延庆千家店地区硅化木赋存层位及形成时代分析

北京延庆千家店土城子组中的硅化木自发现以来,得到了众多学者的关注,但关于硅化木的赋存层位和形成时代一直未有定论,目前主流观点认为硅化木广泛发育于土城子组一段和二段的下部,关于其形成时代则自侏罗纪早期至白垩纪早期的论述均有,这种争论显然不利于木化石的保护、科普和进一步深化认识。在千家店土城子组进行的考察结果展现出与前人观点不同的线索。实地考察、剖面测量和年龄测试结果显示:原位埋藏硅化木形成时代应为晚侏罗世早期,赋存层位为土城子组一段下部,而土城子组二段下部的沉积特征反应出当时水位频繁升降,水体能量剧烈变化,火山活动暂时陷入沉寂的沉积环境,较难满足形成木化石的基本要求。     

北极秋季海冰密集度与中国初冬降雨之间的关系

本文通过对中国地区实测降水及北极海冰卫星数据的分析,研究了北极秋季海冰密集度与中国初冬降雨的关系。合成分析的研究结果表明2000年之前中国南方和北方冬季降水偏少,中部降水偏多,这之后中国南方和北方冬季降水增加,中部降水减少。SVD研究结果显示,北极海冰减少使得近三十年来中国南方和北方冬季降雨呈现逐渐增多,中部地区(从青藏高原向东北方向至日本)降雨逐步减少的趋势。随着北极海冰的进一步减少,如遇合适的气候条件,南方冻雨出现的概率会加大。北极秋季海冰异常的回复过程加之冬季海冰异常的延续信号在中国、蒙古及日本北部激发一个阻塞高压,以巴伦支海/卡拉海为中心激发一个异常低压。这使得来自北冰洋大西洋扇区的冷空气南下至欧洲大陆和亚洲北部,在阻塞高压的影响下,冷空气进一步南下,进入东亚地区。这不仅使得亚洲冬季温度降低,也为中国北部降水增加提供条件。     

Origin of the Breno and Esino dolomites in the western Southern Alps (Italy): Implications for a volcanic influence

The Esino Limestone of the western Southern Alps represents a differentiated Ladinian-Lower Carnian (?) carbonate platform comprised of margin, slope and peritidal inner platform facies up to 1000 m thick. A major regional subaerial exposure event lead to coverage by another peritidal Lower Carnian carbonate platform (Breno Formation). Multiphase dolomitization affected the carbonate sediments. Petrographic examinations identified at least three main generations of dolomites (D1, D2, and D3) that occur as both replacement and fracture-filling cements. These phases have crystal-size ranges of 3–35 μm (dolomicrite D1), 40–600 μm (eu-to subhedral crystals D2), and 200 μm to 5 mm (cavity- and fracture-filling anhedral to subhedral saddle dolomite D3), respectively.The fabric retentive near-micritic grain size coupled with low mean Sr concentration (76 ± 37 ppm) and estimated δ¹⁸O of the parent dolomitizing fluids of D1 suggest formation in shallow burial setting at temperature ∼ 45–50 °C with possible contributions from volcanic-related fluids (basinal fluids circulated in volcaniclastics or related to volcanic activity), which is consistent with its abnormally high Fe (4438 ± 4393 ppm) and Mn (1219 ± 1418 ppm) contents. The larger crystal sizes, homogenization temperatures (D2, 108 ± 9 °C; D3, 111 ± 14 °C) of primary two-phase fluid inclusions, and calculated salinity estimates (D2, 23 ± 2 eq wt% NaCl; D3, 20 ± 4 eq wt% NaCl) of D2 and D3 suggest that they formed at later stages under mid-to deeper burial settings at higher temperatures from dolomitizing fluids of higher salinity, which is supported by higher estimated δ¹⁸O values of their parent dolomitizing fluids. This is also consistent with their high Fe (4462 ± 4888 ppm; and 1091 ± 1183 ppm, respectively) and Mn (556 ± 289 ppm and 1091 ± 1183 ppm) contents, and low Sr concentrations (53 ± 31 ppm and 57 ± 24 ppm, respectively).The similarity in shale-normalized (SN) REE patterns and Ce (Ce/Ce*)_SN and La (Pr/Pr*)_SN anomalies of the investigated carbonates support the genetic relationship between the dolomite generations and their calcite precursor. Positive Eu anomalies, coupled with fluid-inclusion gas ratios (N₂/Ar, CO₂/CH₄, Ar/He), high F⁻ concentration, high F/Cl and high Cl/Br molar ratios suggest an origin from diagenetic fluids circulated through volcanic rocks, which is consistent with the co-occurrence of volcaniclastic lenses in the investigated sequence.     

