Reaction time scales for sulphate reduction in sediments of acidic pit lakes and its relation to in-lake acidity neutralisation

Sulphate reduction is a key reaction to remove acidity from water bodies affected by acid mine drainage. In this study, ³⁵SSO₄²⁻ reduction rates determined in sediments from a variety of acidic lignite pit lakes have been compiled. The rates decreased with pH and are strongly dependent on carbon substrate. The rates were fitted to a Monod model adapted to the specific conditions of acidic pit lakes (APL) sediments: i) sulphate reduction rate is independent from sulphate concentration due to the high concentration typically observed in APL systems (10–30 mM), ii) the observed pH dependency of sulphate reduction was accounted for by an inhibition function F_inihibt which considers the occurrence of low cell numbers of sulphate reducing bacteria at pH values < 4.75. Simulated steady-state sulphate reduction rates are predicting measured rates at carbon substrate concentrations of <10 μM. Estimated steady-state reaction time scales range between 2.4 h at pH 7 and 41 h at pH 3 at a carbon half-saturation constant of K_C−S = 100 μM and are increasing with increasing K_C−S values. Time scales at low pH are too long to allow for significant generation of alkalinity during the time of residence of groundwater passing through the top and hence most reactive zone of APL sediments which has important implications for the remediation of acidic pit lakes.     

不同刚度植物杆群对规则波传播及紊动特性影响研究

以不同刚度硅胶圆杆群为概化植物模型,测定其抗弯弹性模量,通过波浪水槽实验,研究规则波在不同刚度植物杆群内的流速分布、紊动特征及不同刚度杆群的消浪效果。实验结果表明,当波浪通过柔性杆群时,受其摆动的影响,流速周期变化从单峰型逐渐转变成双峰型,杆群刚度越小形成的二次波峰越明显;不同刚度杆群内水体紊动强度变化显示,杆群刚度越大,造成杆群内水体的紊动强度越大;随着杆群抗弯弹性模量的增大,其消浪系数也增大,消浪系数的增长与材料的抗弯弹性模量值非线性关系,而是在某一弹性模量范围内,对消浪系数的影响较为敏感。     

An Analytical Solution for Dynamic Response of the Plate with Different Impedances Subjected to Underwater Explosion

In this paper, the transmitted part of the incident wave is considered to revise Taylor’s solution, which is used to extend its application for analytical models to predict the response of the plate with different material properties. The influence of the material properties and the boundary condition of the plate on fluid and structural dynamics is systematically investigated. The analytical results are compared with those of detailed dynamic FE simulations and the two are in good agreement. The results indicate that the analytical method is valid and suitable for the plates with different material properties subjected to underwater explosion. It is found that Taylor’s results of the plate with small impedance are invalid, which indicates a potential application field for the analytical method.     

SEISMIC IMPACT LOADING IN INELASTIC TENSION-ONLY CONCENTRICALLY BRACED STEEL FRAMES: MYTH OR REALITY?

Tension-Only Concentrically Braced Frames (TOCBF) exhibit deteriorating pinched hysteretic behaviour during strong earthquakes. Slender braces transit between an elastic buckling state, a restraightening state, in which they carry almost no load, an elastic tensile loading state as they are suddenly taut and, finally, a tensile yielding state. It has long been suspected that the sudden increase in tensile forces in the braces of TOCBSF creates detrimental impact loading on the connections and other structural elements. No experimental evidence, however, has been provided so far to confirm, or to quantify, this impact phenomenon. This paper addresses this issue through shake table tests of half scale, two-storey, TOCBF models. By normalizing the hysteresis loops of braces obtained from shake table tests to the yield strength of steel obtained from quasi-static tests, the increase in tensile forces in the braces was obtained. Results of dynamic tensile tests on steel coupons under similar strain rates as observed during the shake table tests showed that this increase in tensile forces is not the result of impact, but is rather caused by a yield strength increase of the steel under high strain rate. A procedure is proposed to estimate and account for this increase in tensile forces in the braces at the design stage.     

A simulation study of the role of raindrop erosion in the formation of desert pavements

A simple model of raindrop erosion—the combined effects of the detachment of sediment by raindrops and its transport by splash or by overland flow—is developed to examine the role of this process in the formation of desert pavements. Application of the model to soils in areas of existing pavement initially simulates the formation of pavements, but the changing sediment size distributions lead to the subsequent destruction of these modelled surfaces. An improved model that accounts for the feedback effects of the changing size distributions on infiltration and microtopography is then developed. Incorporating these effects allows simulated pavements to be maintained over longer periods. The model yields desert pavements whose particle size compositions differ in response to differences in initial soil characteristics, slope and rainfall intensity. This model is tested against empirical data from a site where there is intershrub pavement and associated mounds of fines beneath desert shrubs. The results successfully predict the accumulation of fines under shrubs but underestimate the development of the pavement between shrubs. These findings suggest that the raindrop erosion mechanism on its own cannot account for the development of the pavement and that some other mechanism leading to the surface concentration of coarse particles must also be operating.     

