海水中一氧化氮的极谱法测定

本文首次采用 Nafion和 Co(salen) /Nafion修饰铂电极测定海水中的 NO,对实验条件进行了选择 ,确定了最佳实验条件 ,即反应池通氮除氧 30 min,富集时间为 4min。同时用线性扫描法对海水中的 NO进行测定 ,测得海水中 NO的浓度与氧化峰电流之间有一定线性关系。对 Nafion修饰电极而言 ,线性范围 1～ 76.9μmol/L,R2 =0 .991 6,检出限为 1 μmol/L。同时对 2种方法修饰的铂电极进行了比较 ,即当 NO浓度在 1 0 -6mol/L数量级时 2种电极基本上无差别 ,而在 1 0 -7mol/L数量级时 Co(salen) /Nafion修饰电极要明显优于 Nafion修饰电极     

塞曼石墨炉原子吸收法直接测定海水中的铜

本文选择酒石酸消除海水基体对铜信号的干扰,用塞曼石墨炉原子吸收法直接测定海水中的铜。从Cu的原子化曲线可知,加入酒石酸后,背景值减小,Cu原子吸收信号增强,且出现时间提前,表明酒石酸是有效的海水基体改进剂。用P.E.Z3030光谱仪测得双蒸水及海水中的元素Cu的特征质量(m。)分别为12.5pg及12.7pg;检测限分别为0.18μg/L和0.19μg/L,表明基体效应已消除,符合海洋监测要求。可用纯Cu标准溶液作校正曲线,以国家海洋局的两个标准海水样品中的Cu评定本法的准确度,相对偏差为0及-4.6%,与经典的经富集后的FAAS法的结果相比,相对偏差在3.0—6.5％范围内。用不同类型的光谱仪测定了30个海水样品,回收率在89—104％范围内。本法操作简便、快速。     

塞曼石墨炉原子吸收法直接测定海水中的铬

海水基体对Cr有增感作用。本文研究了抗坏血酸、柠檬酸三铵、酒石酸、乙酸铵等有机基体改进剂对消除基体干扰效果。前二者均有效地消除基体干扰,但1％抗坏血酸 1％柠檬酸三铵混合试剂的效果更好,它不仅可以消除基体干扰,还可降低背景及噪声,Cr的吸收峰也较平滑。本法准确,相对偏差在0.7—4.4％范围内。回收率在92—109％范围内。若海水Cr含量低于定量下限时,可采用多次进样法。     

光通信用IOGHzCMOS八分频器设计

在比较反转触发器（TFF）的各种结构基础上,采用一种单时钟信号控制,实现高速分频的电路结构,设计实现了用于光通信中时钟数据恢复电路的八分频器。该八分频器使用动态负载,输出两路互补信号,采用SMIC0．18um1P6MCMOS工艺,使用Cadence公司的Spectre仿真器进行模拟验证,实验结果证明,在电源电压为1．8V的情况下,该八分频器的工作速度10GHz、功耗仅为4．705mW。     

浙江渔场的渔业资源动态与监测

本文根据历史资料和１９９３年资源动态监资料，阐明了浙江渔场及邻近海域渔业资源的变化状况，重点叙述了鲐、Ｃｈａｎ鱼、虾类、头足类的资源开发利用动态，讨论了渔业资源动态监测工作，提出今后搞好资源监测工作的建议。     

海水钝顶螺旋藻富硒及其含硒藻蓝蛋白的研究

研究了亚硒酸钠梯度浓度对海水钝顶螺旋藻Spirulina platensis生长及藻胆蛋白含量的影响,对含硒藻蓝蛋白进行分离纯化,得到含硒藻蓝蛋白纯品。结果表明,硒添加浓度小于100mg.L-1时,对藻体生长有一定的促进作用,其生物量、藻蓝蛋白和别藻蓝蛋白含量有增加,藻体硒含量及富硒系数明显高于文献报道的相似条件下的淡水螺旋藻;纯化的含硒藻蓝蛋白溶液在弱光照、低温、pH4—8的范围内稳定性较好;含硒藻蓝蛋白的光谱特性与藻蓝蛋白相比几乎没有差异,紫外与可见光吸收光谱特征吸收峰在280nm和620nm,荧光激发峰在558nm,室温条件下最大荧光发射峰在655nm,说明海水钝顶螺旋藻富集硒后及海水的胁迫对其藻蓝蛋白的光谱特性没有明显影响。     

