High-pressure eclogites in northern Jiangsu – southern Shandong province, eastern China

Abstract Eclogites are distributed for more than 500 km along a major tectonic boundary between the Sino-Korean and Yangtze cratons in central and eastern China. These eclogites usually have high-P assemblages including omphacite + kyanite and/or coesite (or its pseudomorph), and form a high-P eclogite terrane. They occur as isolated lenses or blocks 10 cm to 300 m long in gneisses (Type I), serpentinized garnet peridotites (Type II) and marbles (Type III). Type I eclogites were formed by prograde metamorphism, and their primary metamorphic mineral assemblage consists mainly of garnet [pyrope (Prp) = 15–40 mol%], omphacite [jadeite (Jd) = 34–64 mol%], pargasitic amphibole, kyanite, phengitic muscovite, zoisite, an SiO₂ phase, apatite, rutile and zircon. Type II eclogites characteristically contain no SiO₂ phase, and are divided into prograde eclogites and mantle-derived eclogites. The prograde eclogites of Type II are petrographically similar to Type I eclogites. The mantle-derived eclogites have high MgO/(FeO + Fe₂O₃) and Cr₂O₃ compositions in bulk rock and minerals, and consist mainly of pyrope-rich garnet (Prp = 48–60 mol%), sodic augite (Jd = 10–27 mol%) and rutile. Type III eclogites have an unusual mineral assemblage of grossular-rich (Grs = 57 mol%) garnet + omphacite (Jd = 30–34 mol%) + pargasite + rutile. Pargasitic and taramitic amphiboles, calcic plagioclase (An₆₈), epidote, zoisite, K-feldspar and paragonite occur as inclusions in garnet and omphacite in the prograde eclogites. This suggests that the prograde eclogites were formed by recrystallization of epidote amphibolite and/or amphibolite facies rocks with near-isothermal compression reflecting crustal thickening during continent–continent collision of late Proterozoic age. Equilibrium conditions of the prograde eclogites range from P > 26 kbar and T= 500–750°C in the western part to P > 28 kbar and T= 810–880°C in the eastern part of the high-P eclogite terrane. The prograde eclogites in the eastern part are considered to have been derived from a deeper position than those in the western part. Subsequent reactions, manifested by (1) narrow rims of sodic plagioclase or paragonite on kyanite and (2) symplectites between omphacite and quartz are interpreted as an effect of near-isothermal decompression during the retrograde stage. The conditions at which symplectites re-equilibrated tend to increase from west (P < 10 kbar and T < 580°C) to east (P > 9 kbar and T > 680°C). Equilibrium temperatures of Type II mantle-derived eclogites and Type III eclogite are 730–750°C and 680°C, respectively.     

Pan-African eclogite facies metamorphism of ultramafic rocks in the Shackleton Range, Antarctica

In the Shackleton Range of East Antarctica, garnet-bearing ultramafic rocks occur as lenses in supracrustal high-grade gneisses. In the presence of olivine, garnet is an unmistakable indicator of eclogite facies metamorphic conditions. The eclogite facies assemblages are only present in ultramafic rocks, particularly in pyroxenites, whereas other lithologies – including metabasites – lack such assemblages. We conclude that under high-temperature conditions, pyroxenites preserve high-pressure assemblages better than isofacial metabasites, provided the pressure is high enough to stabilize garnet–olivine assemblages (i.e. ≥18–20 kbar). The Shackleton Range ultramafic rocks experienced a clockwise P–T path and peak conditions of 800–850 °C and 23–25 kbar. These conditions correspond to ∼70 km depth of burial and a metamorphic gradient of 11–12 °C km⁻¹ that is typical of a convergent plate-margin setting. The age of metamorphism is defined by two garnet–whole-rock Sm–Nd isochrons that give ages of 525 ± 5 and 520 ± 14 Ma corresponding to the time of the Pan-African orogeny. These results are evidence of a Pan-African suture zone within the northern Shackleton Range. This suture marks the site of a palaeo-subduction zone that likely continues to the Herbert Mountains, where ophiolitic rocks of Neoproterozoic age testify to an ocean basin that was closed during Pan-African collision. The garnet-bearing ultramafic rocks in the Shackleton Range are the first known example of eclogite facies metamorphism in Antarctica that is related to the collision of East and West Gondwana and the first example of Pan-African eclogite facies ultramafic rocks worldwide. Eclogites in the Lanterman Range of the Transantarctic Mountains formed during subduction of the palaeo-Pacific beneath the East Antarctic craton.     