Controls on reservoir heterogeneity of tight sand oil reservoirs in Upper Triassic Yanchang Formation in Longdong Area,southwest Ordos Basin,China: Implications for reservoir quality prediction and oil accumulation

Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively.     

Impact of early dolomitization on multi-scale petrophysical heterogeneities and fracture intensity of low-porosity platform carbonates (Albian-Cenomanian,southern Apennines,Italy)

Petrographic, petrophysical and fracture analyses were carried out on middle Cretaceous platform carbonates of the southern Apennines (Italy) that represent an outcrop analogue of the Val d’Agri and Tempa Rossa reservoirs of the Basilicata region. The studied outcrops, which are made of interlayered limestones and dolomites of inner platform environment, were selected to study the impact of dolomitization on reservoir properties and the control of dolomite texture on fracture development. Two types of dolomites – both formed during very early diagenesis – were found interlayered, at a metre scale, with micrite-rich limestones (mainly mudstones and wackestones). Dolomite A is fine-to medium crystalline and makes non-planar mosaics. Dolomite B is coarse-crystalline and makes planar-s and planar-e mosaics. The intercrystalline space of the planar-e subtype of dolomite B is either open or filled by un-replaced micrite or by late calcite or saddle dolomite cement. Dolomite A and dolomite B have similar average porosities of 3.7 and 3.1% respectively, which are significantly higher than the average porosity of limestones (1.4%). Their poro-perm relationships are similar, with the notable exception of planar-e type B dolomites, which generally display higher permeability values.The intensity of top bounded fractures is distinctly lower in coarse-crystalline dolomites than in fine-crystalline dolomites and limestones, both at the macro- and the micro-scale. On the other hand neither lithology (i.e. limestone vs. dolomite) nor dolomite crystal size control the intensity of perfect bed-bounded fractures, which is strictly controlled by the fracture layer thickness.Our results provide information that could be used as guidance for the characterization and modelling of fractured carbonate reservoirs made of interlayered limestones and dolomites.     

西藏塔惹增地区下白垩统捷嘎组的厘定及其地质意义

笔者于西藏仲巴县塔惹增地区一带前人划分的一套早白垩世早期则弄群中发现了具有典型意义的、代表早白垩世晚期的Ampullina xainzaensis Yu,Ampullina cf. larteli Landerer,Tylostoma cf. brasilianus Maury,Pseudamaura cf. subfournaeti (Pcelincev),Gyrodes gaultiana Orbigny,Leviathania cf. gerassimovi(Pcelincev),Gymnentome cf. pizcuetana(Vilanova)等腹足类化石,以及较为丰富的中圆笠虫Mesorbitolina sp.和达克斯虫Daxia sp。表明在该区则弄群中至少有一部分以前没有被识别出的早白垩世晚期地层。通过岩石组合特征、基本层序、生物化石时代对比,将该套地层归属于捷嘎组。这一地层的确定为冈底斯带白垩系地层划分对比、地层格架建立提供了重要的依据,并丰富了该地层的古生物资料,且为中生代盆地的演化历史、古地理轮廓的确定提供了新的基础资料。     

Early Carboniferous ophiolite in central Qiangtang,northern Tibet: record of an oceanic back-arc system in the Palaeo-Tethys Ocean

Zircon U–Pb dating of two samples of metagabbro from the Riwanchaka ophiolite yielded early Carboniferous ages of 354.4 ± 2.3 Ma and 356.7 ± 1.9 Ma. Their positive zircon εHf(t) values (+7.9 to +9.9) indicate that these rocks were derived from a relatively depleted mantle. The metagabbros can be considered as two types: R1 and R2. Both types are tholeiitic, with depletion of high-field-strength elements (HFSE) and enrichment of large-ion lithophile elements (LILE) similar to those of typical back-arc basin basalts (BABB), such as Mariana BABB and East Scotia Ridge BABB. Geochemical and isotopic characteristics indicate that the R1 metagabbro originated from a back-arc basin spreading ridge with addition of slab-derived fluids, whereas the R2 metagabbro was derived from a back-arc basin mantle source, with involvement of melts and fluids from subducted ocean crust. The Riwanchaka ophiolite exhibits both mid-ocean ridge basalts- and arc-like geochemical affinities, consistent with coeval ophiolites from central Qiangtang. Observations indicate that the Qiangtang ophiolites developed during the Late Devonian–early Carboniferous (D₃–C₁) in a back-arc spreading ridge above an intra-oceanic subduction zone. Based on our data and previous studies, we propose that an oceanic back-arc basin system existed in the Longmuco–Shuanghu–Lancang Palaeo-Tethys Ocean during the D₃–C₁ period.     

