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11.
为了回收大洋粘土制备白炭黑后残液中的Al3 ,并获得氧化铝超细粉体,实验选用NH3.H2O为沉淀剂,在常温下采用沉淀法使残液中Al3 以氢氧化铝形式沉淀并去除其它杂质离子,然后将得到的沉淀在1200℃灼烧,保温1h。利用IR和XRD测试了产物的物相组成和结构,证实实验可以获得纯度较高的α-Al2O3;而SEM和粒度分析结果显示产物粒度细小,部分颗粒可以达到纳米级;BET结果显示Al2O3的比表面积可达32m2/g。根据氧化铝结构和性能等优选的实验条件为大洋粘土的进一步开发利用提供了参考依据。 相似文献
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We studied the dissolved silica cycle in the water column of the North basin of Lake Lugano, Switzerland/Italy. Lake Lugano is a meromictic, eutrophic lake, permanently stratified below 100-m depth. A one-box model was used to calculate a silica mass-balance over 1993, based on various lake measurements, such as sediment traps, sediment cores, water analysis and biota countings. We found that the North basin of Lake Lugano is at steady state as far as dissolved silica is concerned. The primary source of dissolved silica in the lake is river input (about 80%), with diffusion from bottom sediments and groundwater input also playing a role. Atmospheric input is negligible. The main export of dissolved silica occurs via biogenic uptake by diatoms and final burial of their frustules in the bottom sediment. Loss of dissolved silica through the lake outflow only represents 15% of the total output. Of the total amount of Si exported to the lake bottom through diatom sinking, less than 20% is re-supplied to the surface water by diffusion. Thus, the lake acts as an important permanent sink for silica. The long residence time of dissolved silica in the lake (7 years) is related to the strong physical stratification of the lake. Only about 10% of the standing stock are available to phytoplankton uptake. 相似文献
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This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg–1 pH of 7.6 and p(CO2) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg–1, pH of 7.70 and p(CO2) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO2) up to 5.6 times the atmospheric P(CO2). 相似文献
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HU Ping YIN Xiulan ZHAO Linghu & LI Dien . Department of Earth Sciences China University of Geosciences Wuhan China . Northeastern Illinois University Chicago IL USA . China Institute of Geo-Environmental Monitoring Beijing China . Division of Chemistry Los Alamos National Laboratory Los Alamos NM USA 《中国科学D辑(英文版)》2005,48(11)
A large amount of nuclear wastes has been pro-duced due to nuclear weapon development and nuclear electricity generation. One possible resolution for the disposal of the nuclear wastes is to seal them in an underground repository, which requires detailed knowledge on the mobility, chemical behavior and immobilization of radionuclides in underground water. In addition, toxic heavy metals are extensively present in ground and underground water, how to immobilize and remedy these toxic heavy meta… 相似文献
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CAMILLA S. ANDRESEN SVANTE BJORCK 《Geografiska Annaler: Series A, Physical Geography》2005,87(1):159-174
ABSTRACT. Two well dated Holocene sediment records bordering the Denmark Strait region have been used to reconstruct past climate variability. The content of biogenic silica, classic and organic material and moss in a lacustrine record from Lake N14 has been used to infer past variability in precipitation and temperature in southern Greenland. Sedimentologic and petrologic composition of sand in a shelf sediment record from the Djúpáll trough is used to infer past variability in the northwestern storm activity on northwestern Iceland, which probably also affected the inflow of polar waters from the East Greenland Current. Our evaluation of these records with a number of previous studies from the region documents Holocene climatic optimum conditions peaking between 8000 and 6500 calendar years before present (cal yr BP). Mid-Holocene climate deterioration set in around 5000 cal yr BP followed by a further marked setback around 3500 cal yr BP. A stacking of climate variability on a centennial timescale from previous studies in the area shows a fairly good correspondence to the timing of marked cold and warm events as evidenced from the Lake N14 and the Djúpáll trough records. Cooler periods are explained as the response to marked incursions of ice-laden polar water from the Arctic Ocean to the Denmark Strait region. Cool northerly and northwesterly winds along the East Greenland coast in relation to frequent strong atmospheric low pressure in the Barents Sea, coupled with strong high pressure over Greenland, would have favoured southward export of polar waters. A comparison with the proxy records of nuclide production (14 C and 10 Be) suggests that solar activity may have had some influence on the atmospheric pressure distribution in the Denmark Strait region. 相似文献
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Preliminary study on the dissolved and colloidal organic carbon in the Zhujiang River estuary 总被引:3,自引:0,他引:3
INTRODUCTIONEstuariescompriseamajorbiogeochemicalinterfaceconnectingthelandandthesea (Man toura,1 987) .Thebehaviorandfateofaparticularriver bornesubstanceintroducedintoanestuaryisdeterminedtoalargeextentbythebiogeochemicalpropertiesofthesubstanceaswellasp… 相似文献
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Vida Safari Gilnaz Arzpeyma Fereshteh Rashchi Navid Mostoufi 《International Journal of Mineral Processing》2009,93(1):79-83
A new mathematical model was developed for leaching of zinc ores containing silicates such as hemimorphite which produce a gel during leaching with sulfuric acid. This model is based on the shrinking core model in which the particle size and the reacting core shrink simultaneously. It was shown that the actual dissolution time of the ore particles is longer than the time corresponding to the dissolution of chemical zinc oxide itself. It was suggested that because of the existence of silicates in the ore, a gelatinous layer was formed around the reacting core. Since the gel product is soft, it breaks apart when the particles collide and as a result, the particles shrink. However, a thin gelatinous layer always covers the reacting core which increases the mass transfer resistance and increases the leaching time. This model was applied to leaching of a zinc-rich tailing containing hemimorphite and the thickness of the gelatinous layer as well as the diffusion coefficient in this layer was determined. 相似文献