Trace Element Partitioning and Accessory Phase Saturation during H2O-Saturated Melting of Basalt with Implications for Subduction Zone Chemical Fluxes

Experimental phase equilibrium and trace element partitioningdata are reported for H₂O-saturated mid-ocean ridge basalt at2·5 GPa, 750–900°C and oxygen fugacities atthe nickel–nickel oxide buffer. Garnet, omphacite andrutile are present at all temperatures. Amphibole and epidotedisappear as residual phases above 800°C; allanite appearsabove 750°C. The Na–Al-rich silicate glass presentin all run products is likely to have quenched from a supercriticalliquid. Trace element analyses of glasses demonstrate the importantcontrol exerted by residual minerals on liquid chemistry. Inaddition to garnet, which controls heavy rare earth elements(HREE) and Sc, and rutile, which controls Ti, Nb and Ta, allanitebuffers the light REE (LREE; La–Sm) contents of liquidsto relatively low levels and preferentially holds back Th relativeto U. In agreement with previous experimental and metamorphicstudies we propose that residual allanite plays a key role inselectively retaining trace elements in the slab during subduction.Experimental data and analyses of allanite-bearing volcanicrocks are used to derive a model for allanite solubility inliquids as a function of pressure, temperature, anhydrous liquidcomposition and LREE content. The large temperature dependenceof allanite solubility is very similar to that previously determinedfor monazite. Our model, fitted to 48 datapoints, retrievesLREE solubility (in ppm) to within a factor of 1· 40over a pressure range of 0–4 GPa, temperature range of700–1200°C and for liquids with anhydrous SiO₂ contentsof 50–84 wt %. This uncertainty in LREE content is equivalentto a temperature uncertainty of only ± 27°C at 1000K, indicating the potential of allanite as a geothermometer.Silicic liquids from either basaltic or sedimentary protolithswill be saturated in allanite except for Ca-poor protolithsor at very high temperatures. For conventional subduction geothermsthe low solubility of LREE (+ Th) in liquids raises questionsabout the mechanism of LREE + Th transport from slab to wedge.It is suggested either that, locally, temperatures experiencedby the slab are high enough to eliminate allanite in the residueor that substantial volumes of H₂O-rich fluids must pass throughthe mantle wedge prior to melting. The solubility of accessoryphases in fluids derived from subducted rocks can provide importantconstraints on subduction zone thermal structure. KEY WORDS: subduction; experimental petrology; allanite; solubility; supercritical liquid; eclogite     

Phase Relations and Melting of Anhydrous K-bearing Eclogite from 1200 to 1600{degrees}C and 3 to 5 GPa

To investigate eclogite melting under mantle conditions, wehave performed a series of piston-cylinder experiments usinga homogeneous synthetic starting material (GA2) that is representativeof altered mid-ocean ridge basalt. Experiments were conductedat pressures of 3·0, 4·0 and 5·0 GPa andover a temperature range of 1200–1600°C. The subsolidusmineralogy of GA2 consists of garnet and clinopyroxene withminor quartz–coesite, rutile and feldspar. Solidus temperaturesare located at 1230°C at 3·0 GPa and 1300°C at5·0 GPa, giving a steep solidus slope of 30–40°C/GPa.Melting intervals are in excess of 200°C and increase withpressure up to 5·0 GPa. At 3·0 GPa feldspar, rutileand quartz are residual phases up to 40°C above the solidus,whereas at higher pressures feldspar and rutile are rapidlymelted out above the solidus. Garnet and clinopyroxene are theonly residual phases once melt fractions exceed 20% and garnetis the sole liquidus phase over the investigated pressure range.With increasing melt fraction garnet and clinopyroxene becomeprogressively more Mg-rich, whereas coexisting melts vary fromK-rich dacites at low degrees of melting to basaltic andesitesat high melt fractions. Increasing pressure tends to increasethe jadeite and Ca-eskolaite components in clinopyroxene andenhance the modal proportion of garnet at low melt fractions,which effects a marked reduction in the Al₂O₃ and Na₂O contentof the melt with pressure. In contrast, the TiO₂ and K₂O contentsof the low-degree melts increase with increasing pressure; thusNa₂O and K₂O behave in a contrasted manner as a function ofpressure. Altered oceanic basalt is an important component ofcrust returned to the mantle via plate subduction, so GA2 maybe representative of one of many different mafic lithologiespresent in the upper mantle. During upwelling of heterogeneousmantle domains, these mafic rock-types may undergo extensivemelting at great depths, because of their low solidus temperaturescompared with mantle peridotite. Melt batches may be highlyvariable in composition depending on the composition and degreeof melting of the source, the depth of melting, and the degreeof magma mixing. Some of the eclogite-derived melts may alsoreact with and refertilize surrounding peridotite, which itselfmay partially melt with further upwelling. Such complex magma-genesisconditions may partly explain the wide spectrum of primitivemagma compositions found within oceanic basalt suites. KEY WORDS: eclogite; experimental petrology; mafic magmatism; mantle melting; oceanic basalts     

