。