Pollution Condition of Petroleum Hydrocarbon Pollutant and Estimation of Its Environmental Capacities in Summer in the Bohai Sea

The zones around the Bohai Sea are the most developed area in north China [1]. With the development of economy and increasing of population, the marine environment quality has become worse and worse in Bohai Sea, especially in the coastal regions of Bohai Bay, Liaodong Bay and Laizhou Bay [1]. As reported, the petroleum hydrocarbon (PH) contamination in the Bohai Sea was mainly due to the discharge of oily wastewater from inland [1]. There were about 8 734 392.3 104 t water input in the …     

Drag Coefficient,Dynamic Roughness and Reference Wind Speed

Surface waves are the roughness element of the ocean surface. The parameterization of the drag coefficient of the ocean surface is simplified by referencing to wind speed at an elevation proportional to the characteristic wavelength. The dynamic roughness is analytically related to the drag coefficient. Under the assumption of fetch limited wave growth condition, various empirical functions of the dynamic roughness can be converted to equivalent expressions for comparison. For datasets covering a wide range of the dimensionless frequency (inverse wave age), it is important to account for the variable rate of wave development at different wave ages. As a result, the dependence of the Charnock parameter on wave age is nonmonotonic. Finally, the analysis presented here suggests that the significant wave steepness is a sensitive property of the ocean surface and a single variable normalization of the dynamic roughness using a wavelength or wave height parameter actually produces more robust functions than bi-variable normalizations using wave height and wave slope.     

Simulations of Annual Cycle of Phytoplankton Production and the Utilization of Nitrogen in the Yellow Sea

A nutrient dynamic model coupled with a 3D physical model has been developed to study the annual cycle of phytoplankton production in the Yellow Sea. The biological model involves interactions between inorganic nitrogen (nitrate and ammonium), phosphate and phytoplankton biomass. The model successfully reproduces the main features of phytoplankton-nutrient variation and dynamics of production. 1. The well-mixed coastal water is characterized by high primary production, as well as high new production. 2. In summer, the convergence of tidal front is an important hydrodynamic process, which contributes to high biomass at frontal areas. 3. The evolution of phytoplankton blooms and thermocline in the central region demonstrate that mixing is a dominant factor to the production in the Yellow Sea. In this simulation, nitrate- and ammonium-based productions are estimated regionally and temporally. The northern Yellow Sea is one of the highly ranked regions in the Yellow Sea for the capability of fixing carbon and nitrogen. The annual averaged f-ratio of 0.37 indicates that regenerated production prevails over the Yellow Sea. The result also shows that phosphate is the major nutrient, limiting phytoplankton growth throughout the year and it can be an indicator to predict the bloom magnitude. Finally, the relative roles of external nutrient sources have been evaluated, and benthic fluxes might play a significant role in compensating 54.6% of new nitrogen for new production consumption.     

The Effect of Internal Fluid on the Response of Vortex-Induced Vibration of Marine Risers

Based on Iwan‘s wake oseillator model developed with the classical van der Pol equalion, the differential equation for the response of the vortex-induced vihration (VIV) of the riser considering the effect of the internal flowing fluid and the external marine environmental condition is derived. The effect of the intermal flowing fluid on the response of VIV of the riser is studied by means of the Finite Element Method. The results show that the effect of the internal fluid velocity on the VIV of the riser is strong when the natural frequency of the riser is close to the vortex shedding frequency. In addition, the increase of the top tension can decrease the sensitivity of the riser to the internal fluid velocity.