极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

利用地下水预报河南登封4.7级地震的资料分析过程

通过对１９９２年河南登封４．７级地震的资料分析，表明拐河老井地下水位变化是区域应力场的变化效应。在时间上有连续性，在空间上和构造体系上有一定的相关性     

四川盆地碳酸盐岩油气勘探实践与认识

四川盆地烃源十分丰富。但油气演化程度高,大多已进入高成熟和过成熟阶段,至今只在侏罗系发现有油藏,三叠系及其更老地层皆为气藏。储层主要为碳酸盐岩,其特点是低孔低渗,平均孔隙度仅1.7%,平均渗透率小于1×10~(-3)μm~2,但其中的“孔洞发育层段”平均孔隙度可达3%～6%。根据四十年的勘探经验,加强预探并争取新发现是四川盆地油气勘探发展的关键。预探中,按构造带规划大中型气田勘探目标,将成藏条件相似、地域上相邻的局部圈闭群作为一个整体勘探对象,实行稀井广探,少井高效。“八五”以来,在高陡构造带勘探技术、储层横向预探技术等方面有长足的进步,勘探成效不断提高,实现了资源序列的良性循环。     

邯郸市西部岩溶地下水的利用与开发

根据区域内岩溶地下水供需水现状，特别是通过对岩溶地下水最新开采动态资料分析，认为邯郸市西部岩溶水区尚具有一定的开发潜力，并提出了解决岩溶山区(革命老区)人畜用水的可行性和拦蓄滞洪、人工补给的有效途径，为地方经济持续发展提供决策依据，也可为北方类似岩溶地区所借鉴。     

Experimental research on reservoir sensitivity to stress and impacts on productivity in Kela 2 Gas Field

Kela 2 Gas Field, with high formation pressure (74.35MPa), high pressure coefficient (2.022) and difficulty of potential test and evaluation, is the largest integrated proved dry gas reservoir in China so far and the principal source for West-East Gas Development Project. In order to correctly evaluate the elastic-plastic deformation of rocks caused by the pressure decline during production, some researches, as the experiment on reservoir sensitivity to stress of gas filed with abnormal high pressure, are made. By testing the rock mechanic properties, porosities and permeabilities at different temperature and pressure of 342 core samples from 5 wells in this area, the variations of petro-physical properties at changing pressure are analyzed, and the applicable inspection relationship is concluded. The average productivity curve with the reservoir sensitivity to stress is plotted on the basis of the research, integrated with the field-wide productivity equation. The knowledge lays a foundation for the gas well productivity evaluation in the field and the gas field development plan, and provides effective techniques and measures for basic research on the development of similar gas fields.     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

GPS水汽遥感中的大气干延迟局地订正模型研究

在GPS遥感水汽过程中,大气干延迟模型的精度直接影响水汽遥感的精度。根据广东清远站1995～2001年的气象探空资料,计算了GPS水汽测量中的实际大气干延迟。在此资料基础上,利用地面气象要素建立了大气干延迟的年和分月局地订正模型。分析结果表明,年模型的精度优于目前广泛使用的普适模型;月模型与年模型相比,效果不是很明显,建立局地分月订正模型意义不大;在对高度角的敏感程度上,局地模型略大些;当高度角小于75时,大气干延迟弯曲路径与直线路径之差ΔS随天顶角增大而迅速增大。     

沸石在水环境治理中的应用现状与前景

文章叙述了沸石的基本结构以及吸附、离子交换特性，总结了近年来国内外有关沸石在水环境保护方面的研究与应用成果，提出了沸石在今后的水环境保护和改善方面将具有广泛的应用前景。     

冬小麦遥感冠层温度监测土壤含水量的试验研究

在冬小麦主要生育期(2002年4月初到5月底),对不灌溉的冬小麦测定了冠层温度、地温、气温以及土壤含水量,计算了冠气温差且分析了冠层温度和冠气温差与不同土层厚度的土壤含水量相关关系。结果表明:14:00的冠层温度能较好地反映20cm土层的土壤含水量变化,但与其它各土层相关性有较大的波动性;14:00的冠气温差能较好地反映40cm以上土层的土壤含水量变化,二者的相关性很高,在20cm、40cm土层,两者相关系数R2分别为0.98866、0.99389,这为用区域遥感数据反演主要生育期冬小麦的冠气温差进而监测区域40cm土壤含水量提供了实验性的依据;拔节期和灌浆期,用14:00冠气温差来拟合各土壤层的土壤含水量有较高的精度,从而为用区域遥感数据监测区域土壤含水量提供了经验性的模型。     

夏季红枫湖地区农田土壤-大气界面汞交换通量的初步研究

采用动力学通量箱法(Dynamic Flux Chamber)与高时间分辨率大气测汞仪联用技术对贵州红枫湖地区土壤-大气界面间汞交换通量进行了初步研究.结果显示,红枫湖地区土壤-大气界面间汞交换通量变化范围为-8.6 ng～215.3 ng@m-2@h-1,平均27.4士40.1 ng/m2@h(n=255);且土壤与大气界面间的汞交换是双向的既有土壤汞的释放,又有大气汞的沉降,主要以土壤汞的释放为主(n释放=253,n沉降=2n).土壤汞的释放通量与土壤温度、气温、光照强度有强相关关系,相关系数分别为0.80、0.83、0.74.