引入非线性瞬时弹性模量的软土流变模型

软土是一种非线性流变物质,但现行流变模型却忽略了加载瞬时的非线性变形;软土流变试验参数是数学模型参数而非物理模型参数,一个土样一般只对应一种材料参数,但现行流变模型的模型参数常随着荷载变化,且变化无规律,离散性大。基于以有机质为流变相物质的人工土试样室内一维压缩蠕变试验,建立了各级荷载作用下具有相同模型参数的7组件流变模型,用非线性弹簧H描述软土加载瞬时弹塑性变形、并联的三元件组件模拟软土随时间变化的黏弹塑变形。结果表明：引入三次非线性瞬时弹性模量的7组件流变模型能够较准确地反映软土的流变特性。     

酸雨观测异常数据的试验分析和处理方法

本文就酸雨观测仪器在测量操作中出现的异常状态进行了试验和分析,且对校错电极常数、测温系统故障、"后测K值"3种异常状态, 结合酸雨观测业务实践进行了试验、分析和讨论。推导出校错电极常数的电导率订正公式;制定了仪器测温系统故障的应急观测方案;指出"后测K值"会导致数据严重失真, 测量中必须严格遵循 "先测K值"规程;并建议在《酸雨观测业务规范》修订时, 增加本文有关的分析和处理方法。     

Brittleness index predictions from Lower Barnett Shale well-log data applying an optimized data matching algorithm at various sampling densities

The capability of accurately predicting mineralogical brittleness index(BI)from basic suites of well logs is desir-able as it provides a useful indicator of the fracability of tight formations.Measuring mineralogical components in rocks is expensive and time consuming.However,the basic well log curves are not well correlated with BI so correlation-based,machine-learning methods are not able to derive highly accurate BI predictions using such data.A correlation-free,optimized data-matching algorithm is configured to predict BI on a supervised basis from well log and core data available from two published wells in the Lower Barnett Shale Formation(Texas).This transparent open box(TOB)algorithm matches data records by calculating the sum of squared errors be-tween their variables and selecting the best matches as those with the minimum squared errors.It then applies optimizers to adjust weights applied to individual variable errors to minimize the root mean square error(RMSE)between calculated and predicted(BI).The prediction accuracy achieved by TOB using just five well logs(Gr,pb,Ns,Rs,Dt)to predict BI is dependent on the density of data records sampled.At a sampling density of about one sample per 0.5 ft BI is predicted with RMSE～0.056 and R2～0.790.At a sampling density of about one sample per 0.1 ft BI is predicted with RMSE～0.008 and R2～0.995.Adding a stratigraphic height index as an additional(sixth)input variable method improves BI prediction accuracy to RMSE～0.003 and R2～0.999 for the two wells with only 1 record in 10,000 yielding a BI prediction error of＞±0.1.The model has the potential to be applied in an unsupervised basis to predict BI from basic well log data in surrounding wells lacking mineralogical measure-ments but with similar lithofacies and burial histories.The method could also be extended to predict elastic rock properties in and seismic attributes from wells and seismic data to improve the precision of brittleness index and fracability mapping spatially.     

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).     

Cu3 N弹性和热力学性质的第一性原理研究

利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO₃结构Cu₃N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu₃N的弹性常数,Poisson比等,并分析出Cu₃N在零温零压下是稳定的. 通过准谐Debye模型计算Cu₃N的热力学性质,得到了Cu₃N的晶格常数、等压比热容、等容比热     

Investigation of insulation layer dynamic characteristics for high-speed railway

Dynamic performance of insulation is one of the key parameters during the insulation application for high-speed railway subgrade. This paper conducted laboratory and field tests for the materials and dynamic load,especially for thermal performance, elastic deformation, and accumulated deformation of insulation materials.Experiment results show that mechanical properties of insulation layer structure are stable, which satisfies the requirements of the high speed railway.     

Generalized Born scattering of elastic waves in 3-D media

It is well known that when a seismic wave propagates through an elastic medium with gradients in the parameters which describe it (e.g. slowness and density), energy is scattered from the incident wave generating low-frequency partial reflections. Many approximate solutions to the wave equation, e.g. geometrical ray theory (GRT), Maslov theory and Gaussian beams, do not model these signals. The problem of describing partial reflections in 1-D media has been extensively studied in the seismic literature and considerable progress has been made using iterative techniques based on WKBJ, Airy or Langer type ansätze. In this paper we derive a first-order scattering formalism to describe partial reflections in 3-D media. The correction term describing the scattered energy is developed as a volume integral over terms dependent upon the first spatial derivatives (gradients) of the parameters describing the medium and the solution. The relationship we derive could, in principle, be used as the basis for an iterative scheme but the computational expense, particularly for elastic media, will usually prohibit this approach. The result we obtain is closely related to the usual Born approximation, but differs in that the scattering term is not derived from a perturbation to a background model, but rather from the error in an approximate Green's function. We examine analytically the relationship between the results produced by the new formalism and the usual Born approximation for a medium which has no long-wavelength heterogeneities. We show that in such a case the two methods agree approximately as expected, but that in a media with heterogeneities of all wavelengths the new gradient scattering formalism is superior. We establish analytically the connection between the formalism developed here and the iterative approach based on the WKBJ solution which has been used previously in 1-D media. Numerical examples are shown to illustrate the examples discussed.