高精度测量岩石样品Ce同位素组成的TIMS方法

介绍了对岩石样品的Ce同位素组成进行高精度测量的TIMS方法.采用α-羟基异丁酸(α-HIBA) 离子交换法分离和纯化岩石样品中的La、Ce元素, Ce同位素组成和La、Ce含量测定在Triton热电离质谱仪上完成.质谱标样JMC304的138Ce/142Ce比值统计值为0.0225762±0.0000015, 与大部分文献值一致.应用该方法对USGS玄武岩标样BCR-2和峨眉山玄武岩EQB的138Ce/142Ce比值和La、Ce含量进行了分析, 其结果分别为: 0.0225572±0.0000010、25.2±0.3μg/g、55.8±0.9μg/g和0.0225755±0.0000003、54.2±0.4μg/g、117.4±1.3μg/g.BCR-2的La、Ce含量测定结果与其证书值在误差范围内一致, 其分析精度为0.001%~0.005%.所有样品的140Ce/142Ce比值测定结果统计值为7.9439±0.0002, 介于文献最低值7.941与最高值7.947之间, 可能代表了该比值的最佳估计值.      

Concentrations of 137Cs, 90Sr, 108m Ag, 239+240 Pu and atom ratio of 240Pu/239Pu in tanner crabs, Chionoecetes japonicus and Chionoecetes opilio collected around Japan

The anthropogenic radionuclides, ¹³⁷Cs, ⁹⁰Sr, ^108mAg, ^239+240Pu, were measured in two Chionoecetes species, red queen crab (Chionoecetes japonicus) and snow crab (Chionoecetes opilio) collected around Japan during 1996–2007. There was no increase in the concentrations of these radionuclides and no large variation of the atom ratio of ²⁴⁰Pu/²³⁹Pu during this research period. These results indicated that the source of the radionuclides was not the radioactive wastes dumped by the former USSR and Russia and originated from past nuclear weapon tests. The higher atom ratio in the crab species than that from global fallout would be contributed by the Pacific Proving Grounds close-in fallout. The variability of the concentration of radionuclides in the crab species would result from the variability of the composition and quantity in the diet. However, the decrease in the concentration of radionuclides with sampling depth would depend on the concentration in the seawater and diet.     

降水对江浙沪PM_(2.5)的清除效率研究

为了解不同程度的降水对江浙沪地区大气PM_(2.5)的清除作用,搜集了2014—2016年该地区41个城市的降水和PM_(2.5)观测数据,通过对比2 a非降水和全时段PM_(2.5)平均浓度的差异,发现前者显著高于后者,说明降水对该地区PM_(2.5)具有清除作用。利用降水前与降水期间PM_(2.5)的浓度差异作为降水对PM_(2.5)的清除率,降水后与降水期间的浓度差异作为雨后浓度回升的增加率,分别研究了目标区域不同时期、不同降雨量以及不同降雨时长对PM_(2.5)的清除效果。结果显示:(1)与江浙沪南部地区不同的是,北部地区降水清除率与降水前浓度存在正相关,降水后浓度的增加与当地的排放量呈正相关。(2)当降水量为30 mm或者降水时长为36 h时,清除率增幅减缓,说明降水对PM_(2.5)的清除效率存在着阈值。     

圆形断面管道非满流流速计算表达式

工程实际中,常需要计算某一充满度下管道非满流的流量及流速。目前大多数计算模型均采用水力半径作为反映过流断面形状及几何尺寸的特征参数。针对不同充满度的研究结果表明,这种类型模型的计算结果与真实的流动特性并不相符,尤其当水深接近管顶时。根据水动力学基本原理及试验研究手段,对圆形断面管道无压均匀流流量-充满度非单一性进行了探索,并提出了以流量作为形状特征参数的更为合理且简单实用的水流流速计算表达式。     

Evolution of the north flank of Tenerife by recurrent giant landslides

Geomorphologic analysis of submarine and subaerial surface features using a combined topographic/bathymetric digital elevation model coupled with onshore geological and geophysical data constrain the age and geometry of giant landslides affecting the north flank of Tenerife. Shaded relief and contour maps, and topographic profiles of the submarine north flank, permit the identification of two generations of post-shield landslides. Older landslide materials accumulated near the shore (<40-km) and comprise 700 km³ of debris. Thickening towards a prominent axis suggests one major landslide deposit. Younger landslide materials accumulated 40–70 km offshore and comprise the products of three major landslides: the La Orotava landslide complex, the Icod landslide and the East Dorsal landslide complex, each with an onshore scar, a proximal submarine trough, and a distal deposit lobe. Estimated lobe volumes are 80, 80 and 100 km³, respectively. The old post-shield landslide scar is an amphitheatre, 20–25 km wide, partly submarine, now completely filled with younger materials. Age–width relationships for Tenerife's coastal platform plus onshore geological constraints suggest an age of ca. 3 Ma for the old collapse. Young landslides are all less than 560 ka old. The La Orotava and Icod slides involved failures of slabs of subaerial flank to form the subaerial La Orotava and Icod valleys. Offshore, they excavated troughs by sudden loading and basal erosion of older slide debris. The onshore East Dorsal slide also triggered secondary failure of older debris offshore. The slab-like geometry of young failures was controlled by weak layers, deep drainage channels and flank truncation by marine erosion. The (partly) submarine geometry of the older amphitheatre reflects the absence of these features. Relatively low H/L ratios for the young slides are attributed to filling of the slope break at the base of the submarine edifice by old landslide materials, low aspect ratios of the failed slabs and channelling within troughs. Post-shield landslides on Tenerife correlate with major falls in sea level, reflecting increased rates of volcanism and coastal erosion, and reduced support for the flank. Landslide head zones have strongly influenced the pattern of volcanism on Tenerife, providing sites for major volcanic centres.     