鲁苏榴辉岩套的特征及其动力学演化

鲁苏榴辉岩套以广泛分布各类榴辉岩、密切伴生石榴石橄榄岩、石榴石麻粒岩等高压岩石组合 ,普遍发育韧性变形带 ,大量出露燕山晚期碱性花岗岩及深源脉岩为特征。它已经历三迭纪早期华南陆块与华北陆块的碰撞事件、大陆逆掩推覆构造事件及后期白垩纪早期开始的大陆伸展构造事件 ,是我国华南陆块与华北陆块之间的重要过渡单元。     

大别山双河超高压变质岩的稳定同位素研究

大别山双河地区片麻岩的δ18O值与共生榴辉岩同步变化，为（-4.7—+10.3）‰，这些片麻岩的18O亏损与榴辉岩一样是在遭受超高压变质作用之前原岩与大气降水交换的结果。榴辉岩及其围岩片麻岩在板块俯冲、超高压变质和岩片折返过程中可能为一个构造上的整体，两者为“原地”接触关系。     

Timing and exhumation of eclogite facies shear zones, Musgrave Block, central Australia

Timing constraints on shear zones can provide an insight into the kinematic and exhumation evolution of metamorphic belts. In the Musgrave Block, central Australia, granulite facies gneisses have been affected, to varying degrees, by mylonitic deformation, some of which attained eclogite facies. The Davenport Shear Zone is a dominant strike-slip system that formed at eclogite facies conditions ( T  ≈650  °C and P ≈12.0  kbar). Sm–Nd mineral isochrons obtained from equilibrated high-pressure assemblages, as well as ⁴⁰Ar–³⁹Ar data, show that the eclogite and greenschist facies high-strain overprints were coeval, at c .  550  Ma. Mylonitic processes do not appear to have reset the U–Pb system in zircon, but may have partially disturbed it. The thermal gradient in the Musgrave Block crust at c .  550  Ma was c .  16  °C  km⁻¹ and at c .  535  Ma was c .  18  °C  km⁻¹, based on P – T  estimates of eclogite and greenschist facies shear zones, respectively. These estimates are similar to present-day geothermal gradients in many stable continental shield areas, suggesting that the region did not undergo a significant transient perturbation of the geotherm. Therefore, in the Musgrave Block, cooling subsequent to eclogite facies metamorphism appears to have been controlled by exhumation, rather than by the removal of a heat source. Estimated exhumation rates in the range 0.2 to ≥1.5  mm year⁻¹ are comparable with other orogenic belts, rather than cratonic areas elsewhere.     

榴辉岩中铁铝榴石的测定方法研究

对国内主要矿区铁铝石榴子石纯矿物中铁的价态规律进行了研究。证明其所含Ｆｅ均以Ｆｅ＾２＋为主，其质量分数在８３－９４，并将Ｆｅ＾２＋这特征性成分用于某地榴辉岩中铁铝榴石的间接测定，获得结果与焙烧磁化－磁选法一致且精度好，较磁化法简便，快速。     

辽宁榴辉岩包体的石榴石中金云母出溶片晶的发现

在辽宁复县50号金伯利岩岩筒中,发现了罕见的榴辉岩包体,在该包体的主要组成矿物石榴石中发现了金云母出溶片晶。通过显微镜、透射电镜及其能谱观察分析测定与研究,确认该片晶为金云母。金云母无色,断面呈针状,一般宽0.5—5μm,长10—100μm;但宽0.05—0.1μm,长1—2μm的细小片晶也较发育。金云母片晶沿石榴石[111]晶带大致呈夹角为60°—70°的三组定向排列,表明它是由于榴辉岩从地幔深处上升到较浅部时释压作用从石榴石中出溶的产物。世界各地金伯利岩中榴辉岩包体的石榴石、辉石中微小针状出溶矿物(或包裹体)普遍存在,据文献报道,已经鉴定的出溶物有辉石和金红石。迄今为止,金云母出溶片晶的发现尚属首次。     

豫南中温榴辉岩中角闪石的变质演化

在该区中温榴辉岩的各个演化阶段中，出现了不同成分的角闪石。石榴石环带及其核部的闪石等矿物包囊体记录了前榴辉阶段及其进变质演化的特征。在榴岩阶段晚期，蓝闪石稳定出现，其成分环带反映了压力降低的连续过程；角闪石－斜长石后成合晶为石榴石和绿辉石的退变质产物；退变质后期，钙质闪石大量出现。角闪石的矿物组合及其成分变化，反映了中温榴辉岩的顺时针变质演化过程。