近60a来新疆不同海拔气候变化的时空特征分析

全球变暖是当前全球气候变化研究的热点之一,新疆深居亚欧大陆内陆,地形气候复杂,探讨该区域气候变化与海拔的关系对全球气候变化研究具有重要的参考意义。基于1958—2017年新疆41个气象站的月和年平均气候数据,采用一元线性回归、Mann Kendall（M-K）趋势分析和突变检验等方法分析该地区气候变化的时空分布与海拔的关系。结果表明：1958—2017年新疆年均气温、年均降水量均呈上升趋势,但增加幅度具有时间和空间差异。在时间上,北疆四季平均气温增温幅度均大于南疆（冬季除外）,四季降水量增幅北疆大于南疆（夏季除外）;在空间上,北疆气温和降水的增幅均大于南疆。研究区各个站点气温呈现出南部高而北部低的空间格局,年均降水量北部多,南部低。各个站点气温倾向率总体随海拔增加而减少,年均降水量变化率随海拔升高而增加,在不同海拔带内部存在差异。综上所述,受全球气候变暖的影响,近60 a来新疆年均气温和年均降水量均呈上升趋势,尤其是北疆对全球气候变暖的响应较为敏感。     

锁块式水下采油树井口连接器性能分析

水下采油树井口连接器是连接采油树和井口的关键设备,对深海水下勘探开发及采油树的安装连接具有不可或缺的重要意义。以一种锁块式水下连接器为例,介绍其结构组成和工作原理,通过有限元建立连接器的三维模型,分析连接器在下放安装工况、连接锁紧工况、正常生产工况和钻完井工况下的连接性能,得出井口与采油树本体接触面作用力、VX钢圈接触应力和锁块受力情况随外部载荷的相互关系。结果表明,VX钢圈在整个过程中都能够保持良好密封,井口与采油树本体接触面未发生分离,弯矩对连接器连接性能影响很大,在额定弯矩作用时连接器部分锁块已发生弹塑性失效。     

贵州省不同强度区域性凝冻过程环流形势对比分析

利用贵州省84个气象站逐日观测资料以及再分析资料,对4种不同强度区域性凝冻过程进行对比分析。结果表明：500 hPa位势高度场上中高纬度的亚洲东部区域距平场呈现“+-”的分布或有切断低压分布,贝加尔湖至中国华北地区以经向环流为主;850 hPa风场上云南南部以南受偏南风和西南风控制,并且在江南至华南存在西南或西风急流,是4种不同强度凝冻过程中形势场共性特征。500 hPa高度场上中高纬度地区呈两槽一脊或一槽一脊分布;风场上850 hPa东北风回流和700 hPa西南急流形成上暖下冷的形势场,同时850 hPa形成稳定低层切变线;温度场上存在冷-暖-冷的夹心结构,近地面层0 ℃线维持在900 hPa以下,均是较强等级以上的区域性凝冻过程中形势场共性特征。而对于一般性区域性凝冻过程,500 hPa位势高度场上呈多槽脊分布,风场上是否存在东北风回流和低层切变线,温度场上是否存在冷-暖-冷的夹心结构以及近地面层0 ℃线位置等特征均不统一。温度剖面图上,当近地面层0 ℃线位置最低时或出现冷-暖-冷的夹心结构时段与凝冻过程影响范围最广、灾情最重的时间段对应。     

Sulfide intrusion in the tropical seagrasses Thalassia testudinum and Syringodium filiforme

Sulfur and oxygen dynamics in the seagrasses Thalassia testudinum and Syringodium filiforme and their sediments were studied in the US Virgin Islands (USVI) in order to explore sulfide intrusion into tropical seagrasses. Four study sites were selected based on the iron concentration in sediments and on proximity to anthropogenic nutrient sources. Meadow characteristics (shoot density, above- and below-ground biomass, nutrient content) were sampled along with sediment biogeochemistry. Sulfide intrusion was high in T. testudinum, as up to 96% of total sulfur in the plant was derived from sediment-derived sulfides. The sulfide intrusion was negatively correlated to the turnover of sulfides in the sediments regulated by both plant parameters and sediment sulfur pools. Sediment iron content played an indirect role by affecting sulfide turnover rates. Leaf production was negatively correlated with sulfide intrusion suggesting that active growth reduced sulfide intrusion. Sulfide intrusion was lower in S. filiforme (up to 44%) compared to T. testudinum consistent with a higher internal nighttime oxygen concentrations found for S. filiforme. When S. filiforme can take advantage of its ability to maintain high internal oxygen concentrations, as was the case on the USVI, it could increase its success in colonizing unvegetated disturbed sediments with potentially high sulfide concentrations.     

新村湾海黾草（Thalassia hemprichii）的生长策略研究

海草的种内差异是它在特定环境中形成生长策略的关键因素。本研究通过将现场实测数据和文献记录进行类比以探讨新村湾海黾草（Thalassia hemprichii）的生长策略。研究结果表明海黾草地下茎伸长速率的差异可以解释该海草生物量和生长的大部分种内差异;新村湾海黾草垂直地下茎和水平地下茎的伸长速率在夏季分别为2．38cm／yr和24．4cm／yr,在冬季分别为1．87cm／yr和29．2cm／yr。海黾草茎枝密度的变化范围是822shootsm^-2至941shoots m^-2,最大值出现在夏季而最小值出现在冬季,生物量的季节变化与此类似。新村湾海黾草通过交替调节垂直地下茎和水平地下茎的伸长速率以适应光照强度和温度的季节变化,从而导致茎枝密度和地上生物量的相应变化。通过这样的生长策略,海黾草可以把夏季干旱和冬季光照强度下降对其生长造成的消极影响降低到最小程度。