Meteoric diagenesis and dedolomite fabrics in precursor primary dolomicrite in a mixed carbonate–evaporite system

Dedolomitization is a common diagenetic process in shallow burial environments and is often associated with sulphates in mixed carbonate‐evaporite successions. In these settings, elevated Ca²⁺/Mg²⁺ ratios necessary for dedolomitization result from the dissolution of sulphate phases by the incursion of undersaturated groundwater. Reported dedolomite textures from other studies are varied, but the most prevalent is a rhombic texture interpreted to result from the partial to complete pseudomorphic replacement of secondary dolomite rhombs formed in the burial diagenetic realm. In this study of primary cryptocrystalline to finely crystalline dolomicrites in the Prairie Evaporite Formation of north‐eastern Alberta, dedolomitization has resulted in sutured to loosely packed mosaics of dedolomite that range from subhedral to distinctly euhedral (rhombic) crystal fabrics; however, no prior aggrading neomorphism producing dolomite rhombs is evident in the precursor dolomicrites. Non‐pseudomorphic dedolomitization of the dolomicrites results in textures that include rhombic dedolomite crystals with cloudy cores comprising remnant dolomicrite and clear rims. These textures are similar to those observed in the pseudomorphic dedolomitization of secondary dolomite rhombs. The Prairie Evaporite Formation of north‐eastern Alberta has experienced extensive karstification near the erosional margin of the sedimentary succession. Dedolomitization of dolomicrites occurs in marker beds within the Prairie Evaporite succession associated with evaporite karstification. Along with stratigraphic and petrographic considerations, stable isotope results support the interpretation of a shallow dedolomitization event influenced by meteoric waters derived from the basin margin. Negative δ ¹⁸O and low δ ¹³C values (averages of −13·6‰_VPDB and 0·5‰_VPDB, respectively) of the dedolomite, compared with those of the primary dolomicrite (averages of −6·0‰_VPDB and 1·2‰_VPDB, respectively), point to isotopically light diagenetic fluids. These results show that rhombic dedolomite textures can form through shallow, non‐pseudomorphic dedolomitization of dolomicrites by meteoric fluids in the presence of sulphates, with resulting textures that are similar to the pseudomorphic dedolomitization of secondary dolomite rhombs.     

大兴安岭十八站—韩家园地区中酸性侵入岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义

大兴安岭北部塔河县十八站—呼玛县韩家园地区发育早古生代中酸性侵入岩。文章选取二长闪长岩和二长花岗岩开展岩石年代学与地球化学研究。二长闪长岩LA-ICP-MS锆石U-Pb年龄为512.4±3.5 Ma,为早—中寒武世岩浆作用的产物。岩石地球化学分析表明,中酸性侵入岩归属于准铝质—弱过铝质(A/CNK=0.77~1.04)钙碱性—高钾钙碱性系列。岩石稀土总量∑REE=69.51×10~(-6)~275.83×10~(-6),轻重稀土分异明显(La/Yb)_N=9.11~26.64。在稀土元素配分图上,显示为LREE富集、HREE相对平缓的右倾型,Eu异常不显著(δEu=0.90~1.35)。微量元素组成具明显富集大离子亲石元素Ba、Sr,显著亏损高场强元素Nb、Ta、Ti的特征。结合区域资料和本文研究,初步分析认为早古生代侵入体形成于活动大陆边缘或岛弧环境,为前古亚洲洋闭合背景下萨拉伊尔造山作用的产物。     

准中1区三工河组二段低孔渗储层特征及主控因素

通过岩芯观察、测井和录井资料、铸体薄片观察,研究准中1区三工河组二段储层特征及致密化因素。研究表明,储层砂体发育于水下分流河道、河口砂坝和远沙坝;储集岩以长石岩屑砂岩、岩屑砂岩为主;储集空间以次生溶孔为主,含少量原生孔隙,为孔缝型储层。储层受原生沉积相和后生成岩作用改造的双重控制。强烈的压实作用、钙质胶结是导致储层致密的主要因素,后期深埋溶蚀则是储层得以改造的关键控制因素。优质储层主要发育于水下分流河道,表现为粗粒、弱压实、弱钙质胶结、强溶蚀微观特征。