反复荷载下混凝土框架柱塑性铰区基于延性的抗剪承载力机理分析

在试验研究的基础上,以框架结构延性设计为目的采用桁架＋拱模型研究了框架柱塑性铰区域抗剪受力机理,分析了,位移延性系数、加载循环次数等因素对框架柱构件塑性铰区域剪切受力性能的影响,并结合试验结果提出了混凝土框架柱塑性铰区域剪切承载力抗震延性设计实用公式,可有效实现结构的延性破坏机制。主要为配合GBJ10-89的修订,该成果已被《混凝土结构设计规范》（GB50010—2003）吸收。     

地震台阵滤波及子台分布对聚束效果的影响(Ⅱ)——子台分布及聚束效果的分析

本假设对于确定的相关系数及子台间距存在一个相干波长，将不同频率、震中距的相关性变化的原因归纳为视波长的变化．对近事件而言，几乎不存在相关系数十分理想的子台间距的区间范围．对非理想相关的台阵，应用S．Mykkeltveit等介绍的增益公式来预测台阵的增益，其效果与实际情况吻合的较好．论述了区域台阵与侦察远处事件的台阵有诸多不同之处．     

相变前的热力学平衡态对铁电液晶排列的影响

本实验选用ZLI-3654型铁电液晶(FLC)以及SE-3140型取向剂制备FLC器件样品,通过改变FLC相变过程中的降温速率以及相变前的热力学平衡态来研究FLC相变前的热力学平衡态对FLC排列的影响,共进行了十组实验.实验后,将FLC器件静态对比度进行比较,得出手性向列相到近晶A相(N^*-SmA)相变前的热力学平衡态对FLC实现均匀排列起着极其重要的作用的结论.实验结果表明:器件的静态对比度可高达620 ∶1, N^*-SmA相变前的热力学平衡态有利于形成高对比     

中国地震台网各类前兆手段地震监测能力的评价

利用1988～2005年18年间全国会商会所提出的各类定点前兆异常,研究其与下一年(1989～2006年)大陆地震的对应关系,从414次地震资料的统计中得出,除地下水位和地磁外,其它5种前兆观测手段在有震区的异常比均低于无震区或全大陆的异常比,但各手段综合异常比在有震区要高于无震区。遵照"地震监测能力好的前兆手段,在其监测范围内,有震时应有较高的异常比,无震时应有较低的异常比"的原则,我们认为地磁和地下水位是比较好的前兆观测方法。     

Base cation concentrations in forest litter and topsoil have different responses to climate and tree species along elevational gradients

The forest litter is an essential reservoir of nutrients in forests, supplying a large part of absorbable base cations(BC) to topsoil, and facilitating plant growth within litter-soil system. To characterize elevational patterns of base cation concentrations in the forest litter and topsoil, and explore the effects of climate and tree species, we measured microclimate and collected the forest litter and topsoil(0-10 cm) samples across an elevational range of more than 2000 m(1243 ～ 3316 m a.s.l.),and analyzed the concentrations of BC in laboratory. Results showed that: 1) litter Ca concentration displayed a hump-shaped pattern along the elevational gradients, but litter K and Mg showed saddle-shaped patterns. Soil Ca concentration increased with elevation, while soil K and Mg had no significant changes. 2) Ca concentration in the forest litter under aspen(Populus davidiana) was significantly higher than that in all other species, but in topsoil, Ca concentration was higher under coniferous larch and fir(Larix chinensis and Abies fargesii). Litter K and Mg concentrations was higher under coniferous larch and fir, whereas there were nosignificant differences among tree species in the concentrations of K and Mg in topsoil. 3) Climatic factors including mean annual temperature(MAT), growing season precipitation(GSP) and non-growing season precipitation(NGSP) determined BC concentrations in the forest litter and topsoil. Soil C/N and C/P also influenced BC cycling between litter and soil. Observation along elevations within different tree species implies that above-ground tree species can redistribute below-ground cations, and this process is profoundly impacted by climate. Litter and soil Ca, K and Mg with different responses to environmental variables depend on their soluble capacity and mobile ability.